类别 Category:flavoring agents
美国 US/欧盟 EU/ fda / jecfa / fema / Flavis / 文献 Scholar /专利 Patent :
物理性质 Physical Properties:
出现 Appearance: | 无色至浅黄澄清液体(est) colorless to pale yellow clear liquid (est) |
化验 Assay: | 95.00至100.00 95.00 to 100.00
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食品化学品法典列表 Food Chemicals Codex Listed: | No |
比重 Specific Gravity: | 1.01800 to 1.02400 @ 25.00 °C.
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磅每加仑-(est)。 Pounds per Gallon - (est).: | 8.471 to 8.521
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折光率 Refractive Index: | 1.51400 to 1.52000 @ 20.00 °C.
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熔点 Melting Point: | -69.00 °C. @ 760.00 mm 汞 Hg
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沸点 Boiling Point: | 115.00 °C. @ 760.00 mm 汞 Hg
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沸点 Boiling Point: | 114.00 °C. @ 738.00 mm 汞 Hg
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蒸汽压力 Vapor Pressure: | 23.782000 毫米汞柱 mm汞 Hg @ 25.00 °C. (est) |
闪点 Flash Point: | 52.00 °F. tcc TCC ( 11.11 °C. )
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logp(o / w) logP (o/w): | 2.340 |
溶于 Soluble in: |
| alcohol | | 水 water, 1188 mg/L @ 25 &deg °C (est) | | 水 water, 400 mg / l @ 25°C(实验) 400 mg/L @ 25 °C (exp) |
不溶于 Insoluble in: |
| 水 water |
感官特性 Organoleptic Properties:
风味类型 Flavor Type: fatty |
fatty winey |
口味描述 Taste Description: 高脂酒 fatty winey |
来自其他 的气味和/或风味描述(如果找到)。 Odor and/or flavor descriptions from others (if found). |
化妆品信息 Cosmetic Information:
供应商 Suppliers:
安全信息 Safety Information:
首选SDS Preferred SDS: 视图 View |
欧洲信息 European information : |
最重要的危害 Most important hazard(s): | xn-有害。 Xn - Harmful. |
R 11 - 高度 Highly 易燃的 flammable. R 20/22 - 有害 Harmful by by 吸入 inhalation and if 吞下 s壁 wallowe owed. S 02 - 保持 Keep out of the 达到 reach of 孩子们 children. S 07 - 保持 Keep 容器 container 紧紧 tightly 关闭 closed. S 16 - 保持 Keep 远 away from 资料来源 sources of 点火 ignition - No 抽烟 Smoking. S 24/25 - 避免 Avoid contact with skin 皮 and 眼睛 眼睛 eyes. S 26 - In 案件 case of contact with 眼睛 眼睛 eyes, 冲洗 rinse 立即 immediately with 充裕 plenty of 水 water and 寻求 看到 seek 医疗 medical 忠告 advice. S 29 - do Do not 空的 empty 进入 into 下水道 drains. S 33 - 采取 Take 预防措施 precautionary 措施 measures 反对 against 静态的 static 排出 discharge. S 36/37/39 - 穿 我们 Wear 适当 suitable 服装 clothing, 手套和眼睛/面部防护。 gloves and eye/face protection.
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危害识别 Hazards identification |
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物质或混合物的分类 Classification of the substance or mixture |
根据29 cfr 1910(osha hcs)进行ghs分类 GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
没有找到。 None found. |
ghs标签元素 GHS Label elements, 包括预防性声明 including precautionary statements |
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象形图 Pictogram | |
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危险说明 Hazard statement(s) |
没有找到。 None found. |
防范说明 Precautionary statement(s) |
没有找到。 None found. |
口服/肠胃外毒性 Oral/Parenteral Toxicity: |
未报告的哺乳动物 un已报告 reported-mammal (种类 species 未指定 unspecified) LD50 1600 mg/kg kg Gigiena i 萨尼塔利亚 Sanitariya. 对于 For 英语 English 翻译 translation, 见hysaav。卷51(5) see HYSAAV. Vol. 51(5), pg。 61 Pg. 61, 1986.
