cubebol
(3s (3S,3ar 3aR,3br 3bR,4s 4S,7r 7R,7ar)-3 7aR)-3,7-二甲基-4-(丙-2-基)八氢-1h-环戊[1 7-dimethyl-4-(propan-2-yl)octahydro-1H-cyclopenta[1,3] proppropa [1 3]cyclopropa[1,2]苯-3-醇 2]benzen-3-ol

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Name:(3s (3S,3ar 3aR,3br 3bR,4s 4S,7r 7R,7ar)-3 7aR)-3,7-二甲基-4-(丙-2-基)八氢-1h-环戊[1 7-dimethyl-4-(propan-2-yl)octahydro-1H-cyclopenta[1,3] proppropa [1 3]cyclopropa[1,2]苯-3-醇 2]benzen-3-ol
CAS号 CAS Number: 23445-02-5Picture of molecule3D/INCHI
FDA UNII:9C9ZTS2B3U
nikkaji网站 Nikkaji Web:J16.596D
XlogP3-AA: 3.90(估 est)
分子量 Molecular Weight:222.37142000
式 Formula:c15 h26 o C15 H26 O
核磁共振预测器 NMR Predictor:预测(适用于Chrome或Firefox) Predict (works with chrome or firefox)
类别 Category:flavoring agents
 
美国 US/欧盟 EU/ fda / jecfa / fema / Flavis / 文献 Scholar /专利 Patent :
谷歌学术 Google Scholar:搜索 Search
谷歌书 Google Books:搜索 Search
谷歌学术 Google Scholar: with word "volatile"搜索 Search
谷歌学术 Google Scholar: with word "flavor"搜索 Search
谷歌学术 Google Scholar: with word "odor"搜索 Search
调香师和调味师 Perfumer and Flavorist:搜索 Search
谷歌专利 Google Patents:搜索 Search
美国专利 US Patents:搜索 Search
欧盟专利 EU Patents:搜索 Search
pubchem专利 Pubchem Patents:搜索 Search
已发布 PubMed:搜索 Search
NCBI:搜索 Search
jecfa食品调味料 JECFA Food Flavoring:2028荜澄茄/山苍子波 2028 cubebol
fema号 FEMA Number:4497 cubebol
自由贸易区 FDA:不再提供这七种合成调味剂的使用 No longer provide for the use of these seven synthetic flavoring substances
fda mainterm(satf) FDA Mainterm (SATF):23445-02-5 ; CUBEBOL
 
物理性质 Physical Properties:
出现 Appearance: 白结晶固体(估 est)
化验 Assay: 95.00至100.00 95.00 to 100.00
食品化学品法典列表 Food Chemicals Codex Listed: No
熔点 Melting Point: 64.00 to 65.00 °C. @ 760.00 mm 汞 Hg
沸点 Boiling Point: 279.00 to 280.00 °C. @ 760.00 mm 汞 Hg
蒸汽压力 Vapor Pressure:0.000480 毫米汞柱 mm汞 Hg @ 25.00 °C. (估 est)
闪点 Flash Point: 242.00 °F. tcc TCC ( 116.67 °C. )
logp(o / w) logP (o/w): 4.592(估 est)
溶于 Soluble in:
 alcohol
 水 water, 略 slightly
 水 water, 25°c(3.12 mg / l)(估 est)
不溶于 Insoluble in:
 水 water
 
感官特性 Organoleptic Properties:
气味描述 Odor Description:辣薄荷 spicy minty
来自其他 的气味和/或风味描述(如果找到)。 Odor and/or flavor descriptions from others (if found).
 
化妆品信息 Cosmetic Information:
没找到 None found
 
供应商 Suppliers:
艾克辛 Axsyn
仅供实验/研究使用。 For experimental / research use only.
1h-cyclopenta [1 1H-Cyclopenta[1,3] proppropa [1 3]cyclopropa[1,2]苯-3-醇 2]benzen-3-ol,octahydro-3,7-二甲基-4-(1-甲基乙基)- 7-dimethyl-4-(1-methylethyl)-, (3s (3S,3ar 3aR,3br 3bR,4s 4S,7r 7R,7ar)- 7aR)-
Parchem Parchem
cubebol
化学资源协会 Chemical sources Association Inc
需要这个物品来调味/食用吗? Need This Item for Flavor/Food?: 您 You can contact the 化学资源协会 Chemical sources Association Inc
 
