4-甲苯磺酸 4-toluene sulfonic acids
苯磺酸 benzenesulfonic acid, 4-甲基-(1 4-methyl- (1:1:1)

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    对甲苯磺酸(ptsa) p-Toluene Sulphonic Acid (PTSA)
CAS号 CAS Number: 104-15-4Picture of molecule3D/INCHI
其他 Other:100901-72-2
ECHA einecs Ein INec ECS - REACH 预注册 Pre-Reg:203-419-9
FDA UNII:QGV5ZG5741
nikkaji网站 Nikkaji Web:J5.025C
贝尔斯坦数 Beilstein Number:0472690
XlogP3:1.70(est) 1.70 (est)
分子量 Molecular Weight:171.19539000
式 Formula:c7 h7 o3 s C7 H7 O3 S
生物活性总结 BioActivity Summary:清单 listing
核磁共振预测器 NMR Predictor:预测(适用于Chrome或Firefox) Predict (works with chrome or firefox)
类别 Category:hydrotrope, surfactant agents
 
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fda mainterm(iaufc) FDA Mainterm (IAUFC):104-15-4 ; 4-METHYLBENZENESULFONIC ACID

 
物理性质 Physical Properties:
化验 Assay: 95.00至100.00 95.00 to 100.00
食品化学品法典列表 Food Chemicals Codex Listed: No
熔点 Melting Point: 104.50 °C. @ 760.00 mm 汞 Hg
闪点 Flash Point: 32.00 °F. tcc TCC ( 0.00 °C. ) (est)
logp(o / w) logP (o/w): 0.930(est) 0.930 (est)
溶于 Soluble in:
 水 water, 2.023e+005 mg/L @ 25 &deg °C (est)
 水 water, 6.20e + 05 mg / l @ 25°C(实验值) 6.20E+05 mg/L @ 25 °C (exp)
 
感官特性 Organoleptic Properties:
来自其他 的气味和/或风味描述(如果找到)。 Odor and/or flavor descriptions from others (if found).
 
化妆品信息 Cosmetic Information:
CosIng:化妆品数据 cosmetic data
化妆品用途 Cosmetic Uses: 水溶 hydrotropics
表面活性剂 surfactants
 
供应商 Suppliers:
OQEMA
对甲苯磺酸(ptsa) p-Toluene Sulphonic Acid (PTSA)
圣克鲁斯生物技术 Santa Cruz Biotechnology
仅供实验/研究使用。 For experimental / research use only.
对甲苯磺酸≥98% p-Toluenesulfonic acid ≥98%
西格玛·奥尔德里奇 Sigma-Aldrich
仅供实验/研究使用。 For experimental / research use only.
对甲苯磺酸一水合物ACS试剂 , ≥98.5%
斯蒂芬公司 Stepan Company
STEPANATE® PTSA 65-E
斯蒂芬公司 Stepan Company
STEPANATE® PTSA-C
斯蒂芬公司 Stepan Company
STEPANATE® PTSA-C99
 
安全信息 Safety Information:
首选sds SDS : 视图 View
 
危害识别 Hazards identification
 
物质或混合物的分类 Classification of the substance or mixture
根据29 cfr 1910(osha hcs)进行ghs分类 GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
没有找到。 None found.
ghs标签元素 GHS Label elements, 包括预防性声明 including precautionary statements
 
象形图 Pictogram
 
危险说明 Hazard statement(s)
没有找到。 None found.
防范说明 Precautionary statement(s)
没有找到。 None found.
口服/肠胃外毒性 Oral/Parenteral Toxicity:
鹌鹑 口服 oral-quail LD50 > 316 mg/kg
Ecotoxicology and 环境的 环保 Env铁 ironmental 安全 Safety. 卷 Vol. 6, pg。 149 Pg. 149, 1982.

口鼠 口服 oral-rat LD50 2480 mg/kg
"Prehled 恶作剧 Prumyslove 毒物学 Toxikologie; 有机酮 有机 Organicke 懒汉 Latky," 马尔霍尔德 Marhold, j. J., 布拉格 Prague, 捷克斯洛伐克 Czechoslovakia, 香橙 Avicenum, 1986卷-- 1986Vol. -, pg. 1055 Pg. 1055, 1986.

皮肤毒性 Dermal Toxicity:
未定 Not determined
吸入毒性 Inhalation Toxicity:
未定 Not determined
 
使用安全信息 Safety in Use Information:
类别 Category: hydrotrope, surfactant agents
推荐的4-甲苯磺酸用量不超过 Recommendation for 4-toluene sulfonic acid usage levels up to:
 不用于香水。 not for fragrance use.
 
推荐的4-甲苯磺酸调味剂的用量不超过 Recommendation for 4-toluene sulfonic acid flavor usage levels up to:
 不用于调味料。 not for flavor use.
 
安全参考 Safety references:
Epi系统 EPI System: 视图 View
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EPA物质注册服务(tsca TSCA) :104-15-4
EPA ACToR:毒理学资料 Toxicology Data
EPA物质注册服务(SRS) :注册表 Registry
实验室化学安全摘要 Laboratory Chemical Safety Summary :6101
国家过敏和传染病研究所 National Institute of Allergy and Infectious Diseases:Data
德国wgk WGK Germany:1
4-甲基苯磺酸 4-methyl- benzenesulfonic acid
chemidplus Chemidplus:0000104154
技术 RTECS:104-15-4
 
参考资料 References:
 4-甲基苯磺酸 4-methyl- benzenesulfonic acid
NIST化学网络书籍 NIST Chemistry WebBook: 搜索INCHI
加拿大国内分公司。清单 Canada Domestic Sub. List:104-15-4
pubchem(cid) Pubchem (cid):6101
pubchem(sid) Pubchem (sid):134972723
 
其他资料 Other Information:
(iupac) (IUPAC):元素的原子量2009 Atomic Weights of the Elements 2009
(iupac) (IUPAC):元素的原子量2009(pdf) Atomic Weights of the Elements 2009 (pdf)
影片 Videos:元素周期表 The Periodic Table of Videos
RBC :本网站使用的原子量 Atomic Weights use for this web site
(iupac) (IUPAC):元素周期表 Periodic Table of the Elements
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CHEBI:视图 View
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KEGG (GenomeNet):C06677
hmdb(人类代谢组数据库) HMDB (The Human Metabolome Database):搜索 Search
雾度图 Haz-Map:视图 View
化学蜘蛛 ChemSpider:视图 View
维基百科 Wikipedia:视图 View
rsc学习化学 RSC Learn Chemistry:视图 View
配方/制剂 Formulations/Preparations:
•等级 •grades: 无水一水合物40%水溶液 anhydrous; monohydrate; 40% aqueous solution •无水级 •anhydrous grade, 一水合物级溶液形式 monohydrate gradem solution forms, 深棕色半结晶至结晶固体。 dark brown semicrystaline to crystalline solid.
 