老鼠 oral-老鼠 mouse LD50 1800 mg/kg kg "有毒的 Toxicometric 参数 Parameters of 产业 Industrial 有毒的 Toxic Chemicals 下 Under 单 Single 接触 Exposure," 伊兹梅罗夫 Izmerov, n.f. N.F., 等。 et al., 莫斯科 Moscow, 国际项目中心 Centre of International Projects, k GKNT, 1982年-- 1982Vol. -, pg。 87 Pg. 87, 1982.
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皮肤毒性 Dermal Toxicity: |
未定 Not determined
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吸入毒性 Inhalation Toxicity: |
吸入哺乳动物 吸入 inhalation-mammal (种类 species 未指定 unspecified) LC50 18000 mg/m3 Gigiena i 萨尼塔利亚 Sanitariya. 对于 For 英语 English 翻译 translation, 见hysaav。卷51(5) see HYSAAV. Vol. 51(5), pg。 61 Pg. 61, 1986.
吸入小鼠 吸入 inhalation-老鼠 mouse LC50 18000 mg/m3/2H "有毒的 Toxicometric 参数 Parameters of 产业 Industrial 有毒的 Toxic Chemicals 下 Under 单 Single 接触 Exposure," 伊兹梅罗夫 Izmerov, n.f. N.F., 等。 et al., 莫斯科 Moscow, 国际项目中心 Centre of International Projects, k GKNT, 1982年-- 1982Vol. -, pg。 87 Pg. 87, 1982.
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使用安全信息 Safety in Use Information:
类别 Category: | flavoring agents |
推荐的3-甲基噻吩的使用水平不超过 Recommendation for 3-methyl thiophene usage levels up to: | | 不用于香水。 not for fragrance use.
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最大化源自调查的每日摄入量(msdi-eu) Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.12(微克/ 均/天) 0.12 (μg/capita/day) |
修改后的理论增加的最大每日摄入量(mtamdi) Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 78(微克/ /天) 78 (μg/person/day) |
关注点 Threshold of Concern: | 540(微克/ /天) 540 (μg/person/day) |
结构类 Structure Class: | ii II |
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根据委员会法规ec EC号的食品类别。 1565/2000(ec , 2000)在fge.06(efsa 2000) in FGE.06 (EFSA, 2002a). 根据 According to the 行业 Industry the "正常 normal" use is 定义的 de精细 fined as the 平均 average of 已报告 reported 用法 用法 usages and "最大 maximum use" is 定义的 de精细 fined as the 95th 百分位 percentile of 已报告 reported 用法 用法 usages (efsa EFSA, 2002i)。 2002i). |
注意 Note: 毫克/千克= 0.001 / 1000 = 0.000001 = 1/1000000 = 百万分之几 ppm |
| 平均 average 用法 usage mg/kg kg | 最大 maximum 用法 usage mg/kg kg |
乳制品 Dairy products, 不包括02.0(01.0)类产品 excluding products of category 02.0 (01.0): | 0.20000 | 1.00000 |
脂肪和油脂 Fats and oils, 和脂肪乳液(油包水型)(02.0) and fat emulsions (type water-in-oil) (02.0): | 0.10000 | 0.50000 |
食用冰 Edible ices, 包括果子露和果汁冰糕(03.0) including sherbet and sorbet (03.0): | 0.20000 | 1.00000 |
加工水果(04.1) Processed fruit (04.1): | 0.20000 | 1.00000 |
加工蔬菜(包括蘑菇和真菌) Processed vegetables (incl. mushrooms & fungi, 根与根块茎 roots & tubers, 豆类和豆类) pulses and legumes), 和坚果种子(04.2) and nuts & seeds (04.2): | - | - |
糖果(05.0) Confectionery (05.0): | 0.20000 | 1.00000 |
谷物和谷物产品 Cereals and cereal products, 含税面粉根和淀粉块茎 incl. flours & starches from roots & tubers, 脉冲和豆类 pulses & legumes, 不包括面包店(06.0) excluding bakery (06.0): | 0.10000 | 0.50000 |
烘焙用具(07.0) Bakery wares (07.0): | 0.20000 | 1.00000 |
肉和肉制品 Meat and meat products, 包括家禽和野味(08.0) including poultry and game (08.0): | 0.10000 | 0.20000 |
鱼和鱼制品 Fish and fish products, 包括软体动物 including molluscs, 甲壳类和棘皮类动物(麦克 MCE)(09.0) : | 0.10000 | 0.20000 |
鸡蛋和蛋制品(10.0) Eggs and egg products (10.0): | - | - |
甜味剂 Sweeteners, 包括蜂蜜(11.0) including honey (11.0): | - | - |
盐 Salts, 香料 spices, 汤类 soups, 酱料 sauces, 色拉 salads, 蛋白产品 protein products, 等(12.0) etc. (12.0): | 0.10000 | 0.50000 |