安全信息 Safety Information:
 
危害识别 Hazards identification
 
物质或混合物的分类 Classification of the substance or mixture
根据29 cfr 1910(osha hcs)进行ghs分类 GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
没有找到。 None found.
ghs标签元素 GHS Label elements, 包括预防性声明 including precautionary statements
 
象形图 Pictogram
 
危险说明 Hazard statement(s)
没有找到。 None found.
防范说明 Precautionary statement(s)
没有找到。 None found.
口服/肠胃外毒性 Oral/Parenteral Toxicity:
未定 Not determined
皮肤毒性 Dermal Toxicity:
未定 Not determined
吸入毒性 Inhalation Toxicity:
未定 Not determined
 
使用安全信息 Safety in Use Information:
类别 Category: flavoring agents
推荐的荜澄茄醇使用水平 Recommendation for cubebol usage levels up to:
 不用于香水。 not for fragrance use.
 
结构类 Structure Class: I
采用 Use 等级 levels for FEMA GRAS flavoring 物质 物质 substances on 哪一个 which the FEMA 专家 Expert 面板 Panel 基于 based its its 判断 judgments that the 物质 物质 substances are 通常 generally 公认的 recognized as safe (GRAS).
The 专家 Expert 面板 Panel also 发表 publishes 分离 separate 广泛 extensive 评论 reviews of scientific information on all FEMA GRAS flavoring 物质 物质 substances and can be 发现 found at FEMA 味道 Flavor Ingredient 图书馆 Library
出版编号 publication number: 24
点击这里查看出版物24 Click here to view publication 24
 平均 average 通常 usual 百万分之几 ppm平均 average 最大 maximum 百万分之几 ppm
焙烤食品 baked goods: 1.0000030.00000
饮料(不含醇) beverages(nonalcoholic): 1.0000030.00000
醇饮料 beverages(alcoholic): 1.0000030.00000
早餐麦片 breakfast cereal: 1.0000030.00000
起司 cheese: --
口香糖 chewing gum: 1.0000030.00000
调味品/调味品 condiments / relishes: --
糖果烧烤 confectionery froastings: 1.0000030.00000
蛋制品 egg products: --
脂肪/油 fats / oils: --
鱼产品 fish products: --
冷冻乳制品 frozen dairy: 1.0000020.00000
水果冰 fruit ices: --
明胶/布丁 gelatins / puddings: --
砂糖 granulated sugar: 1.0000020.00000
肉汁 gravies: --
硬糖 hard candy: 1.0000020.00000
仿乳制品 imitation dairy: --
速溶咖啡/茶 instant coffee / tea: 1.0000020.00000
果酱/果冻 jams / jellies: 1.0000010.00000
肉制品 meat products: --
奶制品 milk products: 1.0000010.00000
坚果产品 nut products: 1.0000010.00000
其他谷物 other grains: --
家禽 poultry: --
加工水果 processed fruits: --
加工蔬菜 processed vegetables: --
重构蔬菜 reconstituted vegetables: --
调味料 seasonings / flavors: --
休闲食品 snack foods: --
软糖 soft candy: 1.0000030.00000
汤类 soups: --
糖替代品 sugar substitutes: 1.0000030.00000
甜酱 sweet sauces: 1.0000030.00000
 
安全参考 Safety references:
Epi系统 EPI System: 视图 View
EPA ACToR:毒理学资料 Toxicology Data
EPA物质注册服务(SRS) :注册表 Registry
实验室化学安全摘要 Laboratory Chemical Safety Summary :11276107
国家过敏和传染病研究所 National Institute of Allergy and Infectious Diseases:Data
(3s (3S,3ar 3aR,3br 3bR,4s 4S,7r 7R,7ar)-3 7aR)-3,7-二甲基-4-(丙-2-基)八氢-1h-环戊[1 7-dimethyl-4-(propan-2-yl)octahydro-1H-cyclopenta[1,3] proppropa [1 3]cyclopropa[1,2]苯-3-醇 2]benzen-3-ol
chemidplus Chemidplus:0023445025
 