潜在搅拌机 Potential Blenders and core components note
没找到 None Found
 
潜在用途 Potential Uses:
 表面活性剂 surfactants
 
存在(自然 Occurrence (nature, 餐饮 food, 其他) other):note
 自然界中找不到 not found in nature
 
同义词 Synonyms:
 苯磺酸 benzenesulfonic acid, 4-methyl-
 苯磺酸 benzenesulfonic acid, 4-甲基-(1 4-methyl- (1:1:1)
4-methylbenzene 磺酸盐 sulfonate
4-methylbenzene sulfonic acid
para para-methylbenzene sulfonic acid
4-methyl苯磺酸 benzenesulfonic acid
p-methyl苯磺酸 benzenesulfonic acid
4-methyl苯磺酸benzenesulphonic acid
 继碱 stepanate PTSA 65-E
 继碱 stepanate PTSA 65-LS
 继碱 stepanate PTSA-C
 继碱 stepanate PTSA-C99
4-toluene 磺酸盐 sulfonate
para para-toluene 磺酸盐 sulfonate
 toluene sulfonic acid
p-toluene sulfonic acid
para para-toluene sulfonic acid
 toluene-4-sulfonic acid
 toluene-para para-磺酸盐 sulfonate
p-toluenesulfonic acid
para para-toluenesulfonic acid
p-toluenesulphonic acid
p-toluensulfonic acid
p-toluolenesulfonic acid
para para-tolyl sulfonic acid
 