用于特定营养用途的食品(13.0) Foodstuffs intended for particular nutritional uses (13.0): | 0.20000 | 1.00000 |
不含醇 Non-alcoholic ("柔软的 soft") 饮料 beverages, 不包括乳制品(14.1) excl. dairy products (14.1): | 0.10000 | 0.50000 |
含醇的饮料 Alcoholic beverages, 含税无醇和低醇的对口(14.2) incl. alcohol-free and low-alcoholic counterparts (14.2): | 0.20000 | 1.00000 |
即食美味(15.0) Ready-to-eat savouries (15.0): | 0.40000 | 2.00000 |
复合食品(例如砂锅菜) Composite foods (e.g. casseroles, 肉馅饼 meat pies, 百果馅)-无法放在01.0-15.0(16.0)类别中的食物 mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 0.10000 | 0.50000 |
安全参考 Safety references:
欧洲食品安全法规(efsa) European Food Safety Athority(efsa):风味使用水平;亚急性 Flavor usage levels; Subacute, 亚慢性 Subchronic, 慢性和致癌性研究;发育/ 毒性研究;遗传毒性研究... Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
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欧洲食品安全局(efsa EFSA)参考 :
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调味组评估21 Flavouring Group Evaluation 21: 噻唑类 Thiazoles, thiophene, 来自化学组29的噻唑啉和噻吩衍生物;来自化学组30的 物质(委员会法规(ec)2000年7月18日第1565/2000号)-食品添加剂科学小组的意见 thiazoline and thienyl derivatives from chemical group 29. Miscellaneous substances from chemical group 30. (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, 调味料 Flavourings, 处理中 Processing 艾滋病 Aids and 材料 Materials in contact with Food (afc AFC) 视图 View page or 视图 View pdf
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调味组评估76 Flavouring Group Evaluation 76, (fge.76)[1]-考虑通过与结构上相关的噻唑的jecfa(第五十九次会议)评估的含硫杂环化合物 (FGE.76)[1] - Consideration of sulphur-containing heterocyclic compounds evaluated by JECFA (59th meeting) structurally related to thiazoles, thiophene, 来自化学组29的噻唑啉和噻吩衍生物 thiazoline and thienyl derivatives from chemical group 29, efsa EFSA在fge.21中评估了化学30组的其他杂物-食品添加剂专家组的科学观点 , 调味料 Flavourings, 处理中 Processing 艾滋病 Aids and 材料 Materials in 联系 Contact with Food 视图 View page or 视图 View pdf
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调味组评估21 Flavouring Group Evaluation 21, 修订版1(fge.21rev1) Revision 1 (FGE.21Rev1): 噻唑类 Thiazoles, thiophene, 来自化学组29的噻唑啉和噻吩衍生物 thiazoline and thienyl derivatives from chemical group 29 杂 Miscellaneous 物质 substances from chemical group 30 视图 View page or 视图 View pdf
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调味组评估93(fge.93) Flavouring Group Evaluation 93 (FGE.93): jecfa(第六十八次会议)评估的与噻唑结构相关的硫杂环的考虑 Consideration of sulphur heterocyclic evaluated by JECFA (68th meeting) structurally related to thiazoles, thiophene, 噻唑啉 thiazoline and 噻吩基 thienyl 已评估 evaluated by by efsa EFSA in ge FGE.21Rev1 (2009) 视图 View page or 视图 View pdf
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调味品组评价的科学见解21 Scientific Opinion on Flavouring Group Evaluation 21, 版本2(fge.21rev2) Revision 2 (FGE.21Rev2): 噻唑类 Thiazoles, thiophene, 来自化学组29的噻唑啉和噻吩衍生物 thiazoline and thienyl derivatives from chemical group 29. 杂 Miscellaneous 物质 substances from chemical group 30. 视图 View page or 视图 View pdf
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调味品组评价的科学见解21 Scientific Opinion on Flavouring Group Evaluation 21, 版本3(fge.21rev3) Revision 3 (FGE.21Rev3): 噻唑类 Thiazoles, thiophenes, 噻唑啉 thiazoline and 噻吩基 thienyl 衍生品 derivatives from chemical 团体 groups 29 and 30 视图 View page or 视图 View pdf
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关于代表性测试物质清单的声明。 Statement on List of Representative Substances for Testing.