参考资料 References:
莱芬韦尔 Leffingwell:手性或物品 Chirality or Article
 (3s (3S,3ar 3aR,3br 3bR,4s 4S,7r 7R,7ar)-3 7aR)-3,7-二甲基-4-(丙-2-基)八氢-1h-环戊[1 7-dimethyl-4-(propan-2-yl)octahydro-1H-cyclopenta[1,3] proppropa [1 3]cyclopropa[1,2]苯-3-醇 2]benzen-3-ol
NIST化学网络书籍 NIST Chemistry WebBook: 搜索INCHI
pubchem(cid) Pubchem (cid):11276107
pubchem(sid) Pubchem (sid):42355570
信息基 Pherobase:视图 View
 
其他资料 Other Information:
(iupac) (IUPAC):元素的原子量2009 Atomic Weights of the Elements 2009
(iupac) (IUPAC):元素的原子量2009(pdf) Atomic Weights of the Elements 2009 (pdf)
影片 Videos:元素周期表 The Periodic Table of Videos
RBC :本网站使用的原子量 Atomic Weights use for this web site
(iupac) (IUPAC):元素周期表 Periodic Table of the Elements
食品中添加的fda物质(以前为af) FDA Substances Added to Food (formerly EAFUS):视图 View
CHEBI:视图 View
hmdb(人类代谢组数据库) HMDB (The Human Metabolome Database):搜索 Search
典型的g.c. Typical G.C.
vcf在线 VCF-Online:食品中的挥发性有机化合物 VCF Volatile Compounds in Food
化学蜘蛛 ChemSpider:视图 View
维基百科 Wikipedia:视图 View
rsc学习化学 RSC Learn Chemistry:视图 View
o FAO:Cubebol
 
潜在搅拌机 Potential Blenders and core 组件 components note
没找到 None found
 
潜在用途 Potential Uses:
没找到 None found
 
存在(自然 Occurrence (nature, food, 其他) other):note
 雪松油弗吉尼亚@ 0.10% cedarwood oil virginia @ 0.10%
Data gc GC 搜索 Search Trop Picture
 荜澄茄/山苍子油@ 15.18% cubeb oil @ 15.18%
Data gc GC 搜索 Search Trop Picture
 假荜澄茄/山苍子油 false cubebs oil
搜索 Search Trop Picture
 古巴的天竺葵玫瑰香精油(天竺葵属)0.60% geranium rose-scented oil (pelargonium spp.) cuba @ 0.60%
Data gc GC 搜索 Search Trop Picture
 薰衣草油abrialis @微量 lavandin oil abrialis @ trace%
Data gc GC 搜索 Search Trop Picture
 乌拉圭香橙油@痕量% mandarin oil uruguay @ trace%
Data gc GC 搜索 Search Trop Picture
  mikania cordata(burm )b.l.罗宾逊河法国科尔达塔叶油@ 0.20%
Data gc GC 搜索 Search Trop Picture
 
同义词 Synonyms:
 cubeb camphor
1H-cyclopenta[1,3] proppropa [1 3]cyclopropa[1,2]苯-3-醇 2]benzen-3-ol,octahydro-3,7-二甲基-4-(1-甲基乙基)- 7-dimethyl-4-(1-methylethyl)-, (3s (3S,3ar 3aR,3br 3bR,4s 4S,7r 7R,7ar)- 7aR)-
(3s (3S,3ar 3aR,3br 3bR,4s 4S,7r 7R,7ar)-3 7aR)-3,7-dimethyl-4-(propan-2-yl)octahydro-1H-cyclopenta[1,3] proppropa [1 3]cyclopropa[1,2]苯-3-醇 2]benzen-3-ol
(3s (3S,3ar 3aR,3br 3bR, 4s 4S,7r 7R,7ar)- 7aR)-octahydro-3,7-二甲基-4-(1-甲基乙基)-1h-环戊(1 7-dimethyl-4-(1-methyl ethyl)-1H-cyclopenta(1,3)环丙烷(1 3)cyclopropa(1,2)benzen-3-ol
(-)-(1R,4s 4S,5r 5R,6r 6R,7s 7S,10R)-7-isopropyl-4,10-二甲基三环[4.4.0.0(1 10-dimethyl-tricyclo[4.4.0.0(1,5)] decan-4-ol 5)]decan-4-ol
(1R,4s 4S,5r 5R,6r 6R,7s 7S,10R)-7-isopropyl-4,10-二甲基三环[4.4.0.0(1 10-dimethyl-tricyclo[4.4.0.0(1,5)] decan-4-ol 5)]decan-4-ol
 

