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类别 Category:information only not used for fragrances or flavors
美国 US/欧盟 EU/ fda / jecfa / fema / Flavis / 文献 Scholar /专利 Patent :
物理性质 Physical Properties:
| 出现 Appearance: | 无色至浅黄透明液体至固体（est） colorless to pale yellow clear liquid to solid (est) |
| 化验 Assay: | 96.00至100.00 96.00 to 100.00
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| 食品化学品法典列表 Food Chemicals Codex Listed: | No |
| 比重 Specific Gravity: | 1.26500 @ 25.00 °C.
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| 熔点 Melting Point: | 14.00 to 16.00 °C. @ 760.00 mm 汞 Hg
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| 沸点 Boiling Point: | 49.00 to 51.00 °C. @ 760.00 mm 汞 Hg
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| 蒸汽压力 Vapor Pressure: | 255.000000 毫米汞柱 mm汞 Hg @ 25.00 °C. (est) |
| 闪点 Flash Point: | 24.00 °F. tcc TCC ( -4.30 °C. ) (est)
|
| logp（o / w） logP (o/w): | -0.549（est） -0.549 (est) |
| 保质期 Shelf Life: | 如果正确存放，则为12.00个月或更长时间。 12.00 month(s) or longer if stored properly. |
| 存储 Storage: | 在密封容器中冷藏。 refrigerate in tightly sealed containers. |
| 溶于 Soluble in: |
| | alcohol | | | 水 water, 1000000 mg / l @ 20°C（实验） 1000000 mg/L @ 20 °C (exp) |
感官特性 Organoleptic Properties:
| 气味强度 Odor Strength:低 low |
| 气味描述 Odor Description:at 100.00 %. 轻度 mild sour |
| 来自其他 的气味和/或风味描述（如果找到）。 Odor and/or flavor descriptions from others (if found). |
化妆品信息 Cosmetic Information:
供应商 Suppliers:
| 巴斯夫 BASF |
| 乙二醛40％ Glyoxal 40%
气味 Odor: characteristic 采用 Use: 乙二醛表现出广泛的活性 Glyoxal shows a wide range of activities, 例如作为通用的交联剂 e.g. as a versatile crosslinker, 作为有机合成的中间体 as an intermediate for organic syntheses, 作为杀菌剂 as a biocide, 并作为各种亲核试剂的清除剂。 and as a scavenger for a diverse range of nucleophiles. |
| BOC Sciences |
| 仅供实验/研究使用。 For experimental / research use only. |
| 草甘膦> 98％ Glyfosfin >98%
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| 共价化学 Covalent Chemical |
| Glyoxal
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| Emd 微孔 Millipore |
| 仅供实验/研究使用。 For experimental / research use only. |
| Glyoxal
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| Penta International |
| 乙二醛40％溶胶。在水里 GLYOXAL 40% SOL. IN WATER
|
| 圣克鲁斯生物技术 Santa Cruz Biotechnology |
| 仅供实验/研究使用。 For experimental / research use only. |
| Glyoxal, 40％溶液 40 % Solution
|
| 西格玛·奥尔德里奇 Sigma-Aldrich |
| 仅供实验/研究使用。 For experimental / research use only. |
| 乙二醛溶液40 wt。水百分比 Glyoxal solution 40 wt. % in H2O
|
| 银蕨化学 Silver Fern Chemical |
| 乙二醛40 Glyoxal 40
气味 Odor: characteristic 采用 Use: 乙二醛连接多种聚合物 Glyoxal links a wide range of polymers, 例如淀粉 e.g. starch, 纤维素 cellulose, 蛋白质物质 proteinaceous material, 聚丙烯酰胺 polyacrylamide, 聚乙烯醇。 polyvinyl alcohols. |
| 环球防腐化学公司 Universal Preserv-A-Chem Inc. |
| 乙二醛 Ethanedial, 草醛 Oxalaldehyde
气味 Odor: characteristic 采用 Use: 用作聚合物化学中的增溶剂和交联剂 Is used as a solubilizer and cross-linking agent in polymer chemistry for: 蛋白质（皮革鞣制过程） proteins (leather tanning process), 胶原 collagen, 纤维素衍生物（纺织品） cellulose derivatives (textiles), 水胶体 hydrocolloids, 和淀粉（纸涂料）。 and starch (paper coatings). |
安全信息 Safety Information:
| 首选SDS Preferred SDS: 视图 View |
| 欧洲信息 European information : |
| 最重要的危害 Most important hazard(s): | | xn-有害。 Xn - Harmful. |
R 20 - 有害 Harmful by by 吸入 inhalation.
R 36/38 - 烦 的 Irritating to skin 皮 and 眼睛 eyes.
R 43 - 可以 May 原因 cause 敏化 sensitisation by by skin 皮 contact.
R 68 - 可能 Possible risk of 不可逆的 irreversible 效果 影响 effects.
S 02 - 保持 Keep out of the 达到 reach of 孩子们 children.
S 20/21 - 什么时候 When 使用 using do not eat, 喝 drink or 抽烟 smoke.
S 23 - do Do not 呼吸 breath 烟气 fumes.
S 24/25 - 避免 Avoid contact with skin 皮 and 眼睛 eyes.
S 26 - In 案件 case of contact with 眼睛 eyes, 冲洗 rinse 立即 immediately with 充裕 plenty of 水 water and 寻求 seek 医疗 medical 忠告 advice.
S 36/37 - 穿 Wear 适当 suitable 保护性 protective 服装 clothing and 手套 gloves.