The 当前 current 声明 Statement 奠定 lays 下 down a list of 物质 substances in 亚组 sub-团体 groups with 代表 re当下 presentative 物质 substances for 哪一个 which 额外 加成 additional data are required 事前 prior to their 评价 evaluation 通过 through the 程序 Procedure (规 Regulation (ec EC) No 1565/2000). 视图 View page or 视图 View pdf
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调味品组评价的科学见解21 Scientific Opinion on Flavouring Group Evaluation 21, 修订版4(fge.21rev4) Revision 4 (FGE.21Rev4): 噻唑类 Thiazoles, thiophenes, 噻唑啉 thiazoline and 噻吩基 thienyl 衍生品 derivatives from chemical 团体 groups 29 and 30 视图 View page or 视图 View pdf
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调味品组评价的科学见解21 Scientific Opinion on Flavouring Group Evaluation 21, 版本5(fge.21rev5) Revision 5 (FGE.21Rev5): 噻唑类 Thiazoles, thiophenes, 噻唑啉 thiazoline and 噻吩基 thienyl 衍生品 derivatives from chemical 团体 groups 29 and 30 视图 View page or 视图 View pdf
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Epi系统 EPI System: 视图 View |
化学致癌研究信息系统 Chemical Carcinogenesis Research Information System:搜索 Search |
环境诱变信息中央 Env. Mutagen Info. Center:搜索 Search |
EPA物质注册服务(tsca TSCA) :616-44-4 |
EPA ACToR:毒理学资料 Toxicology Data |
EPA物质注册服务(SRS) :注册表 Registry |
实验室化学安全摘要 Laboratory Chemical Safety Summary :12024 |
国家过敏和传染病研究所 National Institute of Allergy and Infectious Diseases:数据 Data |
明智的 WISER:1993年 UN 1993 |
德国wgk WGK Germany:3 |
3-methylthiophene |
chemidplus Chemidplus:0000616444 |
技术 RTECS:适用于CAS#616-44-4的xm9800000 XM9800000 for cas# 616-44-4 |
参考资料 References:
| 3-methylthiophene |
NIST化学网络书籍 NIST Chemistry WebBook: | 搜索INCHI |
加拿大国内分公司。清单 Canada Domestic Sub. List: | 616-44-4 |
pubchem(cid) Pubchem (cid): | 12024 |
pubchem(sid) Pubchem (sid): | 134977870 |
其他资料 Other Information:
潜在搅拌机 Potential Blenders and core 组件 components note
潜在用途 Potential Uses:
存在(自然 Occurrence (nature, food, 其他) other): note
同义词 Synonyms:
beta- | methyl thiophene | 3- | methylthiophene | | thiophene, 3-甲基 3-methyl- | 3- | thiotolene |
文章 Articles:
美国专利 US Patents:3,931,166-某些2 166 - Certain 2,5-二甲基-3-硫代吡嗪 5-dimethyl-3-thiopyrazines |
已发布 PubMed:聚噻吩薄膜从超疏水性到超亲水性的电响应可逆转变。 Electro-responsively reversible transition of polythiophene films from superhydrophobicity to superhydrophilicity. |
已发布 PubMed:红 Red, 绿 green, 蓝色(rgb)电致变色纤维,用于新型智能变色织物。 blue (RGB) electrochromic fibers for the new smart color change fabrics. |
已发布 PubMed:使用选择性试剂电离飞行时间质谱仪获得的no(+)与一些生理上显着的挥发性有机硫和有机硒化合物反应的产物离子分布。 Product ion distributions for the reactions of NO(+) with some physiologically significant volatile organosulfur and organoselenium compounds obtained using a selective reagent ionization time-of-flight mass spectrometer. |
