类别 Category:flavor and fragrance agents
美国 US/欧盟 EU/ fda / jecfa / fema / Flavis / 文献 Scholar /专利 Patent :
物理性质 Physical Properties:
出现 Appearance: | 无色至浅黄澄清液体(est) colorless to pale yellow clear liquid (est) |
化验 Assay: | 95.00至100.00 95.00 to 100.00
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食品化学品法典列表 Food Chemicals Codex Listed: | No |
比重 Specific Gravity: | 0.92600 to 0.93600 @ 20.00 °C.
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磅每加仑-(est)。 Pounds per Gallon - (est).: | 7.714 to 7.798
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折光率 Refractive Index: | 1.46400 to 1.47400 @ 20.00 °C.
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沸点 Boiling Point: | 198.00 °C. @ 760.00 mm 汞 Hg (est)
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蒸汽压力 Vapor Pressure: | 0.515000 毫米汞柱 mm汞 Hg @ 25.00 °C. (est) |
闪点 Flash Point: | 150.00 °F. tcc TCC ( 65.60 °C. ) (est)
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logp(o / w) logP (o/w): | 3.200(est) 3.200 (est) |
溶于 Soluble in: |
| alcohol | | 水 water, 25°C(est)时为137.2 mg / l 137.2 mg/L @ 25 °C (est) |
不溶于 Insoluble in: |
| 水 water |
感官特性 Organoleptic Properties:
气味类型 Odor Type: citrus |
fresh clean citrus minty spearmint herbal |
气味描述 Odor Description:用于柑橘和薄荷味 Used in citrus and minty flavours: 在饮料和奶制品中的含量为0.3-0.5百万分之几 ppm , 酱汁含量最高可达5百万分之几 ppm : 环氧可在醇和水溶液中损失 the epoxide can be lost in alcoholic and aqueous solutions, 在酸性条件下。 in acidic conditions.新鲜干净的柑橘薄荷留兰香草药 fresh clean citrus minty spearmint herbal |
来自其他 的气味和/或风味描述(如果找到)。 Odor and/or flavor descriptions from others (if found). |
化妆品信息 Cosmetic Information:
供应商 Suppliers:
安全信息 Safety Information:
首选sds SDS : 视图 View |
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危害识别 Hazards identification |
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物质或混合物的分类 Classification of the substance or mixture |
根据29 cfr 1910(osha hcs)进行ghs分类 GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
没有找到。 None found. |
ghs标签元素 GHS Label elements, 包括预防性声明 including precautionary statements |
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象形图 Pictogram | |
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危险说明 Hazard statement(s) |
没有找到。 None found. |
防范说明 Precautionary statement(s) |
没有找到。 None found. |
口服/肠胃外毒性 Oral/Parenteral Toxicity: |
肌内小鼠 intramuscular-老鼠 mouse LD50 100 mg/kg Journal of 科学的 Scientific and 产业 Industrial 研究 Research, C节 Section C: 生物科学。卷21 Biological Sciences. Vol. 21, pg。 342 Pg. 342, 1962.
老鼠 oral-老鼠 mouse LD50 2700 ul uL/kg Iyakuhin 贤九 Kenkyu. 研究 Study of 医疗 Medical 商店 Supplies. 卷 Vol. 9, pg。 518 Pg. 518, 1978.