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| 危害识别 Hazards identification |
| |
| 物质或混合物的分类 Classification of the substance or mixture |
| 根据29 cfr 1910（osha hcs）进行ghs分类 GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| 没有找到。 None found. |
| ghs标签元素 GHS Label elements, 包括预防性声明 including precautionary statements |
| |
| 象形图 Pictogram | |
| |
| 危险说明 Hazard statement(s) |
| 没有找到。 None found. |
| 防范说明 Precautionary statement(s) |
| 没有找到。 None found. |
| 口服/肠胃外毒性 Oral/Parenteral Toxicity: |
几内亚口服 口服 oral-guinea 猪 pig LD50 760 mg/kg
行为的 BEHAVIORAL: 嗜睡（一般抑郁活动） SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
胃肠道 GASTROINTESTINAL: 其他变化 OTHER CHANGES
Journal of 产业 Industrial 卫生 Hygiene and Toxicology. 卷 Vol. 23, pg。 259 Pg. 259, 1941.
几内亚口服 口服 oral-guinea 猪 pig LD50 > 10000 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0538086
腹腔内小鼠 intra腹膜的 peritoneal-mouse LD50 200 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. AD438-895
老鼠 口服 oral-mouse LD50 400 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. AD438-895
老鼠 口服 oral-mouse LD50 1280 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0538086
静脉兔子 intravenous-rabbit LD50 60 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535072
口服兔子 口服 oral-rabbit LD50 > 3175 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0538086
口鼠 口服 oral-rat LD50 4290 mg/kg
Union 碳化物 Carbide Data 片 Sheet. 卷 Vol. 11/4/1971
口鼠 口服 oral-rat LD50 2960 mg/kg
肺 LUNGS, 胸部 THORAX, 或呼吸 OR RESPIRATION: 呼吸抑制 RESPIRATORY DEPRESSION
行为的 BEHAVIORAL: 嗜睡（一般抑郁活动） SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535124
口鼠 口服 oral-rat LD50 200 mg/kg
行为的 BEHAVIORAL: 肌肉 MUSCLE WEAKNESS
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0533618
静脉狗 intravenous-dog ldlo 低密度脂蛋白 LDLo 300 ul uL/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535072
几内亚口服 口服 oral-guinea 猪 pig LD50 10000 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0538086
老鼠 口服 oral-mouse LD50 400 mg/kg
行为的 BEHAVIORAL: 肌肉 MUSCLE WEAKNESS
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0533618
腹腔内兔子 intra腹膜的 peritoneal-rabbit LD50 60 mg/kg
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535072
腹膜内大鼠 intra腹膜的 peritoneal-rat ldlo 低密度脂蛋白 LDLo 100 mg/kg
国民 National 学院 Academy of Sciences, 国家研究委员会 National Research Council, 化学生物协调中心 Chemical-Biological Coordination Center, 评论。卷5 Review. Vol. 5, pg。 9 Pg. 9, 1953.
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| 皮肤毒性 Dermal Toxicity: |
几内亚皮肤病 skin 皮-guinea 猪 pig LD50 6600 mg/kg
"Toxicology of 毒品 Drugs and 化学药品 Chemicals," 德希曼 Deichmann, w.b. W.B., 纽约 New York, 学术出版社 Academic Press, 公司 Inc., 1969卷-- 1969Vol. -, pg。 291 Pg. 291, 1969.
皮肤兔子 skin 皮-rabbit LD50 10 ml/kg
LIVER: 其他变化 OTHER CHANGES
肺 LUNGS, 胸部 THORAX, 或呼吸 OR RESPIRATION: 急性肺水肿 ACUTE PULMONARY EDEMA
肾 KIDNEY, 输尿管 URETER, 和膀胱 AND BLADDER: "肾小管改变（包括急性肾衰竭） CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, 急性 ACUTE 管状的 TUBULAR 坏死 NEcro CROSIS)"
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535072
皮肤兔子 skin 皮-rabbit LD50 10 ml/kg
Union 碳化物 Carbide Data 片 Sheet. 卷 Vol. 11/4/1971
皮鼠 skin 皮-rat LD50 > 2000 mg/kg
皮肤 SKin IN and AND 附属物 APPEND年龄 AGES (皮肤 SKin IN): "皮炎 DERMATITIS, 其他 Other: 后 AFTER 系统的 SYSTEMIC EXPOSURE"
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535506
皮肤兔子 skin 皮-rabbit LD50 10 ml/kg
LIVER: 其他变化 OTHER CHANGES
肺 LUNGS, 胸部 THORAX, 或呼吸 OR RESPIRATION: 急性肺水肿 ACUTE PULMONARY EDEMA
肾 KIDNEY, 输尿管 URETER, 和膀胱 AND BLADDER: "肾小管改变（包括急性肾衰竭） CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, 急性 ACUTE 管状的 TUBULAR 坏死 NEcro CROSIS)"
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535072
皮肤兔子 skin 皮-rabbit LD50 10 毫升 mL/kg
Union 碳化物 Carbide Data 片 Sheet. 卷 Vol. 11/12/1965
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| 吸入毒性 Inhalation Toxicity: |
吸入大鼠 吸入 inhalation-rat LC50 2410 mg/m3/4H
SENSE 器官 ORGANS and AND 特别 SPECIAL 感官 SENSES: 其他变化 OTHER CHANGES: 嗅觉 OLFACTION
肺 LUNGS, 胸部 THORAX, 或呼吸 OR RESPIRATION: DYSPNEA
国民 National 技术 Technical 信息 Information 服务 Service. 卷 Vol. OTS0535127
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使用安全信息 Safety in Use Information:
| 类别 Category: | | information only not used for fragrances or flavors |
| 乙二醛用量建议 Recommendation for glyoxal usage levels up to: | | | 不用于香水。 not for fragrance use.