已发布 PubMed:选择性测定Fe 3+离子的聚合物膜电极和涂层石墨电极的结构和性能特点。 Construction and performance characteristics of polymeric membrane electrode and coated graphite electrode for the selective determination of Fe³⁺ ion. |
已发布 PubMed:聚(3-烷基噻吩)单链扭转紊乱的理论研究 Theoretical study of torsional disorder in poly(3-alkylthiophene) single chains: 分子内电荷转移特性及其对光伏性能的影响。 intramolecular charge-transfer character and implications for photovoltaic properties. |
已发布 PubMed:带有漆酶的聚(3-甲基噻吩)薄膜基于从聚合物到漆酶的直接电子转移进行生物电催化o(2)还原。 Bioelectrocatalytic O(2) reduction with a laccase-bearing poly(3-methylthiophene) film based on direct electron transfer from the polymer to laccase. |
已发布 PubMed:聚(3-甲基噻吩)/石墨烯复合材料 Poly(3-methylthiophene)/graphene composite: 原位合成及其电化学表征。 in-situ synthesis and its electrochemical characterization. |
已发布 PubMed:表面引发的聚(3-甲基噻吩)作为高性能聚合物太阳能电池的空穴传输层。 Surface-initiated poly(3-methylthiophene) as a hole-transport layer for polymer solar cells with high performance. |
已发布 PubMed:合成和评估含两个羰基的水泡乙酰胆碱转运蛋白抑制剂的体外生物活性 Synthesis and evaluation of in vitro bioactivity for vesicular acetylcholine transporter inhibitors containing two carbonyl groups. |
已发布 PubMed:对桉树次生化合物的敏感性不同,解释了通过普通的环尾(pseudocheirus peregrinus)和普通的刷尾负鼠(trichosurus vulpecula)进食。 Development of novel molecularly imprinted solid-phase microextraction fibers and their application for the determination of antibiotic drugs in biological samples by SPME-LC/MS(n). |
已发布 PubMed:现场控制 Site-controlled 应用 application of 电动 electric 潜在 potential on a 进行 conduc锡 ting 聚合物 polymer "帆布 canvas". |
已发布 PubMed:锡铟氧化物表面引发的聚(3-甲基噻吩)合成及其电化学性能。 Surface-initiated synthesis of poly(3-methylthiophene) from indium tin oxide and its electrochemical properties. |
已发布 PubMed:和超声波对牛奶中微生物质量和香气活性成分的影响 Effects of ultraviolet light and ultrasound on microbial quality and aroma-active components of milk. |
已发布 PubMed: 修饰的纳菲 Nafion /单壁碳纳米管/聚(3-甲基噻吩)玻璃碳电极表面上存在抗坏血酸和尿酸情况下,电化学选择性测定多巴胺。 |
已发布 PubMed:表面限制的镍介导的交叉偶联反应 Surface-confined nickel mediated cross-coupling reactions: 田田催化剂转移缩聚反应中引发剂环境的表征 characterization of initiator environment in Kumada catalyst-transfer polycondensation. |
已发布 PubMed:聚(3-烷基噻吩) Poly(3-alkylthiophenes): 用于从 血浆中分离药物的固相微萃取的新型吸附材料。 new sorption materials for solid phase microextraction of drugs isolated from human plasma. |
已发布 PubMed:对猪油对半胱氨酸与木糖的美拉德反应形成挥发物的影响。 Effects of lard on the formation of volatiles from the Maillard reaction of cysteine with xylose. |
已发布 PubMed:借助双极电化学方法对导电聚合物薄膜进行梯度掺杂。 Gradient doping of conducting polymer films by means of bipolar electrochemistry. |
已发布 PubMed:使用发光聚合物单纳米线进行dna检测。 DNA detection using a light-emitting polymer single nanowire. |