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已发布 PubMed:分散的球形十六烷钒酸盐,其溴化物具有氧化溴化活性。 Discrete spherical hexadecavanadates incorporating a bromide with oxidative bromination activity.
已发布 PubMed:高效液相色谱法测定工作场所空气中的对甲苯磺酸 [Determination of p-toluenesulfonic acid in the air of workplace by HPLC].
已发布 PubMed: 微波辅助合成bis和tris(ω-溴乙酰苯) : 新型双(咪唑并[1]的通用前体 versatile precursors for novel bis(imidazo[1,2-a]吡啶) 2-a]pyridines), 双(咪唑并[1 bis(imidazo[1,2-a]嘧啶)及其三类似物。 2-a]pyrimidines) and their tris-analogs.
已发布 PubMed:Nafion-SiO2杂化催化剂制备碳酸橙花酯 Preparation of glycerol carbonate esters by using hybrid Nafion-silica catalyst.
已发布 PubMed:腺嘌呤作为支架开发新型p2x3受体拮抗剂的评价。 Evaluation of adenine as scaffold for the development of novel P2X3 receptor antagonists.
已发布 PubMed:通过分子掺杂调整石墨烯层的电性能。 Tailoring the electrical properties of graphene layers by molecular doping.
已发布 PubMed:合成 synthesis, 取代度较高的乙酰化玉米淀粉的优化和表征。 optimization and characterization of acetylated corn starch with the high degree of substitution.
已发布 PubMed:一锅反应路线不同 Divergent reaction pathways for one-pot, 新型4h-吡喃[3]的三组分合成 three-component synthesis of novel 4H-pyrano[3,在超声 下的2-h]喹啉。 2-h]quinolines under ultrasound irradiation.
已发布 PubMed: 级联氧化脱芳香化/ 半松果酚 semipinacol重排 : 一种2-螺环-3-氧吲哚衍生物的方法。 an approach to 2-spirocyclo-3-oxindole derivatives.
已发布 PubMed:pt /聚吡咯-对甲苯磺酸过氧化氢敏感电极的制备,用作生物传感器。 Preparation of Pt/polypyrrole-para toluene sulfonate hydrogen peroxide sensitive electrode for the utilizing as a biosensor.
已发布 PubMed:他克莫司的一些转化 Some transformations of tacrolimus, 免疫抑制药物。 an immunosuppressive drug.
已发布 PubMed:高速振动研磨条件下,罐-硝酸银体系促进三组分接触到吡咯 Three-component access to pyrroles promoted by the CAN-silver nitrate system under high-speed vibration milling conditions: 汉茨吡咯合成的一般化。 a generalization of the Hantzsch pyrrole synthesis.
已发布 PubMed:芳基胺的多米诺波娃罗夫反应轻松合成功能化四氢喹啉 Facile synthesis of functionalized tetrahydroquinolines via domino Povarov reactions of arylamines, 丙酸甲酯和芳香醛。 methyl propiolate and aromatic aldehydes.
已发布 PubMed:内消旋卟啉类似物的合成及药理筛选。 Synthesis and pharmacological screening of novel meso-substituted porphyrin analogs.
已发布 PubMed:在中等温度和压力下,对甲苯磺酸和硫酸稀水溶液的预处理和玉米秸秆糖化的比较。 A comparison of dilute aqueous p-toluenesulfonic and sulfuric acid pretreatments and saccharification of corn stover at moderate temperatures and pressures.
已发布 PubMed:环亚氨基酯与森田-巴利斯-希尔曼溴化物的顺序反应,催化 (γ-丁内酰胺-γ-丁内酯)部分的不对称结构。 Catalytic asymmetric construction of spiro(γ-butyrolactam-γ-butyrolactone) moieties through sequential reactions of cyclic imino esters with Morita-Baylis-Hillman bromides.
已发布 PubMed:1h-吡唑并[3]的区域选择性多组分合成 Regioselective multi-component synthesis of 1H-pyrazolo[3,4-d]嘧啶-6(7h)-硫酮。 4-d]pyrimidine-6(7H)-thiones.
已发布 PubMed:涂有海胆样聚苯胺层级结构的聚四氟乙烯复合膜 Poly(tetrafluoroethylene) composite membranes coated with urchin-like polyaniline hiberarchy: 制备和性质。 preparation and properties.
已发布 PubMed:萃取和液相色谱-串联质谱法测定二氢睾丸激素的验证 Validation of a sequential extraction and liquid chromatography-tandem mass spectrometric method for determination of dihydrotestosterone, 前列腺组织中的雄烷二醇和雄烷二醇-葡糖醛酸。 androstanediol and androstanediol-glucuronide in prostate tissues.
已发布 PubMed:从共价键合的二钴肟催化放氢。 Catalytic hydrogen evolution from a covalently linked dicobaloxime.
已发布 PubMed:伊曲康唑的二甲苯磺酸盐和使用环糊精的溶出度提高。 Ditosylate salt of itraconazole and dissolution enhancement using cyclodextrins.
已发布 PubMed:微环境ph-修饰剂的双嘧达莫新型配方,可改善在低水合酸下的溶出度和生物利用度。 Novel formulations of dipyridamole with microenvironmental pH-modifiers for improved dissolution and bioavailability under hypochlorhydria.
已发布 PubMed:光谱的 Spectroscopic, 对甲基甲苯磺酸4-甲基苯铵的热力学研究-一种新的有机nlo单晶。 thermal and mechanical studies on 4-methylanilinium p-toluenesulfonate - a new organic NLO single crystal.
已发布 PubMed:香豆素-三恶烷 Coumarin-trioxane hybrids: 合成和评估作为一类新的抗疟疾支架。 synthesis and evaluation as a new class of antimalarial scaffolds.
已发布 PubMed:含双官能二氮杂四唑的新型一锅假五组分缩合反应 A novel one-pot pseudo-five-component condensation reaction towards bifunctional diazepine-tetrazole containing compounds: 1h-四唑-1h-1的合成 synthesis of 1H-tetrazolyl-1H-1,4-二氮杂-2 4-diazepine-2,3-二腈和1h-四唑基-苯并[b] [1 3-dicarbonitriles and 1H-tetrazolyl-benzo[b][1,4]二氮杂s。 4]diazepines.
已发布 PubMed:ptsa催化的mannich型环化-氧化串联反应 PTSA-catalyzed Mannich-type-cyclization-oxidation tandem reactions: 一锅合成1 one-pot synthesis of 1,3,来自醛的5-取代的吡唑 5-substituted pyrazoles from aldehydes, 肼和炔烃。 hydrazines and alkynes.
已发布 PubMed:蠕虫状胶束辅助棒涂 Wormlike micelle assisted rod coating: 在柔性塑料上方便地制造大面积导电纳米材料薄层的通用方法。 a general method for facile fabrication of large-area conductive nanomaterial thin layer onto flexible plastics.
已发布 PubMed:使用升华的强布朗斯台德酸进行二羧酸和二醇的脱水缩聚。 Dehydration polycondensation of dicarboxylic acids and diols using sublimating strong brønsted acids.