|
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| 乙二醛风味使用水平的推荐值 Recommendation for glyoxal flavor usage levels up to: |
| | 不用于调味料。 not for flavor use.
|
安全参考 Safety references:
参考资料 References:
| | 乙醛 oxaldehyde |
| NIST化学网络书籍 NIST Chemistry WebBook: | 搜索INCHI |
| 加拿大国内分公司。清单 Canada Domestic Sub. List: | 107-22-2 |
| pubchem（cid） Pubchem (cid): | 7860 |
| pubchem（sid） Pubchem (sid): | 134972262 |
其他资料 Other Information:
| （iupac） (IUPAC): | 元素的原子量2009 Atomic Weights of the Elements 2009 |
| （iupac） (IUPAC): | 元素的原子量2009（pdf） Atomic Weights of the Elements 2009 (pdf) |
| 影片 Videos: | 元素周期表 The Periodic Table of Videos |
| RBC : | 本网站使用的原子量 Atomic Weights use for this web site |
| （iupac） (IUPAC): | 元素周期表 Periodic Table of the Elements |
| 用于食品接触物质的fda间接添加剂 FDA Indirect Additives used in Food Contact Substances: | 视图 View |
| CHEBI: | 视图 View |
| CHEMBL: | 视图 View |
| KEGG (GenomeNet): | C14448 |
| hmdb（人类代谢组数据库） HMDB (The Human Metabolome Database): | 搜索 Search |
| 食物 FooDB: | FDB007802 |
| 出口关税代码 Export Tariff Code: | 2912.19.3000 |
| 雾度图 Haz-Map: | 视图 View |
| vcf在线 VCF-Online: | 食品中的挥发性有机化合物 VCF Volatile Compounds in Food |
| 化学蜘蛛 ChemSpider: | 视图 View |
| 维基百科 Wikipedia: | 视图 View |
| rsc学习化学 RSC Learn Chemistry: | 视图 View |
配方/制剂 Formulations/Preparations:
＆bull;无水形式的结晶二水合物 •commercially available in anhydrous form as crystalline dihydrate, 或以40％的水溶液形式包含聚合抑制剂。二水合物 or as a 40% aqueous solution which may contain polymerization inhibitors. dihydrate
＆bull;等级 •grades: 40％溶液；纯 40% solution; pure, 固体; solid; vp.
乙二醛是一种以30％的水溶液形式商业出售的二醛 •glyoxal is a dialdehyde supplied commercially as 30% aqueous solution, 由单体和溶剂的混合物组成聚合物水合物以及少量杂质使溶液呈酸性。 consisting of mixture of monomeric & polymeric hydrates along with small amounts of impurities which render the solution acid.
＆bull;乙二醛可以在平面顺式和反式构象之间进行旋转异构化 •glyoxal can undertake rotational isomerization between the planar cis and trans conformations, 反式乙二醛是更稳定的异构体。 with trans-glyoxal being the more stable isomer.
官方软膏基质是聚乙二醇4000和400的混合物。该基质是水溶性的，不染色。当需要更牢固的制备时，可以用等量的聚乙二醇4000代替不超过10％的聚乙二醇400。 •...it is generally employed as an aqueous solutionin which hydrated oligomers are present due to nucleophilic addition. ...some of the most important hydrated derivatives of glyoxal formed by nucleophilic addition in aqueous solutioninclude the monomer ethane-1,1,2,2-四醇（i） 2-tetraol (i), 二聚体2-二羟甲基-（1 the dimer 2-dihydroxymethyl-(1,3）二氧戊环-4 3)dioxolane-4, 5-反式二醇（ii ii） , 和三聚体双（二氧戊环）（即 and the trimer bis(dioxolane) (i.e., 2,2'-bi-1 2'-bi-1,3-二氧戊环基-4 3-dioxolanyl-4,4',5, 5'-四醇）（ii iii ii iii）-顺式和反式构型。然而 , 不同结构的比例随浓度和pH值而变化。 the proportion of the different structures varies with concentration and ph.