已发布 PubMed:噻吩和甲基噻吩在沥青质中的热解机理 Pyrolysis mechanisms of thiophene and methylthiophene in asphaltenes. |
已发布 PubMed:无保护基的脱氮杂二胺合成 A protecting group-free synthesis of deazathiamine: 抑制剂设计的一步。 a step toward inhibitor design. |
已发布 PubMed:电聚合的给体-受体低带隙共轭共聚物的还原和氧化掺杂动力学。 Reduction and oxidation doping kinetics of an electropolymerized donor-acceptor low-bandgap conjugated copolymer. |
已发布 PubMed:聚合物的发光彩色条码纳米线 Light-emitting color barcode nanowires using polymers: 纳米级光学特性。 nanoscale optical characteristics. |
已发布 PubMed:谷胱甘肽与还原糖之间的美拉德反应中形成的芳香活性化合物的研究。 Investigation of the aroma-active compounds formed in the maillard reaction between glutathione and reducing sugars. |
已发布 PubMed:聚(3-甲基噻吩)/钯亚微修饰传感器电极。第二Poly(3-methylthiophene)/palladium sub-micro-modified sensor electrode. Part II: 伏安法和eis EIS研究 , 儿茶酚胺橙花递质的分析 and analysis of catecholamine neurotransmitters, 抗坏血酸和对乙酰氨基酚。 ascorbic acid and acetaminophen. |
已发布 PubMed:铜包覆的发光聚(3-甲基噻吩)杂化纳米管的光致发光特性 Photoluminescence characteristics for hybrid nanotubes of light emitting poly(3-methylthiophene) coated with copper: 荧光作用。 fluorescence effect. |
已发布 PubMed:对3-甲基噻吩和3-己基噻吩的共聚物进行p-掺杂的原位esr / uv-vis-nir和atr-ftir光谱电化学研究。 In situ ESR/UV-vis-NIR and ATR-FTIR spectroelectrochemical studies on the p-doping of copolymers of 3-methylthiophene and 3-hexylthiophene. |
已发布 PubMed:顶空固相微萃取-气相色谱和偏最小二乘预测巴西阿拉比卡咖啡烘焙咖啡的感官特性。 Prediction of sensory properties of Brazilian Arabica roasted coffees by headspace solid phase microextraction-gas chromatography and partial least squares. |
已发布 PubMed:使用聚(3-甲基噻吩)/金纳米粒子复合材料修饰的玻璃碳电极灵敏地测定多巴胺和尿酸。 Sensitive determination of dopamine and uric acid by the use of a glassy carbon electrode modified with poly(3-methylthiophene)/gold nanoparticle composites. |
已发布 PubMed:聚3-甲基噻吩改性的声凝胶-碳电极上的伏安法测定痕量汞。 Voltammetric determination of trace mercury at a sonogel-carbon electrode modified with poly-3-methylthiophene. |
已发布 PubMed:伏安法在聚(3-甲基噻吩)电极上检测磺酰胺。 Voltammetric detection of sulfonamides at a poly(3-methylthiophene) electrode. |
已发布 PubMed:导电聚合物离子传感器电极-iii。电位硫化物离子选择电极。 Conducting polymer ion sensor electrodes-III. Potentiometric sulfide ion selective electrode. |
已发布 PubMed:研究和比较了一些有机和生物分子在各种导电聚合物电极上的电化学行为。 Investigation and comparison of the electrochemical behavior of some organic and biological molecules at various conducting polymer electrodes. |
已发布 PubMed:取代噻吩的c-s键氧化加成(c5me5)rh(pme3)片段的选择性 Selectivity in the oxidative addition of C-S bonds of substituted thiophenes to the (C5Me5)Rh(PMe3) fragment: 理论与实验的比较。 a comparison of theory with experiment. |