已发布 PubMed:碘介导/布朗斯台德酸催化的乙烯基芳烃二聚 Iodine mediated/Brønsted acid-catalyzed dimerization of vinylarenes: 通过阱捕获的串联反应产生n-(4-碘 iodo-1 ,3-二芳基丁基)乙酰胺。 3-diarylbutyl) acetamides.
已发布 PubMed:压敏粘合系统,使用丙烯酸酯嵌段共聚物响应光照射和后烘烤,作为按需拆卸的双重外部刺激。 Pressure-sensitive adhesion system using acrylate block copolymers in response to photoirradiation and postbaking as the dual external stimuli for on-demand dismantling.
已发布 PubMed:有效率的 Efficient, 高非对映选择性ms 4å促成一锅 highly diastereoselective MS 4 Å-promoted one-pot, 三组分合成2 three-component synthesis of 2,通过短环环化形成6-二取代的4-甲苯磺酰氧基四氢吡喃。 6-disubstituted-4-tosyloxytetrahydropyrans via Prins cyclization.
已发布 PubMed:盐溶液中离子液体的离子对和阴离子驱动的聚集。 Ion pairing and anion-driven aggregation of an ionic liquid in aqueous salt solutions.
已发布 PubMed:1-[((1-乙氧基亚丙基)氨基] -2-乙基-4-(4-羟基苄基)咪唑-5(4h)-1。 1-[(1-ethoxypropylidene)amino]-2-ethyl-4-(4-hydroxybenzyl)imidazol-5(4H)-one.
已发布 PubMed: 高度功能化的新型铬诺 铬 chromeno的有效合成[4 ,3-b]吡咯和吲哚并[6] 3-b]pyrroles and indolizino[6,7-b]吲哚类作为有效的抗菌剂和抗氧化剂。 7-b]indoles as potent antimicrobial and antioxidant agents.
已发布 PubMed:用侧基原酸酯轻松合成酸不稳定的聚合物。 Facile synthesis of acid-labile polymers with pendent ortho esters.
已发布 PubMed:缬氨酸苄酯的对甲苯磺酸对映体拆分是通过优先结晶而实现的。 Enantiomeric resolution of p-toluenesulfonate of valine benzyl ester by preferential crystallizaion.
已发布 PubMed:石墨线条图案技术生产的低成本气体传感器,用于监测香蕉的成熟度。 Low-cost gas sensors produced by the graphite line-patterning technique applied to monitoring banana ripeness.
已发布 PubMed:结合点击多组分反应 Combining click-multicomponent reaction: 一锅合成三唑基甲氧基苯基吲唑[2] one-pot synthesis of triazolyl methoxy-phenyl indazolo[2,1-b]酞嗪-三酮衍生物。 1-b]phthalazine-trione derivatives.
已发布 PubMed:在室温下将 藻迅速转化为呋喃斯坦骨架。 Rapid conversion of spirostans into furostan skeletons at room temperature.
已发布 PubMed:纤维二糖与对甲苯磺酸相互作用 Interactions of D-cellobiose with p-toluenesulfonic acid in aqueous solution: (13)c nmr研究。 a (13)C NMR study.
已发布 PubMed:研磨制备一些新的三氟甲基取代的六氢嘧啶的绿合成和抗菌评估。 Green synthesis and antimicrobial evaluation of some new trifluoromethyl-substituted hexahydropyrimidines by grinding.
已发布 PubMed:合成与电磁 Synthesis and electromagnetic, 核-壳Fe3O4-聚 Poly(3 , 4-乙撑二氧噻吩)微球。 4-ethylenedioxythiophene) microspheres.
已发布 PubMed:未保护的吲哚在水中的非均相催化加氢 Heterogeneous catalytic hydrogenation of unprotected indoles in water: 应对长期挑战的绿解决方案。 a green solution to a long-standing challenge.
已发布 PubMed:取代1的合成与收缩活性 Synthesis and contractile activity of substituted 1,2,3,4-四氢异喹啉。 4-tetrahydroisoquinolines.
已发布 PubMed:水溶液中离子液体聚集体结构的荧光研究。 Fluorescence study on the structure of ionic liquid aggregates in aqueous solutions.
已发布 PubMed:三相生物流化床反应器处理高浓度丙烯酸丁酯生产废水 [Treatment of high-concentration butyl-acrylate-production wastewater by A three-phase biological fluidized bed reactor].
已发布 PubMed:通过衍生自间苯二酚和2-甲基间苯二酚的三吡喃样中间体合成一系列芳族苯并卟啉和杂类似物。 Synthesis of a series of aromatic benziporphyrins and heteroanalogues via tripyrrane-like intermediates derived from resorcinol and 2-methylresorcinol.
已发布 PubMed:嘧啶硫磷对硫胞嘧啶和尿嘧啶部分的抗菌活性。 Antimicrobial activity of pyrimidinophanes with thiocytosine and uracil moieties.
已发布 PubMed:通过在具有正交ph梯度的微制备规模多隔室电解槽中进行等电阱捕集来进行浓缩和分馏。第2部分。 Concentration and fractionation by isoelectric trapping in a micropreparative-scale multicompartmental electrolyzer having orthogonal pH gradients. Part 2.
已发布 PubMed:轻度c-h卤化卤化物并分离出不常见的钯(i)-钯(ii)物种。 Mild C-H halogenation of anilides and the isolation of an unusual palladium(I)-palladium(II) species.
已发布 PubMed: 毒素可在临床相关浓度下抑制乳腺癌抗性蛋白和多药抗性蛋白4的转运。 Uremic toxins inhibit transport by breast cancer resistance protein and multidrug resistance protein 4 at clinically relevant concentrations.
已发布 PubMed:对甲苯磺酸量子化学研究 Quantum chemical study of p-toluenesulfonic acid, 对甲苯磺酸根阴离子和水对甲苯磺酸络合物。与实验光谱数据进行比较。 p-toluenesulfonate anion and the water-p-toluenesulfonic acid complex. Comparison with experimental spectroscopic data.
已发布 PubMed:葡萄糖氧化酶-聚吡咯电极在对甲苯磺酸和对甲苯磺酸钠中合成。 Glucose oxidase-polypyrrole electrodes synthesized in p-toluenesulfonic acid and sodium p-toluenesulfonate.
已发布 PubMed:负载的对甲苯磺酸是一种高度耐用且环保的异氰酸酯清除剂。 Supported p-toluenesulfonic acid as a highly robust and eco-friendly isocyanide scavenger.
已发布 PubMed:为什么两个还不够 Why two are not enough: 细菌群落中摩尔 原始位点降解对甲苯磺酸盐 degradation of p-toluenesulfonate by a bacterial community from a pristine site in Moorea, 法属波利尼西亚。 French Polynesia.
已发布 PubMed:具有侧羟基官能团的可生物降解的功能性聚(酯酰胺) Biodegradable functional poly(ester amide)s with pendant hydroxyl functional groups: 合成 synthesis, 表征 characterization, 制造和体外细胞反应。 fabrication and in vitro cellular response.
已发布 PubMed:缓蚀剂的包封和释放到二氧化钛纳米容器中。 Encapsulation and release of corrosion inhibitors into titania nanocontainers.