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潜在搅拌机 Potential Blenders and core 组件 components note
潜在用途 Potential Uses:
存在（自然 Occurrence (nature, food, 其他） other): note
同义词 Synonyms:
| | 形式的 diformal | | | 手工 ethandial | | | ethane dial | | | ethane-1,2-dial | | | ethanedial | | | ethanedione | | 1,2- | ethanedione | | | 明胶醇 gelifundol | | | glyoxal aldehyde | | | 乙醛 glyoxylaldehyde | | | oxalaldehyde | | | 乙醛 oxaldehyde |
文章 Articles:
| 已发布 PubMed:末端氨基酸对美拉德模型系统中由肽形成吡嗪的影响。 Impact of the N-terminal amino acid on the formation of pyrazines from peptides in Maillard model systems. |
| 阶段 J-Stage:萜烯氢过氧化物裂解α-二羰基化合物 Cleavage of a-Dicarbonyl Compounds by Terpene Hydroperoxide |
| 已发布 PubMed:自动化和定量的顶空管内萃取，用于准确测定葡萄酒和啤酒中的高挥发性化合物。 Automated and quantitative headspace in-tube extraction for the accurate determination of highly volatile compounds from wines and beers. |
| 已发布 PubMed:3-氨基-4的热生成 Thermal generation of 3-amino-4,5-二甲基呋喃-2（5h）-一 5-dimethylfuran-2(5H)-one, 假定的索托隆前体 the postulated precursor of sotolone, 来自包含乙醛酸和丙酮酸氨基酸模型系统。 from amino acid model systems containing glyoxylic and pyruvic acids. |
| 已发布 PubMed:含赖氨酸二肽的美拉德模型系统中形成吡嗪。 Formation of pyrazines in Maillard model systems of lysine-containing dipeptides. |
| 已发布 PubMed:葡萄糖降解 Degradation of glucose: 重新研究反应性α-二羰基化合物。 reinvestigation of reactive alpha-Dicarbonyl compounds. |
| 已发布 PubMed:α-二羰基化合物-形成基于碳水化合物的黑素的关键中间体 alpha-Dicarbonyl compounds--key intermediates for the formation of carbohydrate-based melanoidins. |
| 已发布 PubMed:氨基酸和羰基化合物在温和条件下的反应形成风味成分。 Formation of flavor components by the reaction of amino acid and carbonyl compounds in mild conditions. |
| 已发布 PubMed:抗氧化能力的测定 Determination of Antioxidant Capacities, α-二羰基 α-Dicarbonyls, hplc-dad-esi-ms在佛罗里达州的蜂蜜中使用酚和酚类植物化学物质（n。） and Phenolic Phytochemicals in Florida Varietal Honeys using HPLC-DAD-ESI-MS(n.) |
| 已发布 PubMed:液相色谱-电喷雾电离质谱联用技术研究婴儿食品中的α-二羰基化合物 Investigation of α-Dicarbonyl Compounds in Baby Foods by High-Performance Liquid Chromatography Coupled with Electrospray Ionization Mass Spectrometry. |
| 已发布 PubMed:甲基乙二醛与高果糖龙舌兰糖浆的抑菌活性有关。 Methylglyoxal is associated with bacteriostatic activity of high fructose agave syrups. |
| 已发布 PubMed:腹膜透析液中α-二羰基葡萄糖降解产物的生理反应性的结构和浓度特异性评估。 Structure- and Concentration-Specific Assessment of the Physiological Reactivity of α-Dicarbonyl Glucose Degradation Products in Peritoneal Dialysis Fluids. |
| 已发布 PubMed:咖啡中的游离α-二羰基化合物 Free α-dicarbonyl compounds in coffee, 大麦咖啡和酱油具有体外消化作用。 barley coffee and soy sauce and effects of in vitro digestion. |
| 已发布 PubMed:碳水化合物降解系统中苯甲酰蛋氨酸氧化的模型研究。 Model Studies on the Oxidation of Benzoyl Methionine in a Carbohydrate Degradation System. |
| 已发布 PubMed:煮沸期间在肽-葡萄糖混合物中产生的精氨酸衍生的高级糖基化终产物。 Arginine-derived advanced glycation end products generated in peptide-glucose mixtures during boiling. |
| 已发布 PubMed:高效液相色谱法测定乙二醛 High-performance liquid chromatography determination of glyoxal, 甲基乙二醛 methylglyoxal, 使用4-甲氧基-邻-苯二胺作为衍生试剂测定尿液中的二乙酰基。 and diacetyl in urine using 4-methoxy-o-phenylenediamine as derivatizing reagent. |
| 已发布 PubMed:外源性因子对gsh的调节导致暴露于慢性醇加高葡萄糖的vl-17a细胞中的乙二醛酶1酶活性变化。 Modulation of GSH with exogenous agents leads to changes in glyoxalase 1 enzyme activity in VL-17A cells exposed to chronic alcohol plus high glucose. |
| 已发布 PubMed:美拉德反应模型系统中脂质诱导的羟基自由基促进了饮食中n（ε）-羧甲基赖氨酸形成。 Hydroxyl radical induced by lipid in Maillard reaction model system promotes diet-derived N(ε)-carboxymethyllysine formation. |
| 已发布 PubMed:中国工业场所的有害空气中羰基化合物的有害排放。 Hazardous airborne carbonyls emissions in industrial workplaces in China. |
| 已发布 PubMed:食品中的高级糖基化终产物及其对健康的影响。 Advanced glycation endproducts in food and their effects on health. |
| 已发布 PubMed:形成4（5）-甲基咪唑及其前体 Formation of 4(5)-methylimidazole and its precursors, α-二羰基化合物 α-dicarbonyl compounds, 在美拉德模型系统中。 in Maillard model systems. |
| 已发布 PubMed:α-二羰基化合物的细胞毒性作用于体外模拟消化过程。 Cytotoxicity of α-dicarbonyl compounds submitted to in vitro simulated digestion process. |