已发布 PubMed:饮食中的二乙炔草丁二醇可诱导2相药物代谢酶,并通过抑制脂质过氧化作用来阻断四氯化碳对小鼠的肝毒性。 Development of potential manufacturing routes for substituted thiophenes--preparation of halogenated 2-thiophenecarboxylic acid derivatives as building blocks for a new family of 2,6-二卤代芳基1 6-dihaloaryl 1,2,4-三唑杀虫剂。 4-triazole insecticides. |
已发布 PubMed:气相色谱-硫化学发光检测法测定焦化汽油中硫化合物的分布 [Determination and distribution of sulfur compounds in coked gasoline by gas chromatography-sulfur chemiluminescence detection]. |
已发布 PubMed:通过定向锂化对3-甲基噻吩进行高度选择性的5-取代。 Highly selective 5-substitution of 3-methylthiophene via directed lithiation. |
已发布 PubMed:3-甲基噻吩/吡咯对对dna小沟的识别。 DNA minor-groove recognition by 3-methylthiophene/pyrrole pair. |
已发布 PubMed:导电聚合物的电化学39.导电聚合物与贵金属纳米颗粒之间的接触通过电流感应原子力显微镜研究。 Electrochemistry of conductive polymers 39. Contacts between conducting polymers and noble metal nanoparticles studied by current-sensing atomic force microscopy. |
已发布 PubMed:声学乳化技术开发水不溶性单体在水性电解质中的新型环保电聚合方法。 Development of a novel environmentally friendly electropolymerization of water-insoluble monomers in aqueous electrolytes using acoustic emulsification. |
已发布 PubMed:微生物印迹聚吡咯/聚(3-甲基噻吩)复合膜用于细菌内生芽孢杆菌的检测。 Microbial imprinted polypyrrole/poly(3-methylthiophene) composite films for the detection of Bacillus endospores. |
已发布 PubMed:在平面和纳米粒子au表面上的3-甲基噻吩自组装单层。 3-methylthiophene self-assembled monolayers on planar and nanoparticle Au surfaces. |
已发布 PubMed:电化学的 Electrochemical 性能 performance of 8-hydroxy-2'-deoxyguanosine and its its 检测 detection at poly(3-methylthiophene) 改性 modified 玻璃状 glassy carbon 电极 electrode. |
已发布 PubMed:使用nafion /碳纳米管涂覆的聚(3-甲基噻吩)修饰电极对多巴胺进行高选择性和灵敏的测定。 Highly selective and sensitive determination of dopamine using a Nafion/carbon nanotubes coated poly(3-methylthiophene) modified electrode. |
已发布 PubMed:一种新型的3--3-甲基噻吩-γ-环糊精薄膜的电化学合成方法,用于氯丙嗪和某些橙花递质的分析。 A novel electrochemical synthesis of poly-3-methylthiophene-gamma-cyclodextrin film Application for the analysis of chlorpromazine and some neurotransmitters. |
已发布 PubMed:用硫化学发光检测器气相色谱法测定流化催化裂化汽油中的硫化合物 [Determination of sulfur compounds in fluid catalytic cracking gasoline by gas chromatography with a sulfur chemiluminescence detector]. |
已发布 PubMed:单层光伏器件中电化学沉积的聚(3-甲基噻吩)性能。 Electrochemically deposited poly(3-methylthiophene) performance in single layer photovoltaic devices. |
已发布 PubMed:固态超分子组织 Solid-state supramolecular organization, 直接根据粉末衍射数据建立 established directly from powder diffraction data, 核寡聚噻吩-s的合成和光致发光效率 and photoluminescence efficiency of rigid-core oligothiophene-S,二氧化硫。 S-dioxides. |
已发布 PubMed:用于低浓度测量的全固态钙溶剂聚合物膜电极。 All-solid-state calcium solvent polymeric membrane electrode for low-level concentration measurements. |