文章 Articles:

谷歌专利 Google Patents:使用多维醇作为调味成分 Use of cubebol as a flavoring ingredient
已发布 PubMed:两个偶氮类日本柳杉种群的精油表征及其生物学评价。 Essential oil characterization of two Azorean Cryptomeria japonica populations and their biological evaluations.
已发布 PubMed:挥发物成分鉴定圆锥形草中隐性物种的方法。 Identification of cryptic species within liverwort Conocephalum conicum based on the volatile components.
已发布 PubMed:[五味子茎中的倍半萜类]。 [Sesquiterpenes from stem of Schisandra glaucescens].
已发布 PubMed:毛黄连木叶片中萜类成分的种群间变异性来自阿尔及利亚 Inter-population variability of terpenoid composition in leaves of Pistacia lentiscus L. from Algeria: 化学生态学方法。 a chemoecological approach.
已发布 PubMed:倍半灰质的倍半萜烯合酶cop4和cop6 Sesquiterpene synthases Cop4 and Cop6 from Coprinus cinereus: 法呢基焦磷酸几何异构体的催化混杂和环化。 catalytic promiscuity and cyclization of farnesyl pyrophosphate geometric isomers.
已发布 PubMed:通过酿酒酵母中甲羟戊酸途径的代谢工程增强法呢基二磷酸法库作为倍半萜类的直接前体。 Enhancement of farnesyl diphosphate pool as direct precursor of sesquiterpenes through metabolic engineering of the mevalonate pathway in Saccharomyces cerevisiae.
已发布 PubMed:(-)-cubebol和(-)-10-epicubebol的立体控制合成,涉及分子内的α-锂化环氧化物的环丙烷化。 Stereocontrolled syntheses of (-)-cubebol and (-)-10-epicubebol involving intramolecular cyclopropanation of alpha-lithiated epoxides.
已发布 PubMed:面选择性铂-合成(-)-荜澄茄/山苍子体 Synthesis of (-)-cubebol by face-selective platinum-, 金- gold-, 或铜催化的环异构化 or copper-catalyzed cycloisomerization: 手性转移和机理见解的证据。 evidence of chirality transfer and mechanistic insights.
已发布 PubMed:通过计算机驱动的代谢工程提高酿酒酵母中的倍半萜烯产量。 Enhancing sesquiterpene production in Saccharomyces cerevisiae through in silico driven metabolic engineering.
已发布 PubMed:黑心材型柳杉粳米提取物的蚊幼虫活性。 Mosquito larvicidal activities of extractives from black heartwood-type Cryptomeria japonica.
已发布 PubMed:日本雪松的防草剂 Antifeedants against Locusta migratoria from the Japanese Cedar, 柳杉ii。 Cryptomeria japonica II.
已发布 PubMed:酿酒酵母中植物倍半萜的生产 Production of plant sesquiterpenes in Saccharomyces cerevisiae: 抑制erg9对倍半萜生物合成的影响。 effect of ERG9 repression on sesquiterpene biosynthesis.
已发布 PubMed:面选择性铂-合成(-)-荜澄茄/山苍子体 Synthesis of (-)-cubebol by face-selective platinum-, 金- gold-, 或铜催化的环异构化 or copper-catalyzed cycloisomerization: 手征转移的证据。 evidence for chirality transfer.
已发布 PubMed:炔丙基乙酸酯的铂和金催化重排反应 Platinum- and gold-catalyzed rearrangement reactions of propargyl acetates: (-)-α-荜澄茄/山苍子烯的总合成 total syntheses of (-)-alpha-cubebene, (-)-荜澄茄/山苍子体 (-)-cubebol, 倍半萜烯和相关萜。 sesquicarene and related terpenes.
已发布 PubMed:[从日本雪松中分离和制备倍半萜醇 [Isolation and preparation of sesquiterpenols from the Japanese cedar, 柳杉d。不要 Cryptomeria japonica D. Don, 反相高效液相色谱的制备及其表征]。 by preparative reversed-phase high performance liquid chromatography and its characterization].
已发布 PubMed:日本雪松的防草剂 Antifeedants against Locusta migratoria from the Japanese Cedar, 柳杉ii。 Cryptomeria japonica II.
 
笔记 Notes:
没找到 None found
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