| 已发布 PubMed:响应面法作为通过酚类化学方法减少食品中活性羰基物质的优化策略。 Response surface methodology as optimization strategy for reduction of reactive carbonyl species in foods by means of phenolic chemistry. |
| 已发布 PubMed:蜂胶诱导棉纺织品的抗菌活性和其他技术性能。 Propolis induced antibacterial activity and other technical properties of cotton textiles. |
| 已发布 PubMed: 秀丽隐杆 的djr-1.2是由处于dauer dauer状态的daf-16诱导的。 |
| 已发布 PubMed:焙烧引起的阿拉伯三糖变化 Roasting-induced changes in arabinotriose, 咖啡阿拉伯半乳聚糖侧链的模型。 a model of coffee arabinogalactan side chains. |
| 已发布 PubMed:消化对香醋中游离α-二羰基化合物的影响 Effect of in vitro digestion on free α-dicarbonyl compounds in balsamic vinegars. |
| 已发布 PubMed:uhplc-dad-ms / ms对碳酸软饮料中具有α-二羰基结构的糖降解产物进行分析 Analysis of sugar degradation products with α-dicarbonyl structure in carbonated soft drinks by UHPLC-DAD-MS/MS. |
| 已发布 PubMed:有毒α-二羰基化合物的测定 Determination of toxic α-dicarbonyl compounds, glyoxal, 甲基乙二醛 methylglyoxal, 和二乙酰 and diacetyl, 通过热处理释放到脂质商品的顶部空间。 released to the headspace of lipid commodities upon heat treatment. |
| 已发布 PubMed:三聚氰胺与糖和类似糖的化合物的非酶促糖基化作用。 Non-enzymatic glycation of melamine with sugars and sugar like compounds. |
| 已发布 PubMed:2的双席夫碱加合物 Double Schiff base adducts of 2,3-丁二酮与甘氨酸 3-butanedione with glycine: 氨基酸碳原子参与形成吡嗪环。 formation of pyrazine rings with the participation of amino acid carbon atoms. |
| 已发布 PubMed:少量的活性羰基化合物作为组织脂质氧化产物；以及它们的形成机理。 Small reactive carbonyl compounds as tissue lipid oxidation products; and the mechanisms of their formation thereby. |
| 已发布 PubMed:酚化合物对美拉德反应中吡嗪鎓自由基生成机理的影响。 Influence of phenolic compounds on the mechanisms of pyrazinium radical generation in the Maillard reaction. |
| 已发布 PubMed:甲基乙二醛和乙二醛的风味化学。 Flavour chemistry of methylglyoxal and glyoxal. |
| 已发布 PubMed:末端氨基酸对美拉德模型系统中由肽形成吡嗪的影响。 Impact of the N-terminal amino acid on the formation of pyrazines from peptides in Maillard model systems. |
| 已发布 PubMed:1的调查 Survey of 1,不同花卉来源的商业蜂蜜中的2-二羰基化合物。 2-dicarbonyl compounds in commercial honey of different floral origin. |
| 已发布 PubMed:鉴定和定量高果糖玉米糖浆中的六种主要α-二羰基工艺污染物。 Identification and quantification of six major α-dicarbonyl process contaminants in high-fructose corn syrup. |
| 已发布 PubMed:咖啡滤液的作用 Effect of coffee filtrate, 甲基乙二醛 methylglyoxal, glyoxal, 和咖啡因鼠 歐洲海濱草和s。肠鸡在地面鸡胸中的存活率。 and caffeine on Salmonella typhimurium and S. enteritidis survival in ground chicken breasts. |
| 已发布 PubMed: 来自褐藻（海藻（fucus vesiculosus））的环戊单宁通过清除活性羰基来抑制高级糖基化终产物的形成。 |
| 已发布 PubMed:实验动物模型中印度淡水珍珠贻贝的抗氧化剂含量和活性，以预防节螺藻。 Antioxidant content and activity of the Indian fresh-water pearl mussel in the prevention of arthritis in an experimental animal model. |
| 已发布 PubMed:腹膜透析中葡萄糖降解产物的化学和生理相关性。 Chemical and physiological relevance of glucose degradation products in peritoneal dialysis. |
| 已发布 PubMed:多步超高效液相色谱/串联质谱分析，可用于糖化活性的无目标定量和鉴定最相关的糖化产物。 Multistep ultrahigh performance liquid chromatography/tandem mass spectrometry analysis for untargeted quantification of glycating activity and identification of most relevant glycation products. |
| 已发布 PubMed:生物解毒活性作为罗伊氏乳杆菌益生菌特性的潜力。 The potential of biodetoxification activity as a probiotic property of Lactobacillus reuteri. |
| 已发布 PubMed:活性聚乙烯醇/β-环糊精复合材料的开发以清除不良食品成分。 Development of active polyvinyl alcohol/β-cyclodextrin composites to scavenge undesirable food components. |
| 已发布 PubMed:肽的化学修饰及其对食品特性的影响。 Chemical modifications of peptides and their impact on food properties. |
| 已发布 PubMed:蔓越莓植物化学物质通过清除活性羰基来抑制 血红蛋白和血清白蛋白的糖基化。 Cranberry phytochemicals inhibit glycation of human hemoglobin and serum albumin by scavenging reactive carbonyls. |
| 已发布 PubMed:微生物氧化酶催化乙醇醛转化为乙二醛。 Microbial oxidases catalyzing conversion of glycolaldehyde into glyoxal. |
| 已发布 PubMed:通过uhplc / dad / msms对腹膜透析液中的六种主要α-二羰基污染物进行定量分析。 Quantification of the six major α-dicarbonyl contaminants in peritoneal dialysis fluids by UHPLC/DAD/MSMS. |