已发布 PubMed:嗜热苯并噻吩降解分枝杆菌sp的分离和鉴定。 Isolation and characterization of thermophilic benzothiophene-degrading Mycobacterium sp. |
已发布 PubMed:聚合物修饰电极,可用于安培生物传感器内可逆氧化还原nad + / nadh。 Polymer modified electrodes for the reversible oxidation-reduction of NAD+/NADH for use within amperometric biosensors. |
已发布 PubMed:厚度剪切模式谐振器表面上粘弹性薄膜的贴合唯一性问题。 The problem of uniqueness of fit for viscoelastic films on thickness-shear mode resonator surfaces. |
已发布 PubMed:顶空固相微萃取-气相色谱-脉冲火焰光度检测法测定啤酒中的硫化物 Determination of sulphur compounds in beer using headspace solid-phase microextraction and gas chromatographic analysis with pulsed flame photometric detection. |
已发布 PubMed:胶体中的甲基噻吩异构体的表面增强拉曼光谱研究。 Surface Enhanced Raman Spectroscopic Study of Isomeric Methylthiophenes in Silver Colloid. |
已发布 PubMed:导电聚合物电极在中性水溶液中的氧的电位响应。 Potentiometric response of conducting polymer electrodes for oxygen in neutral aqueous solutions. |
已发布 PubMed:掺杂clo4的聚(3-甲基噻吩)压片中热历史依赖的转变。 Thermal-history-dependent transition in pressed pellets of ClO4--doped poly(3-methylthiophene). |
已发布 PubMed:导电聚合物互连的制造。 Fabrication of conducting polymer interconnects. |
已发布 PubMed:聚(3-辛基噻吩)的电位响应 Potentiometric response of poly(3-octylthiophene), 水溶液中的聚(3-甲基噻吩)和聚噻吩。 poly(3-methylthiophene) and polythiophene in aqueous solutions. |
已发布 PubMed:电化学和导电的聚(3-甲基噻吩)电极上某些有机和生物分子的检测。 Electrochemistry and detection of some organic and biological molecules at conducting poly(3-methylthiophene) electrodes. |
已发布 PubMed:聚(3-甲基噻吩)涂层玻璃碳电极上酚类化合物的高度稳定的伏安测量。 Highly stable voltammetric measurements of phenolic compounds at poly(3-methylthiophene)-coated glassy carbon electrodes. |
已发布 PubMed:聚(3-甲基噻吩)中的双极化子 Bipolarons in poly(3-methylthiophene): 光谱的 Spectroscopic, 磁性 magnetic, 和电化学测量。 and electrochemical measurements. |
已发布 PubMed:通过近边缘X射线吸收精细结构光谱研究,对掺杂在pt电极上的聚(3-甲基噻吩)的pi和sigma带进行掺杂后的分子演化。 Evolution upon doping of the pi and sigma bands of poly-(3-methylthiophene) grafted on Pt electrodes as studied by near-edge x-ray-absorption fine-structure spectroscopy. |
已发布 PubMed:掺杂和未掺杂电聚合聚(3-甲基噻吩)薄膜固有的π键能带和类似金属的行为的证据。 Evidence of intrinsic extended pi -bonding band and metalliclike behavior in undoped and doped electropolymerized poly(3-methylthiophene) films. |
已发布 PubMed:3-烷基呋喃在小鼠肝脏和肾脏中的毒性-分布关系。 Toxicity-distribution relationships among 3-alkylfurans in mouse liver and kidney. |
已发布 PubMed:小鼠肺中3-烷基呋喃的毒性-分布关系。 Toxicity-distribution relationships among 3-alkylfurans in the mouse lung. |
已发布 PubMed:金属取代碳酸酐酶 Metal substitutions incarbonic anhydrase: 卤离子探针研究。 a halide ion probe study. |
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