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皮肤毒性 Dermal Toxicity: |
未定 Not determined
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吸入毒性 Inhalation Toxicity: |
未定 Not determined
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使用安全信息 Safety in Use Information:
类别 Category: | flavor and fragrance agents |
IFRA IFRA 码 Code of 实践 Practice 通知 not Notification of the 49th 修正案 Amendment to the IFRA IFRA 码 Code of 实践 Practice |
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采用 Use 等级 levels for FEMA GRAS flavoring 物质 物质 substances on 哪一个 which the FEMA 专家 Expert 面板 Panel 基于 based its 判断 judgments that the 物质 物质 substances are 通常 基因 generally 公认的 recognized as safe (GRAS). |
The 专家 Expert 面板 Panel 也 also 发表 publishes 分离 sepa率 鼠 rate 广泛 extensive 评论 reviews of scientific information on all FEMA GRAS flavoring 物质 物质 substances and can be 发现 found at FEMA 味道 Flavor Ingredient 图书馆 Library |
出版编号 publication number: 24 |
点击这里查看出版物24 Click here to view publication 24 |
| 平均 average 通常 usual 百万分之几 ppm | 平均 average 最大 maximum 百万分之几 ppm |
焙烤食品 baked goods: | - | - |
饮料(不含醇) beverages(nonalcoholic): | 0.05000 | 0.50000 |
醇饮料 beverages(alcoholic): | - | - |
早餐麦片 breakfast cereal: | - | - |
起司 cheese: | - | - |
口香糖 chewing gum: | - | - |
调味品/调味品 condiments / relishes: | 0.50000 | 5.00000 |
糖果烧烤 confectionery froastings: | - | - |
蛋制品 egg products: | - | - |
脂肪/油 fats / oils: | - | - |
鱼产品 fish products: | - | - |
冷冻乳制品 frozen dairy: | - | - |
水果冰 fruit ices: | - | - |
明胶/布丁 gelatins / puddings: | - | - |
砂糖 granulated sugar: | - | - |
肉汁 gravies: | - | - |
硬糖 hard candy: | - | - |
仿乳制品 imitation dairy: | - | - |
速溶咖啡/茶 instant coffee / tea: | - | - |
果酱/果冻 jams / jellies: | - | - |
肉制品 meat products: | - | - |
奶制品 milk products: | 0.05000 | 0.50000 |
坚果产品 nut products: | - | - |
其他谷物 other grains: | - | - |
家禽 poultry: | - | - |
加工水果 processed fruits: | - | - |
加工蔬菜 processed vegetables: | - | - |
重构蔬菜 reconstituted vegetables: | - | - |
调味料 seasonings / flavors: | - | - |
休闲食品 snack foods: | - | - |
软糖 soft candy: | - | - |
汤类 soups: | - | - |
糖替代品 sugar substitutes: | - | - |
甜酱 sweet sauces: | - | - |
安全参考 Safety references:
参考资料 References:
| 6-甲基-3-丙-1-烯-2-基-7-氧杂双环[4.1.0]庚烷 6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane |
NIST化学网络书籍 NIST Chemistry WebBook: | 搜索INCHI |
加拿大国内分公司。清单 Canada Domestic Sub. List: | 1195-92-2 |
pubchem(cid) Pubchem (cid): | 91496 |
pubchem(sid) Pubchem (sid): | 135049028 |
信息基 Pherobase: | 视图 View |
其他资料 Other Information:
潜在搅拌机 Potential Blenders and core 组件 components note
潜在用途 Potential Uses:
存在(自然 Occurrence (nature, food, 其他) other): note
同义词 Synonyms:
7-oxa | bicyclo[4.1.0]heptane, 1-methyl-4- (1-methylethenyl)- | 7-oxa | bicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)- | 1,2- | epoxylimonene | | limonene 1,2-epoxide | | limonene 1,2-oxide | | limonene epoxide | (cis+trans)-1,2-(+)- | 氧化烯 limonene oxide | | 氧化烯 limonene oxide 混合的 mixed 异构体 isomers | (+)- | 氧化烯 limonene oxide, 顺式和反式的混合物 mixture of cis and trans | D-8-p- | menthene-1,2-epoxide | 6- | methyl-3-prop-1-en-2-yl-7-氧杂双环[4.1.0]庚烷 7-oxabicyclo[4.1.0]heptane | 1- | methyl-4-(1-methylethenyl)-7-oxabicyclo(4.1.0)heptane | 1- | methyl-4-(1-methylethenyl)-7-氧杂双环[4.1.0]庚烷 7-oxabicyclo[4.1.0]heptane | 1- | methyl-4-(1-methylvinyl)-7-oxabicyclo(4.1.0)heptane | 1- | methyl-4-(1-methylvinyl)-7-氧杂双环[4.1.0]庚烷 7-oxabicyclo[4.1.0]heptane | 1- | methyl-4-(prop-1-en-2-yl)-7-氧杂双环[4.1.0]庚烷 7-oxabicyclo[4.1.0]heptane | 4-iso | propenyl-1-methyl-7-oxabicyclo[4.1.0]heptan | 4-iso | propenyl-1-methyl-7-氧杂双环[4.1.0]庚烷 7-oxabicyclo[4.1.0]heptane |
文章 Articles:
谷歌专利 Google Patents:氧化柠檬烯的热解 Pyrolysis of limonene oxide |
已发布 PubMed: 可见光 下多壁碳纳米管/二氧化钛复合纳米纤维对亚百万分之几 ppm柠檬烯的光催化作用 |
已发布 PubMed:溴化倍半萜的合成与结构修饰 Synthesis and structural revision of a brominated sesquiterpenoid, 阿丁烯 aldingenin C. |
已发布 PubMed:假设蛋白质的结构表征 Structural characterization of a hypothetical protein: 可能与嗜酸链球菌中的三甲胺代谢有关。 a potential agent involved in trimethylamine metabolism in Catenulispora acidiphila. |
已发布 PubMed:埋藏试验后,(+)-柠檬烯环氧化物在小鼠体内的潜在抗氧化剂和抗焦虑作用。 Potential antioxidant and anxiolytic effects of (+)-limonene epoxide in mice after marble-burying test. |
已发布 PubMed:通过计算设计的库可快速稳定酶。 Computationally designed libraries for rapid enzyme stabilization. |
已发布 PubMed:等离子体等离子体质谱法研究臭氧引发的in烯反应产物 Study of ozone-initiated limonene reaction products by low temperature plasma ionization mass spectrometry. |
已发布 PubMed:天然化合物(+)-柠檬烯环氧化物对曼氏血吸虫的驱虫活性。 Anthelmintic activity of the natural compound (+)-limonene epoxide against Schistosoma mansoni. |
已发布 PubMed: 南非海狗(arctocephalus 脓杆菌 pusillus)对映体的嗅觉辨别能力。 |
已发布 PubMed:天然化合物(+)-柠檬烯环氧化物的急性毒性及其抗焦虑作用的评价。 Evaluation of acute toxicity of a natural compound (+)-limonene epoxide and its anxiolytic-like action. |
已发布 PubMed:芸苔的吲哚喹唑啉生物碱及其细胞毒活性 Indoloquinazoline alkaloids from Euodia rutaecarpa and their cytotoxic activities. |
已发布 PubMed:qm / mm酶法li烯1机理的研究 QM/MM study of the mechanism of enzymatic limonene 1,2-环氧水解。 2-epoxide hydrolysis. |
已发布 PubMed: (+)-环乙缩醛 -cymbodiacetal的全合成 : 对仿生路线的重新评估。 a re-evaluation of the biomimetic route. |
已发布 PubMed:鼠局部淋巴结试验评估肌成分的致敏性。 Evaluation of allergenicity of constituents of myoga using the murine local lymph node assay. |
已发布 PubMed:彻底评估常规对映体气相色谱法分析香橙精油中挥发性手性化合物的有效性 Thorough evaluation of the validity of conventional enantio-gas chromatography in the analysis of volatile chiral compounds in mandarin essential oil: 多维气相色谱的比较研究。 A comparative investigation with multidimensional gas chromatography. |
已发布 PubMed:手性萜烯的构象偏好 Conformational preference of a chiral terpene: 振动圆二色性(vcd) vibrational circular dichroism (VCD), s-(-)-柠檬烯氧化物的红外和拉曼研究。 infrared and Raman study of S-(-)-limonene oxide. |
已发布 PubMed:许多芳香植物中发现的单萜类似物的结构和解痉活性关系。 Structure and spasmolytic activity relationships of monoterpene analogues found in many aromatic plants. |
已发布 PubMed:针损伤对马尾松(马尾松)挥发物释放速率的影响。 Effect of needle damage on the release rate of Masson pine (Pinus massoniana) volatiles. |
已发布 PubMed:柠檬烯的杀螨活性 Acaricidal activity of limonene, 细头鼠(boophilus)微加 microplus上的氧化烯和β-氨基醇衍生物。 |
已发布 PubMed:含有柠檬烯的蛋白质和阿拉伯胶稳定的水包油乳液的化学和物理稳定性。 Chemical and physical stability of protein and gum arabic-stabilized oil-in-water emulsions containing limonene. |