| 已发布 PubMed:味觉调节的肌酐和还原性碳水化合物形成的n-（1-甲基-4-氧代咪唑啉丁-2-亚基）α-氨基酸。 Taste modulating N-(1-methyl-4-oxoimidazolidin-2-ylidene) α-amino acids formed from creatinine and reducing carbohydrates. |
| 已发布 PubMed:3-氨基-4的热生成 Thermal generation of 3-amino-4,5-二甲基呋喃-2（5h）-一 5-dimethylfuran-2(5H)-one, 假定的索托隆前体 the postulated precursor of sotolone, 来自包含乙醛酸和丙酮酸氨基酸模型系统。 from amino acid model systems containing glyoxylic and pyruvic acids. |
| 已发布 PubMed:糖尿病和动脉粥样硬化中的脂质糖基化和蛋白质糖基化。 Lipid glycation and protein glycation in diabetes and atherosclerosis. |
| 已发布 PubMed:3-脱氧半乳糖酮 3-deoxygalactosone, a "new" 1,乳制品中的2-二羰基化合物。 2-dicarbonyl compound in milk products. |
| 已发布 PubMed:羰基化合物甲基乙二醛和乙二醛通过产生超氧阴离子和激活mapk p38来影响肠道细胞中白介素8的分泌。 Carbonyl compounds methylglyoxal and glyoxal affect interleukin-8 secretion in intestinal cells by superoxide anion generation and activation of MAPK p38. |
| 已发布 PubMed:与乙二醛和乙醇醛反应对明胶膜进行化学和纹理修饰的模型研究。 Model studies on chemical and textural modifications in gelatin films by reaction with glyoxal and glycolaldehyde. |
| 已发布 PubMed:含赖氨酸二肽的美拉德模型系统中形成吡嗪。 Formation of pyrazines in Maillard model systems of lysine-containing dipeptides. |
| 已发布 PubMed:量化 Quantification of N2-羧甲基 carboxymethyl-2'-deoxyguanosine in 小牛 calf thymus 脱氧核糖核酸 DNA and 养成的 cultured 的 human 肾 kidney 上皮的 epithelial 细胞 细胞 cells by by capillary 高性能的 高 high-性能 performance 液体 liquid 色谱串联 色谱法 chromatography-串联 tandem mass 光谱法 spectrometry 耦合的 coupled with 稳定 stable 同位素 isotope 稀释 dilution method. |
| 已发布 PubMed:谷胱甘肽在乙末端与乙二醛反应。 Glutathione reacts with glyoxal at the N-terminal. |
| 已发布 PubMed:不同植物来源的商业蜂蜜的α-二羰基含量分布图 Profiling of alpha-dicarbonyl content of commercial honeys from different botanical origins: 鉴定3 identification of 3,4-二脱氧葡萄糖苷-3-烯（3 4-dideoxyglucoson-3-ene (3,4-dge）和相关化合物。 4-DGE) and related compounds. |
| 已发布 PubMed:同位素标记研究的起源3 Isotope labeling studies on the origin of 3,4-己二酮和1 4-hexanedione and 1,丙氨酸/葡萄糖模型系统中的2-丁二酮。 2-butanedione in an alanine/glucose model system. |
| 已发布 PubMed:葡萄糖降解 Degradation of glucose: 重新研究反应性α-二羰基化合物。 reinvestigation of reactive alpha-Dicarbonyl compounds. |
| 已发布 PubMed:食物衍生的羰基化合物会影响caco-2细胞中明串球菌介素6和-8的基础分泌和刺激分泌。 Food derived carbonyl compounds affect basal and stimulated secretion of interleukin-6 and -8 in Caco-2 cells. |
| 已发布 PubMed:开发和验证hplc方法以量化3 Development and validation of an HPLC method to quantify 3,腹膜透析液中的4-dideoxyglucosone-3-ene。 4-dideoxyglucosone-3-ene in peritoneal dialysis fluids. |
| 已发布 PubMed:预处理和交联剂影响的基于猪血浆蛋白的薄膜的特性 Characterization of porcine plasma protein-based films as affected by pretreatment and cross-linking agents. |
| 已发布 PubMed: 基于乙二醛双（2-羟基茴香醚）的铬（ii iii ii iii）离子选择电极 |
| 已发布 PubMed:在线分析鉴定和监测丙烯酰胺途径中的中间体和产物。 Identification and monitoring of intermediates and products in the acrylamide pathway using online analysis. |
| 已发布 PubMed:含有天冬酰胺的模型系统中丙烯酰胺和吡嗪的形成。 Acrylamide and pyrazine formation in model systems containing asparagine. |
| 已发布 PubMed:口服糖毒素决定热量限制对氧化应激的影响 Oral glycotoxins determine the effects of calorie restriction on oxidant stress, 与年龄有关的疾病 age-related diseases, 和寿命。 and lifespan. |
| 已发布 PubMed:甲基乙二醛 methylglyoxal: 它的存在和潜在的清除剂。 its presence and potential scavengers. |
| 已发布 PubMed:酪蛋白-nε-（羧甲基）赖氨酸和nε-（羧甲基）赖氨酸在caco-2细胞中诱导热休克蛋白和蛋白酶体系统。 Induction of heat shock proteins and the proteasome system by casein-N epsilon-(carboxymethyl)lysine and N epsilon-(carboxymethyl)lysine in Caco-2 cells. |
| 已发布 PubMed:α-二羰基化合物-形成基于碳水化合物的黑素的关键中间体 alpha-Dicarbonyl compounds--key intermediates for the formation of carbohydrate-based melanoidins. |
| 已发布 PubMed:甲基乙二醛 methylglyoxal: 它在饮料和潜在的清除剂中的存在。 its presence in beverages and potential scavengers. |
| 已发布 PubMed:食品及相关系统中ε-（羧甲基）赖氨酸含量测定 Determination of N epsilon-(carboxymethyl)lysine in foods and related systems. |
| 已发布 PubMed:使用9-（3）的激光解吸/电离质谱快速分析α-二羰基化合物 Rapid analysis of alpha-dicarbonyl compounds by laser desorption/ionization mass spectrometry using 9-(3,以4-二氨基苯基）ac啶（daa）为反应基质。 4-diaminophenyl)acridine (DAA) as a reactive matrix. |