已发布 PubMed:硅纳米粒子辅助激光解吸/电离质谱分析脱质子酸 Analysis of deprotonated acids with silicon nanoparticle-assisted laser desorption/ ionization mass spectrometry.
已发布 PubMed:用表面活性剂和非表面活性剂涂覆的勃姆石纳米颗粒稳定的乳液的界面性质。 Interfacial properties of emulsions stabilized with surfactant and nonsurfactant coated boehmite nanoparticles.
已发布 PubMed:一种有效且化学选择性的酰基合成方法。 An efficient and chemoselective procedure for acylal synthesis.
已发布 PubMed:基于蒽的三脚架化学传感器,用于阴离子传感。 An anthracene-based tripodal chemosensor for anion sensing.
已发布 PubMed:双二氢嘧啶 Bis dihydropyrimidine: 合成和抗分枝杆菌活性。 synthesis and antimycobacterial activity.
已发布 PubMed:含热和酸响应性光致变色螺萘并恶嗪的有机胶凝剂。 Thermo- and acid-responsive photochromic spironaphthoxazine-containing organogelators.
已发布 PubMed:5-脂氧合酶抑制剂mk-0633的实用合成。 A practical synthesis of 5-lipoxygenase inhibitor MK-0633.
已发布 PubMed: 铬诺 铬 chromeno [2 ,通过三组分偶联反应合成3-d]嘧啶-三酮。 3-d]pyrimidine-triones synthesis by a three-component coupling reaction.
已发布 PubMed:合成(1r Synthesis of (1R,4s 4S,6r)-5 6R)-5,5,6-三甲基-2-磷酸双环[2.2.2]辛烷及其衍生物。 6-trimethyl-2-phosphabicyclo[2.2.2]octane and derivatives.
已发布 PubMed:合成 synthesis, 官能化氨基酸基聚(酯酰胺)的表征和生物降解。 characterization and biodegradation of functionalized amino acid-based poly(ester amide)s.
已发布 PubMed:亚当·迈克尔(Adam michael)曾说过:“前调是黑胡椒香料,花香温暖,带有水果和天鹅绒的特征。中调和基调散发出柔软的露水花瓣质感。 A general and convenient preparation of [bis(trifluoroacetoxy)iodo]perfluoroalkanes and [bis(trifluoroacetoxy)iodo]arenes by oxidation of organic iodides using oxone and trifluoroacetic acid.
已发布 PubMed:通过串联还原胺化/分子间s(n)ar序列轻松合成2-芳氧基嘧啶衍生物。 A facile synthesis of 2-aryloxypyrimidine derivatives via a tandem reductive amination/intermolecular S(N)Ar sequence.
已发布 PubMed:以对甲苯磺酸掺杂的co-ppy / c作为阴极电催化剂,改善了质子交换膜燃料电池的性能。 Improved performance of proton exchange membrane fuel cells with p-toluenesulfonic acid-doped co-PPy/C as cathode electrocatalyst.
已发布 PubMed:背对背二核铂叔吡啶基络合物 Back-to-back dinuclear platinum terpyridyl complexes: 合成和光物理研究。 synthesis and photophysical studies.
已发布 PubMed: comamonas 睾丸激素 测试 testosteroni t-2的全长lysr型调节子tsar的结构研究揭示了四聚体lttr折叠的新型开放构象。
已发布 PubMed:香豆素衍生物的合成和研究,可潜在地用作存储介质。 Synthesis and study of novel coumarin derivatives potentially utilizable as memory media.
已发布 PubMed:pd(ii)催化c-h羧化的合成应用及机理研究 Synthetic applications of Pd(II)-catalyzed C-H carboxylation and mechanistic insights: 邻氨基苯甲酸便捷途径 expedient routes to anthranilic acids, 恶唑啉酮 oxazolinones, 和喹唑啉酮。 and quinazolinones.
已发布 PubMed:六核硫醇镍金属漆辅助的质子还原 Reduction of protons assisted by a hexanuclear nickel thiolate metallacrown: 质子化和电催化二氢的释放。 protonation and electrocatalytic dihydrogen evolution.
已发布 PubMed:丙酮化物保护的便捷合成3 Convenient Synthesis of Acetonide Protected 3,4-二羟基苯丙氨酸(多巴)用于fmoc固相肽合成。 4-Dihydroxyphenylalanine (DOPA) for Fmoc Solid-Phase Peptide Synthesis.
已发布 PubMed:ptsa-zncl2 PTSA-ZnCl2: 一种合成1的有效催化剂 an efficient catalyst for the synthesis of 1,2,来自mid胺肟和有机腈的4-恶二唑。 4-oxadiazoles from amidoximes and organic nitriles.
已发布 PubMed:在离子液体中化学催化合成阿魏酸酯化的单酰基和二酰基甘油。 Chemoenzymatic synthesis of feruloylated monoacyl- and diacyl-glycerols in ionic liquids.
已发布 PubMed:具有富电子和贫电子的萘-1的二铁质子还原催化剂 Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-二硫醇盐配体。 8-dithiolate ligands.
已发布 PubMed:使用改良的离体兔眼试验评估眼刺激潜力。 Assessing ocular irritation potential using a modified ex vivo rabbit eye test.
已发布 PubMed:银(i)催化的级联 Silver(I)-catalyzed cascade: 直接从炔基氧杂环丁烷获得呋喃。 direct access to furans from alkynyloxiranes.
已发布 PubMed:高价碘催化酮羧酸氧化为内酯。 Hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones.
已发布 PubMed:布朗斯台德酸催化的炔丙基化/环异构化串联反应 Brønsted acid-catalyzed propargylation/cycloisomerization tandem reaction: 由炔丙醇和酰胺一锅合成取代的恶唑。 one-pot synthesis of substituted oxazoles from propargylic alcohols and amides.
已发布 PubMed:对酸敏感的pt(ii)2 Acid-sensitive Pt(II) 2,6-二(吡啶-2-基)嘧啶-4(1h)-复合物。 6-di(pyridin-2-yl)pyrimidin-4(1H)-one complexes.
已发布 PubMed:新的一锅四组分合成双取代吡啶[2 New one-pot four-component synthesis of disubstituted pyrido[2,3-d]嘧啶-6-羧酰胺衍生物。 3-d]pyrimidine-6-carboxamide derivatives.
已发布 PubMed:硫化矿物黄铁矿在非水溶液中作为电化学传感器的应用 Use of the sulfide mineral pyrite as electrochemical sensor in non-aqueous solutions: 电位滴定乙腈中的弱酸 potentiometric titration of weak acids in acetonitrile, 丙腈和苄腈。 propionitrile and benzonitrile.
已发布 PubMed:1,4-富勒烯醇c60aroh 4-Fullerenols C60ArOH: 合成和功能化。 synthesis and functionalization.
已发布 PubMed:离子对介导的低渗透性药物的膜转运的准平衡分析。 Quasi-equilibrium analysis of the ion-pair mediated membrane transport of low-permeability drugs.
已发布 PubMed:微波驱动木材与乙二醇液化。 Microwave driven wood liquefaction with glycols.
已发布 PubMed:合成3-芳基-4h-苯并[3的新型三组分反应 A novel three-component reaction for the synthesis of 3-aryl-4H-benzo [1,4]恶嗪-2-胺。 4] oxazin-2-amine.