已发布 PubMed:二十一种含氧单萜的抗菌活性的筛选。 Screening of antibacterial activities of twenty-one oxygenated monoterpenes. |
已发布 PubMed:臭氧和d-柠檬烯在活性炭上的异质反应 Heterogeneous reactions of ozone and D-limonene on activated carbon. |
已发布 PubMed:Rotundifolone结构类似物的抗伤害感受活性 Antinociceptive activity of structural analogues of rotundifolone: 构效关系。 structure-activity relationship. |
已发布 PubMed:十二烷基硫酸钠-壳聚糖和阿拉伯胶稳定的水包油乳液中柠檬醛和柠檬烯的化学和物理稳定性。 Chemical and physical stability of citral and limonene in sodium dodecyl sulfate-chitosan and gum arabic-stabilized oil-in-water emulsions. |
已发布 PubMed:利用急性皮肤刺激性试验和豚鼠最大化试验对肌肉中挥发性成分的毒性进行研究。 Toxicity study of the volatile constituents of Myoga utilizing acute dermal irritation assays and the Guinea-pig Maximization test. |
已发布 PubMed:柑桔冷榨果皮油的特征香气成分的评价 Evaluation of characteristic aroma compounds of Citrus natsudaidai Hayata (Natsudaidai) cold-pressed peel oil. |
已发布 PubMed:菌素基因在莫能菌素生物合成过程中在聚醚环形成中的作用的证据。 Evidence for the role of the monB genes in polyether ring formation during monensin biosynthesis. |
已发布 PubMed:蓝细菌对柠檬烯和柠檬烯进行立体选择性生物转化 Stereoselective biotransformation of limonene and limonene oxide by cyanobacterium, 球菌属pcc 7942。 Synechococcus sp. PCC 7942. |
已发布 PubMed:柠檬烯环氧水解酶的催化机理 Catalytic mechanism of limonene epoxide hydrolase, 理论研究。 a theoretical study. |
已发布 PubMed:结核分枝杆菌的非典型环氧化物水解酶的结构提供了对其功能的了解。 Structure of an atypical epoxide hydrolase from Mycobacterium tuberculosis gives insights into its function. |
已发布 PubMed:[不同化感水稻品种根系分泌物中的萜类化合物]。 [Terpenoids in root exudates of different allelopathic rice varieties]. |
已发布 PubMed:整合子相关的移动基因盒编码折叠蛋白 Integron-associated mobile gene cassettes code for folded proteins: bal32a的结构 the structure of Bal32a, 可适应的α alpha + beta beta桶系列的新成员。 |
已发布 PubMed:有机化合物乙酰乙酸乙酯(eaa)是乙酰乙酸乙酯。它主要用作各种化合物生产中的化学中间体 The number of functional olfactory receptor genes and the relative size of olfactory brain structures are poor predictors of olfactory discrimination performance with enantiomers. |
已发布 PubMed:环氧丙烷与二氧化碳的交替共聚。 Alternating copolymerization of limonene oxide and carbon dioxide. |
已发布 PubMed: 对手性中心具有异丙烯基的对映体的嗅觉辨别能力。 Olfactory discrimination ability of human subjects for enantiomers with an isopropenyl group at the chiral center. |
已发布 PubMed:利用云杉悬浮培养技术改造萜烯。 Transformation of terpenes using a Picea abies suspension culture. |
已发布 PubMed:用氧化的r-(+)-柠檬烯及其氢过氧化物馏分进行补丁测试。 Patch testing with oxidized R-(+)-limonene and its hydroperoxide fraction. |
已发布 PubMed:红球红球菌柠檬烯1的结构 Structure of Rhodococcus erythropolis limonene-1,2-环氧水解酶揭示了一个新的活性位点。 2-epoxide hydrolase reveals a novel active site. |
已发布 PubMed:使用spme和gc-ms测定柠檬烯氧化产物 Determination of limonene oxidation products using SPME and GC-MS. |
已发布 PubMed:氧萜烯作为氟哌啶醇从乙醇和丙二醇中 类皮肤渗透的增强剂及其对角质层的作用方式。 Oxide terpenes as human skin penetration enhancers of haloperidol from ethanol and propylene glycol and their modes of action on stratum corneum. |
已发布 PubMed: 贮藏条件对柑桔卷心菜组成的影响前田中(Hyuganatsu hyuganatsu)精油。 |
已发布 PubMed:柠檬烯和50%氧气的加合毒性以及谷胱甘肽在 肺细胞排毒中的作用。 Additive toxicity of limonene and 50% oxygen and the role of glutathione in detoxification in human lung cells. |
已发布 PubMed: f-344大鼠中叔丁醇与α alpha2u-球蛋白结合的特征。 |