| 已发布 PubMed:甲基乙二醛作为新西兰麦卢卡蜂蜜的主要抗菌成分的鉴定和定量分析。 Identification and quantification of methylglyoxal as the dominant antibacterial constituent of Manuka (Leptospermum scoparium) honeys from New Zealand. |
| 已发布 PubMed:隔离 Isolation, 鉴定 identification, 和烘焙咖啡抗菌化合物的定量。 and quantification of roasted coffee antibacterial compounds. |
| 已发布 PubMed:同时测定酮酸和二羰基化合物 Simultaneous determination of ketoacids and dicarbonyl compounds, 美拉德关键中间体，对陈年葡萄酒产生香气。 key Maillard intermediates on the generation of aged wine aroma. |
| 已发布 PubMed:rp-hplc-dad在绿和烘焙咖啡中分离和测定α-二羰基化合物。 Isolation and determination of alpha-dicarbonyl compounds by RP-HPLC-DAD in green and roasted coffee. |
| 已发布 PubMed:防止羰基应激诱导的细胞死亡 Preventing cell death induced by carbonyl stress, 氧化应激或线粒体毒素与维生素B抗衰老剂。 oxidative stress or mitochondrial toxins with vitamin B anti-AGE agents. |
| 已发布 PubMed:番石榴叶水提物对 脐静脉内皮细胞（huvec）模型阐明的抗凋亡分子机制 Molecular action mechanism against apoptosis by aqueous extract from guava budding leaves elucidated with human umbilical vein endothelial cell (HUVEC) model. |
| 已发布 PubMed:搅拌棒吸附萃取-原位衍生化法测定环境和生物基质中的乙二醛和甲基乙二醛 Determination of glyoxal and methylglyoxal in environmental and biological matrices by stir bar sorptive extraction with in-situ derivatization. |
| 已发布 PubMed:在含水葡萄糖/甘氨酸模型系统中黄烷-3-醇对产物生成的结构-反应性关系。 Structure-reactivity relationships of flavan-3-ols on product generation in aqueous glucose/glycine model systems. |
| 已发布 PubMed:通过超高温欧姆加热减少腹膜透析液中葡萄糖降解产物的形成。 Reducing the formation of glucose degradation products in peritoneal dialysis solutions by ultrahigh temperature ohmic heating. |
| 已发布 PubMed:铜催化的抗坏血酸氧化导致乙二醛/年龄的形成和细胞毒性。 Copper-catalyzed ascorbate oxidation results in glyoxal/AGE formation and cytotoxicity. |
| 已发布 PubMed:研究碳酸氢铵对模型体系中丙烯酰胺形成的促进作用。 Investigations on the promoting effect of ammonium hydrogencarbonate on the formation of acrylamide in model systems. |
| 已发布 PubMed:小麦蛋白质基天然聚合物的化学修饰 Chemical modification of wheat protein-based natural polymers: 交联对机械性能和相结构的影响。 cross-linking effect on mechanical properties and phase structures. |
| 已发布 PubMed:在模拟的生理条件下捕获活性羰基物质与茶多酚的反应。 Trapping reactions of reactive carbonyl species with tea polyphenols in simulated physiological conditions. |
| 已发布 PubMed:水美拉德体系中的表儿茶素羰基捕集反应 Epicatechin carbonyl-trapping reactions in aqueous maillard systems: 鉴定和结构阐明。 Identification and structural elucidation. |
| 已发布 PubMed:香港商业烹饪来源的羰基排放。 Carbonyl emissions from commercial cooking sources in Hong Kong. |
| 已发布 PubMed:化学交联的麦醇溶蛋白的膜的开发和表征。 Development and characterization of films based on chemically cross-linked gliadins. |
| 已发布 PubMed:某些营养食品药草对葡萄糖和乙二醛诱导的ldl糖基化的抑制作用。 Inhibitory effect of some selected nutraceutic herbs on LDL glycation induced by glucose and glyoxal. |
| 已发布 PubMed:可溶性酿酒酵母加工α-葡萄糖苷酶的结合残基和催化结构域 Binding residues and catalytic domain of soluble Saccharomyces cerevisiae processing alpha-glucosidase I. |
| 已发布 PubMed:不同氧化应激条件下晚期糖基化终产物和羰基化合物的评估 Evaluation of advanced glycation end products and carbonyl compounds in patients with different conditions of oxidative stress. |
| 已发布 PubMed:腹膜透析过程中葡萄糖降解产物3-deoxyglucosone和乙二醛的命运。 Fate of the glucose degradation products 3-deoxyglucosone and glyoxal during peritoneal dialysis. |
| 已发布 PubMed:氧化后在食用油中形成遗传毒性二羰基化合物。 Formation of genotoxic dicarbonyl compounds in dietary oils upon oxidation. |
| 已发布 PubMed:含致癌性二羰基化合物的氧化膳食油在c3h / hen小鼠体内引起肝脏癌变和形成8-羟基-脱氧鸟苷。 Liver carcinogenesis and formation of 8-hydroxy-deoxyguanosine in C3H/HeN mice by oxidized dietary oils containing carcinogenic dicarbonyl compounds. |
| 已发布 PubMed:n-末端吡嗪酮 N-Terminal pyrazinones: 一类新型的肽结合高级糖基化终产物。 a new class of peptide-bound advanced glycation end-products. |
| 已发布 PubMed:美拉德反应和酶促褐变影响pru av 1的致敏性 Maillard reaction and enzymatic browning affect the allergenicity of Pru av 1, 樱桃的主要变应原。 the major allergen from cherry (Prunus avium). |
| 已发布 PubMed:烟酰胺的水性光解。 Aqueous photolysis of niclosamide. |