已发布 PubMed:合成1 Synthesis of 1,1-二氧苯并[b]噻吩-2-基甲氧基羰基(bsmoc)通过还原bsmoc-5-恶唑二酮来保护正甲基氨基酸,并将其用于肽合成中。 1-Dioxobenzo[b]thiophene-2-ylmethyloxycarbonyl (Bsmoc) protected N-methyl amino acids by reduction of Bsmoc-5-oxazoli-dinones and their use in peptide synthesis.
已发布 PubMed:阴离子染料在掺杂聚苯胺上的吸附和解吸动力学。 Adsorption and desorption kinetics of anionic dyes on doped polyaniline.
已发布 PubMed:一锅将蒂巴因转化为氢可酮并合成新松酮缩酮。 One-pot conversion of thebaine to hydrocodone and synthesis of neopinone ketal.
已发布 PubMed:一类新的扩展pi共轭体系 A novel class of extended pi-conjugated systems: 一锅法合成双-3-氨基咪唑[1 one-pot synthesis of bis-3-aminoimidazo[1,2-a]吡啶 2-a]pyridines, 嘧啶和吡嗪。 pyrimidines and pyrazines.
已发布 PubMed:新的亲脂酪氨酸酯。与羟基酪氨酯进行比较抗氧化剂评估。 New lipophilic tyrosyl esters. Comparative antioxidant evaluation with hydroxytyrosyl esters.
已发布 PubMed:用简单的光谱技术表征对水分敏感的原料。 Characterization of moisture-sensitive raw materials with simple spectroscopic techniques.
已发布 PubMed:空气中二氧化氮监测胶带的改进。 Improvement of a monitoring tape for nitrogen dioxide in air.
已发布 PubMed:苦味素的n-甲基转移酶属于在药用植物中发现的,具有生物活性的单萜类吲哚生物碱γ-生育酚样甲基转移酶的新家族。 A convenient iodination method for alcohols using cesium iodide/methanesulfonic acid and its comparison using cesium iodide/p-toluenesulfonic acid or cesium iodide/aluminium chloride.
已发布 PubMed:使用聚吡咯/ bdnf涂层电极促进 橙花节橙花元外植体的橙花突生长。 Promoting neurite outgrowth from spiral ganglion neuron explants using polypyrrole/BDNF-coated electrodes.
已发布 PubMed:新型基于异氰化物的三组分一锅法合成氰基苯基氨基乙酰胺衍生物。 Novel isocyanide-based three-component one-pot synthesis of cyanophenylamino-acetamide derivatives.
已发布 PubMed:合成 synthesis, 生物活性分子设计 biological active molecular design, 脱氮黄素-胆甾烷杂化化合物的分子对接研究。 and molecular docking study of novel deazaflavin-cholestane hybrid compounds.
已发布 PubMed:异常稳定 Unusually stable, 多才多艺 versatile, 和纯槟榔二甲苯磺酸盐 and pure arenediazonium tosylates: 他们的准备 their preparation, 结构 structures, 和综合适用性。 and synthetic applicability.
已发布 PubMed:串联Friedel工艺将环化成新型per类似物。 Tandem Friedel-Crafts annulation to novel perylene analogues.
已发布 PubMed:p-tsa通过汉兹多组分缩合反应催化轻松,高效地合成聚氢喹啉衍生物。 P-TSA catalyzed facile and efficient synthesis of polyhydroquinoline derivatives through hantzsch multi-component condensation.
已发布 PubMed:Tetr的新型多组分一锅合成脱水-1​​h-1 Novel multicomponent one-pot synthesis of tetrahydro-1H-1,5-苯并二氮杂-2-甲酰胺衍生物。 5-benzodiazepine-2-carboxamide derivatives.
已发布 PubMed:某些芳族酯合成的环保方法 Eco-friendly methodologies for the synthesis of some aromatic esters, 著名的化妆品成分。 well-known cosmetic ingredients.
已发布 PubMed:硒桥联的二铁六羰基铁配合物,作为fe-fe氢化酶活性位点的仿生模型。 Selenium-bridged diiron hexacarbonyl complexes as biomimetic models for the active site of Fe-Fe hydrogenases.
已发布 PubMed:的新型一锅式伪五组分合成4 A novel one-pot pseudo-five-component synthesis of 4,5,6,7-四氢-1h-1 7-tetrahydro-1H-1,4-二氮杂-5-甲酰胺衍生物。 4-diazepine-5-carboxamide derivatives.
已发布 PubMed:两性聚(琥珀酸四乙二醇酯)的合成及其在水中聚集的热敏性。 Synthesis of amphiphilic poly(tetraethylene glycol succinate) and the thermosensitivity of its aggregation in water.
已发布 PubMed:酸催化的亲核芳族取代 Acid-catalyzed nucleophilic aromatic substitution: 多步机制的实验和理论探索。 experimental and theoretical exploration of a multistep mechanism.
已发布 PubMed:用台式磺酸对碳水化合物底物进行多用途的乙酰化反应,并将其应用于一锅法合成过乙酰化的硫糖苷。 Versatile acetylation of carbohydrate substrates with bench-top sulfonic acids and application to one-pot syntheses of peracetylated thioglycosides.
已发布 PubMed:磷酸酯单体的合成及与牙本质的键合 Synthesis of phosphate monomers and bonding to dentin: 酯化方法和五氧化二磷的使用。 esterification methods and use of phosphorus pentoxide.
已发布 PubMed:新型基于异氰酸酯的三组分合成3 Novel isocyanide-based three-component synthesis of 3,4-二氢喹喔啉-2-胺衍生物。 4-dihydroquinoxalin-2-amine derivatives.
已发布 PubMed:[羟基(甲苯磺酰氧基)碘]苯介导的酮的α-叠氮化。 [Hydroxy(tosyloxy)iodo]benzene mediated alpha-azidation of ketones.
已发布 PubMed:紫外光的合成和异构体乙基菊的光辐照导致脂质过氧化。 Synthesis and photoirradiation of isomeric ethylchrysenes by UVA light leading to lipid peroxidation.
已发布 PubMed:基于异氰酸酯的新型三组分反应 A novel isocyanide-based three-component reaction: 合成高度取代的1 synthesis of highly substituted 1,6-二氢吡嗪-2 6-dihydropyrazine-2,3-二腈衍生物。 3-dicarbonitrile derivatives.
已发布 PubMed:仿制药的点击化学方法 A click chemistry approach to glycomimetics: 迈克尔加法2 Michael addition of 2,3,4,6-四-邻-乙酰基-1-硫代-β-d-吡喃葡萄糖到4-脱氧-1 6-tetra-O-acetyl-1-thio-beta-D-glucopyranose to 4-deoxy-1,2-o-异亚丙基-1-甘油-戊-4-enopyranos-3-ulose-一种方便的合成新型4-deoxy-(1→5)-5-c-thiodisaccharides的途径。 2-O-isopropylidene-L-glycero-pent-4-enopyranos-3-ulose--a convenient route to novel 4-deoxy-(1-->5)-5-C-thiodisaccharides.
已发布 PubMed:固体支持的酸,可作为芳香族醚脱保护的温和多功能试剂。 Solid-supported acids as mild and versatile reagents for the deprotection of aromatic ethers.
已发布 PubMed:功能性弹性体聚(酯酰胺)共聚物的合成与表征。 Synthesis and characterization of functional elastomeric poly(ester amide) co-polymers.