已发布 PubMed:真菌对(r)-(+)-和(s)-(-)-柠檬烯的生物转化以及使用固相微萃取进行筛选。 Biotransformation of (R)-(+)- and (S)-(-)-limonene by fungi and the use of solid phase microextraction for screening. |
已发布 PubMed: 微型牛排植物(mosla 石竹 dianthera maxim)的香气活性化合物。 |
已发布 PubMed:甲基叔丁基醚与α2u-球蛋白在雄性f-344大鼠中的体内相互作用的评价。 Evaluation of the in vivo interaction of methyl tert-butyl ether with alpha2u-globulin in male F-344 rats. |
已发布 PubMed:红球红球菌dcl14包含柠檬烯的新型降解途径。 Rhodococcus erythropolis DCL14 contains a novel degradation pathway for limonene. |
已发布 PubMed:α2u-球蛋白的结构及其与透明液滴诱导剂的复合物。 The structures of alpha 2u-globulin and its complex with a hyaline droplet inducer. |
已发布 PubMed:红球红球菌dcl14柠檬烯-1 The Rhodococcus erythropolis DCL14 limonene-1,2-环氧水解酶基因编码一种属于新型环氧水解酶的酶。 2-epoxide hydrolase gene encodes an enzyme belonging to a novel class of epoxide hydrolases. |
已发布 PubMed:Limonene-1,来自红球红球菌dcl14的2-环氧水解酶属于一类新型的环氧水解酶。 2-epoxide hydrolase from Rhodococcus erythropolis DCL14 belongs to a novel class of epoxide hydrolases. |
已发布 PubMed:2-仲丁基-4 2-sec-butyl-4,5-二氢噻唑是小鼠尿蛋白和大鼠α2u-球蛋白的配体 5-dihydrothiazole is a ligand for mouse urinary protein and rat alpha 2u-globulin: 生理和毒理学意义。 physiological and toxicological relevance. |
已发布 PubMed:选定的单萜对甲烷氧化的影响 Effect of selected monoterpenes on methane oxidation, 反硝化 denitrification, 和纯培养中细菌的有氧代谢。 and aerobic metabolism by bacteria in pure culture. |
已发布 PubMed:雄性大鼠肾脏中甲基叔丁基醚的体外吸收 In vitro uptake of methyl tert-butyl ether in male rat kidney: 使用两室模型来描述蛋白质相互作用。 use of a two-compartment model to describe protein interactions. |
已发布 PubMed:从头角膜性角膜炎触角到新鲜的橙色空气挥发物的脑电图活动。 Electroantennogram activity from antennae ofCeratitis capitata (Wied.) to fresh orange airborne volatiles. |
已发布 PubMed:单萜体外抑制肿瘤细胞生长 Inhibition of tumor cell growth by monoterpenes in vitro: ras独立作用机制的证据。 evidence of a Ras-independent mechanism of action. |
已发布 PubMed:α2u-球蛋白是脂笼蛋白超家族中唯一与透明液滴诱导剂结合的成员。 Alpha 2u-globulin is the only member of the lipocalin protein superfamily that binds to hyaline droplet inducing agents. |
已发布 PubMed:d-柠檬烯(柑橘类溶剂)的空气氧化会产生强力过敏原。 Air oxidation of d-limonene (the citrus solvent) creates potent allergens. |
已发布 PubMed:小鼠抗透明液滴性肾病的生化基础 Biochemical basis for mouse resistance to hyaline droplet nephropathy: 在这种雄性大鼠特异性综合征中缺乏α2u-球蛋白超家族的相关性。 lack of relevance of the alpha 2u-globulin protein superfamily in this male rat-specific syndrome. |
已发布 PubMed:d-柠檬烯(柑橘类溶剂)的致敏性的动物实验。 Animal experiments on the allergenicity of d-limonene--the citrus solvent. |
已发布 PubMed:平行放射性和质谱检测的气相色谱仪的设计应用于鉴定与α2u-球蛋白有关的d-柠檬烯的主要代谢物。 Design of a gas chromatograph with parallel radioactivity and mass spectrometric detection. Application to the identification of the major metabolite of d-limonene associated with alpha 2u-globulin. |
已发布 PubMed:与2u-球蛋白的体外化学结合的特性-评价结构-活性关系。 Characteristics of chemical binding to alpha 2u-globulin in vitro--evaluating structure-activity relationships. |
已发布 PubMed:α2u-球蛋白和α2u-球蛋白-异生物共轭物的溶酶体降解。 Lysosomal degradation of alpha 2u-globulin and alpha 2u-globulin-xenobiotic conjugates. |
已发布 PubMed:柠檬烯1的代谢 Metabolism of limonene-1,大鼠中的2-环氧化物。 2-epoxide in the rat. |
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