| 已发布 PubMed:宠物瓶中储存的矿泉水中的乙醛污染。 Aldehyde contamination of mineral water stored in PET bottles. |
| 已发布 PubMed:乙二醛/乙醛 Glyoxal/glycolaldehyde: 酒的苹果酸乳酸发酵涉及的氧化还原系统。 a redox system involved in malolactic fermentation of wine. |
| 已发布 PubMed:棉籽蛋白与甲醛交联的化学反应 Chemical reactions in cottonseed protein cross-linking by formaldehyde, 戊二醛 glutaraldehyde, 和乙二醛用于形成具有增强的机械性能的蛋白质膜。 and glyoxal for the formation of protein films with enhanced mechanical properties. |
| 已发布 PubMed:酰胺是由生理糖形成的新型蛋白质修饰。 Amides are novel protein modifications formed by physiological sugars. |
| 已发布 PubMed:精氨酸赖氨酸交联反应的鉴定与定量评价 Identification and quantitative evaluation of the lysine-arginine crosslinks GODIC, 莫迪奇 MODIC, 多义的 DODIC, 和食物中的葡萄糖潘。 and glucosepan in foods. |
| 已发布 PubMed:乙二醛精氨酸修饰的分离和表征。 Isolation and characterization of glyoxal-arginine modifications. |
| 已发布 PubMed:氨基酸和羰基化合物在温和条件下的反应形成风味成分。 Formation of flavor components by the reaction of amino acid and carbonyl compounds in mild conditions. |
| 已发布 PubMed:羰基化合物在结晶化葡萄的葡萄汁和葡萄酒的so（2）结合现象中的作用。 Role of carbonyl compounds in SO(2) binding phenomena in musts and wines from botrytized grapes. |
| 已发布 PubMed:正甲基硫脲参与的证据 Evidence for the involvement of N-methylthiourea, 环状裂解代谢物 a ring cleavage metabolite, 谷胱甘肽枯竭小鼠中甲巯咪唑对肝毒性的影响 in the hepatotoxicity of methimazole in glutathione-depleted mice: 结构毒性和代谢研究。 structure-toxicity and metabolic studies. |
| 已发布 PubMed:斯特雷克型反应形成芳香活性醛和酸定量模型研究。 Quantitative model studies on the formation of aroma-active aldehydes and acids by strecker-type reactions. |
| 已发布 PubMed:丙烯醛作为脂质过氧化产物的现状。 Current status of acrolein as a lipid peroxidation product. |
| 已发布 PubMed:研究碳水化合物和氨基酸非酶褐变反应早期的自由基中间体。 Studies on radical intermediates in the early stage of the nonenzymatic browning reaction of carbohydrates and amino acids. |
| 已发布 PubMed:歐洲海濱草hisg428 cher石还原剂的分子分析，可快速表征突变特异性。 Molecular analysis of Salmonella hisG428 ochre revertants for rapid characterization of mutational specificity. |
| 已发布 PubMed:中期肝脏生物测定中咖啡及其相关化合物潜在的致癌性分析。 Analysis of the potential carcinogenicity of coffee and its related compounds in a medium-term liver bioassay of rats. |
| 已发布 PubMed:抑制性的 Inhibitory 影响 effect of 2"-o-糖基 -O-glycosyl 异维亭 isovitexin and α-生育酚 alpha-tocopherol on 遗传毒性 geno有毒的 toxic glyoxal formation in a lipid 过氧化 per氧化 oxidation 系统 system. |
| 已发布 PubMed:肉类诱变剂形成和抑制的机制。 Mechanism(s) involved in meat mutagen formation and inhibition. |
| 已发布 PubMed:乙二醛通过饮用水对大鼠的亚慢性口腔毒性。 Subchronic oral toxicity of glyoxal via drinking water in rats. |
| 已发布 PubMed:分光光度法测定食品中的铜。 Spectrophotometric determination of copper in foods, 饲料和植物 feedingstuffs and plants: 乙二醛双（4-苯基-3-硫代半脲）和浴铜素二磺酸盐方法的比较。 a comparison between the glyoxal bis(4-phenyl-3-thiosemicarbazone) and bathocuproine disulphonate methods. |
| 已发布 PubMed:霉菌中2-氧醛的代谢。黑曲霉中两种甲基乙二醛还原酶的纯化和表征。 Metabolism of 2-oxoaldehyde in mold. Purification and characterization of two methylglyoxal reductases from Aspergillus niger. |
| 已发布 PubMed:九种咖啡对鼠 歐洲海濱草ta100的致突变性Comparative mutagenicity of nine brands of coffee to Salmonella typhimurium TA100, ta102 TA102, 和ta104。 and TA104. |
| 已发布 PubMed:α-二羰基和α-羟基羰基化合物对诱变杂环胺的致突变作用。 Desmutagenic effect of alpha-dicarbonyl and alpha-hydroxycarbonyl compounds against mutagenic heterocyclic amines. |
| 已发布 PubMed:通过加热的葡萄糖和氧自由基形成剂在c-8位的核苷和dna中的鸟嘌呤进行羟化。 Hydroxylation of guanine in nucleosides and DNA at the C-8 position by heated glucose and oxygen radical-forming agents. |
| 已发布 PubMed:食物中的诱变剂和致癌物。 Mutagens and carcinogens in foods. |
| 已发布 PubMed:亚硫酸盐抑制咖啡的诱变特性。 Sulfite suppresses the mutagenic property of coffee. |
| 已发布 PubMed:丙二醛对亚硝胺形成的影响 Effect of malondialdehyde on nitrosamine formation. |
| 已发布 PubMed:从经过脱落化学处理的水果中提取的精制橙油新化合物。 Compounds new to essential orange oil from fruit treated with abscission chemicals. |
| 已发布 PubMed:氨基酸和多肽对金刚烷化合物的氧化褐变。 Oxidative browning of Amadori compounds from amino acids and peptides. |
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