已发布 PubMed:液相色谱/串联质谱联用化学衍生化分析水中的甾体雌激素 Analysis of steroid estrogens in water using liquid chromatography/tandem mass spectrometry with chemical derivatizations.
已发布 PubMed:[60]富勒烯融合的内酯的新型功能化。 Novel functionalizations of [60]fullerene-fused lactones.
已发布 PubMed:超支化脂族聚酯接枝凹凸棒石对重金属离子的吸附性能 Adsorption properties of hyperbranched aliphatic polyester grafted attapulgite towards heavy metal ions.
已发布 PubMed:布朗斯台德酸催化的苄基化1 Brønsted acid-catalyzed benzylation of 1,3-二羰基衍生物。 3-dicarbonyl derivatives.
已发布 PubMed:对甲苯磺酸用于烷氧基硅烷受控接枝到含硅烷醇的表面上 Use of p-toluenesulfonic acid for the controlled grafting of alkoxysilanes onto silanol containing surfaces: 可调亲水性的制备 preparation of tunable hydrophilic, 疏水的 hydrophobic, 和超疏水二氧化硅。 and super-hydrophobic silica.
已发布 PubMed:酸催化环酮的醛醇缩环三聚反应制得三亚硝基苯衍生物。方法论发展和机械洞察力。 Trisannulated benzene derivatives by Acid catalyzed aldol cyclotrimerizations of cyclic ketones. Methodology development and mechanistic insight.
已发布 PubMed: 四元金属环配合物与亚硝酰基钌的合成及其在盐酸 HCl加成后的开环。
已发布 PubMed:溶血磷脂酰胆碱及其相关衍生物的新合成。对甲苯磺酸盐用于保护羟基的用途。 A new synthesis of lysophosphatidylcholines and related derivatives. Use of p-toluenesulfonate for hydroxyl group protection.
已发布 PubMed:布朗斯台德酸催化1的炔丙基化 Brønsted acid catalyzed propargylation of 1,3-二羰基衍生物。四取代呋喃的合成。 3-dicarbonyl derivatives. Synthesis of tetrasubstituted furans.
已发布 PubMed:实验性蛛网膜下腔出血后诱导型一氧化氮合酶在血脑屏障功能中的作用有限。 Limited role of inducible nitric oxide synthase in blood-brain barrier function after experimental subarachnoid hemorrhage.
已发布 PubMed:使用未保护和未激活的供体在室温离子液体中进行糖基化。 Glycosylation in room temperature ionic liquid using unprotected and unactivated donors.
已发布 PubMed:通过nmr进行定量分析 Calibration by NMR for quantitative analysis: 对甲苯磺酸为参考物质。 p-toluenesulfonic acid as a reference substance.
已发布 PubMed:结合橙花营养蛋白-3的聚吡咯对听橙花元橙花突生长的促进作用。 The effect of polypyrrole with incorporated neurotrophin-3 on the promotion of neurite outgrowth from auditory neurons.
已发布 PubMed:铁氢酶的活性位点模型 Active-site models for iron hydrogenases: 双核铁配合物的还原化学。 reduction chemistry of dinuclear iron complexes.
已发布 PubMed:4负载的铱(iii)甲硅烷基烷基和环环化合物 Iridium(III) silyl alkyl and iridacyclic compounds supported by 4,4'-di-tert-butyl-2,2'-bipyridyl.
已发布 PubMed:持续产生不稳定的信息素成分 Sustained production of the labile pheromone component, (z (Z,z)-6 Z)-6,9-heneicosadien-11-一个 9-heneicosadien-11-one, 从稳定的前体中监测白标蛾。 from a stable precursor for monitoring the whitemarked tussock moth.
已发布 PubMed:淤浆光反应器中集中太阳 的非均相光催化降解对甲苯磺酸。 Heterogeneous photocatalytic degradation of p-toluenesulfonic acid using concentrated solar radiation in slurry photoreactor.
已发布 PubMed:新的二phosph-二膦和二膦配体的钯(ii)配合物的合成和表征。通过催化共/乙烯共聚生产低分子量交替聚酮。 Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight alternating polyketones via catalytic CO/ethene copolymerisation.
已发布 PubMed:d-甘油-d-gulo-heptono-1合成基于d-和l-丙氨酸多羟基氨基酸 Synthesis of polyhydroxy amino acids based on D- and L-alanine from D-glycero-D-gulo-heptono-1,4-内酯 4-lactone.
已发布 PubMed:对不欧的海洋生物碱马来石全合成的探索 Explorations on the total synthesis of the unusual marine alkaloid chartelline A.
已发布 PubMed:冻结导致酸性水溶液中甲酚红的质子化增强。 Enhanced protonation of cresol red in acidic aqueous solutions caused by freezing.
已发布 PubMed:偶氮二羧酸二烷基酯与p(iii)化合物反应中的光延型中间体的进一步表征。 Further characterization of Mitsunobu-type intermediates in the reaction of dialkyl azodicarboxylates with P(III) compounds.
已发布 PubMed:高效液相色谱/质谱法低水平测定原料药中对甲苯磺酸酯和苯磺酸酯 Low level determination of p-toluenesulfonate and benzenesulfonate esters in drug substance by high performance liquid chromatography/mass spectrometry.
已发布 PubMed:合成hypercloso-b12h12的稳定十二烷氧基衍生物。 Synthesis of stable dodecaalkoxy derivatives of hypercloso-B12H12.
已发布 PubMed:对甲苯磺酸无溶剂条件下快速有效合成多取代喹啉 Rapid and efficient synthesis of poly-substituted quinolines assisted by p-toluene sulphonic acid under solvent-free conditions: 微波 与常规加热的对比研究。 comparative study of microwave irradiation versus conventional heating.
已发布 PubMed:紫外-可见光谱用于追踪二甲苯胺在对甲苯磺酸中的均相聚合动力学。 UV-vis spectroscopy for following the kinetics of homogeneous polymerization of diphenylamine in p-toluene sulphonic acid.
已发布 PubMed:[固定化对苯二酚睾丸激素bs1310(pbs1010)细胞降解对甲苯磺酸]。 [Degradation of p-toluenesulfonate by immobilized Comamonas testosteroni BS1310 (pBS1010) cells].
已发布 PubMed:有效合成甲基1 An efficient synthesis of methyl 1,3-邻异亚丙基-α-d-果糖呋喃糖苷和2 3-O-isopropylidene-alpha-D-fructofuranoside and 2,3:5,来自蔗糖的6-二-邻-异亚丙基-d-葡萄糖二甲基乙缩醛衍生物。 6-di-O-isopropylidene-D-glucose dimethyl acetal derivatives from sucrose.
已发布 PubMed:固态核磁共振与2的热聚合 Solid-state NMR and the thermal polymerization of 2,4-己二炔-1 4-hexadiyne-1,6-二醇双-(对甲苯磺酸盐)。 6-diol bis-(p-toluenesulfonate).
已发布 PubMed: 在两个{ru(trpy trpy)(bpy bpy)}之间进行电子通信的切换(trpy trpy = 2 ,2':6',2' '-三吡啶 -terpyridine and bpy bpy = 2,2'-bipyridine) 中心 centers by by 质子化 质子 protonation on the 桥接 bridging 二巯基噻二唑 dimercaptothiadiazolato 配体 ligand.
已发布 PubMed:内毒素的长链酰基的分子内迁移。 Intramolecular migration of long chain acyl group of enacyloxin IIa methyl ester.
已发布 PubMed:β-取代的β-氨基酯的实际对映选择性合成。 Practical enantioselective synthesis of beta-substituted-beta-amino esters.
已发布 PubMed:甲磺酸甲酯和乙酯的测定 Determination of methyl and ethyl esters of methanesulfonic, 药物活性成分中的苯磺酸和对甲苯磺酸通过固相微萃取(spme)与gc / sim-ms偶联。 benzenesulfonic and p-toluenesulfonic acids in active pharmaceutical ingredients by solid-phase microextraction (SPME) coupled to GC/SIM-MS.
已发布 PubMed:位阻二酰基1的转化 Conversion of sterically hindered diacylated 1,将2-苯二胺转化为2-取代的苯并咪唑。 2-phenylenediamines into 2-substituted benzimidazoles.
已发布 PubMed:α-hordothionin的晶体结构,分辨率为1.9埃。 Crystal structure of alpha-hordothionin at 1.9 Angstrom resolution.
已发布 PubMed:三(2-吡啶基甲基)胺的单核氧钒络合物。 Mononuclear oxovanadium complexes of tris(2-pyridylmethyl)amine.
已发布 PubMed:结构活性的考量和体外评估19种甲烷的遗传毒性的方法 Structure-activity considerations and in vitro approaches to assess the genotoxicity of 19 methane-, 苯磺酸和甲苯磺酸酯。 benzene- and toluenesulfonic acid esters.
已发布 PubMed:具有独特包容能力的骨架改性环糊精衍生物的短合成。 Short synthesis of skeleton-modified cyclodextrin derivatives with unique inclusion ability.
已发布 PubMed:对-甲苯磺酸(ptsa)催化使用超声波辐照快速合成β-吲哚基酮。 An expeditious synthesis of beta-indolylketones catalyzed by p-toluenesulfonic acid (PTSA) using ultrasonic irradiation.
已发布 PubMed:含有碳水化合物部分的手性聚合物 Chiral polymers containing a carbohydrate moiety: 合成。 synthesis.
已发布 PubMed:轻松合成1-取代的2-氨基-3-氰基吡咯 Facile synthesis of 1-substituted 2-amino-3-cyanopyrroles: 5的新合成前体 new synthetic precursors for 5,6-未取代的吡咯并[2 6-unsubstituted pyrrolo[2,3-d]嘧啶。 3-d]pyrimidines.
已发布 PubMed:六水合钴(ii)双(4-甲苯磺酸盐)。 Hexaaquacobalt(II) bis(4-toluenesulfonate).
已发布 PubMed:一种新型的外膜阴离子通道(孔蛋白),作为睾丸激素t-2中4-甲苯磺酸盐假定的两组分传输系统的一部分。 A novel outer-membrane anion channel (porin) as part of a putatively two-component transport system for 4-toluenesulphonate in Comamonas testosteroni T-2.
已发布 PubMed:溶于二甲基亚砜的苯磺酸和4-甲苯磺酸拉曼光谱。 Raman spectroscopy of benzenesulfonic and 4-toluenesulfonic acids dissolved in dimethylsulfoxide.
已发布 PubMed:牙科用dna-脂质膜的嵌入行为和拉伸强度。 Intercalation behavior and tensile strength of DNA-lipid films for the dental application.
已发布 PubMed:离子液体卤化物亲核性在醚裂解中的应用 Application of ionic liquid halide nucleophilicity for the cleavage of ethers: 从醚再生苯酚的绿协议。 a green protocol for the regeneration of phenols from ethers.
已发布 PubMed: 3α alpha的合成 , 7α alpha , 14α alpha-三羟基-5beta beta-cholan-24-oic酸 : 脊椎动物中潜在的伯 酸。 a potential primary bile acid in vertebrates.
已发布 PubMed:(2s的手性合成 Chiral synthesis of (2S,3s)-2-(2-吗啉-2--2-基-2-苯基甲氧基)苯酚。 3S)-2-(2-morpholin-2-yl-2-phenylmethoxy)phenol.
已发布 PubMed:[能够降解对甲苯磺酸厌氧微生物群落分析]。 [Analysis of the anaerobic microbial community capable of degrading p-toluene sulphonate].
已发布 PubMed:固相合成羟脯氨酸衍生物的文库。 Solid-phase synthesis of a library of hydroxyproline derivatives.
已发布 PubMed:组合生成小分子的各种骨架。 Generating diverse skeletons of small molecules combinatorially.
已发布 PubMed:方便地从乳糖制备l-阿拉伯糖基己糖5糖衍生物。 Convenient preparation of L-arabino-hexos-5-ulose derivatives from lactose.
已发布 PubMed:[从厌氧微生物群落降解对甲苯磺酸产甲烷菌]。 [Methanogenic sarcina from an anaerobic microbial community degrading p-toluene sulfonate].
已发布 PubMed:额外的监管机构 An additional regulator, 扎克 TsaQ, 沙皇参与了对睾丸激素t-2中对甲苯磺酸降解过程中的运输调节。 is involved with TsaR in regulation of transport during the degradation of p-toluenesulfonate in Comamonas testosteroni T-2.
已发布 PubMed:巯基自由基与胸腺嘧啶的反应 Thiyl radical reaction with thymine: 氢提取的精华/精粹/精萃速率常数,并与苄基c-h键进行比较。 absolute rate constant for hydrogen abstraction and comparison to benzylic C-H bonds.
已发布 PubMed:连续的pummerer-diels-alder路线,用于产生和捕获呋喃[3] A sequential Pummerer-Diels-Alder route for the generation and trapping of furo[3,4-c]吡啶 4-c]pyridines: 合成1-芳基萘木脂素的杂环类似物。 synthesis of heterocyclic analogues of 1-arylnaphthalene lignans.
已发布 PubMed:用碘代苯和对甲苯磺酸新型醇氧化α-甲苯磺酰化及其在直接制备杂芳族化合物中的合成。 Novel oxidative alpha-tosyloxylation of alcohols with iodosylbenzene and p-toluenesulfonic acid and its synthetic use for direct preparation of heteroaromatics.
已发布 PubMed:新开发的两亲脂质和dna-脂质复合物对细菌的抗菌特性。 Antibacterial characteristics of newly developed amphiphilic lipids and DNA-lipid complexes against bacteria.
已发布 PubMed:新型细菌素系列光敏剂用于光动力癌症的治疗 [New photosensitizers of bacteriochlorin series for photodynamic cancer therapy].
已发布 PubMed:沙皇的特征 Characterization of TsaR, 氧敏感的lysr型调节剂,用于降解睾丸激素t-2中对甲苯磺酸盐。 an oxygen-sensitive LysR-type regulator for the degradation of p-toluenesulfonate in Comamonas testosteroni T-2.
已发布 PubMed:[意外地从androsta-1形成雌酮衍生物 [Unexpected formation of an estrone derivative from androsta-1,4-二烯-3 4-diene-3,17-dione]。 17-dione].
已发布 PubMed:抗肿瘤药500.纳西他汀。 Antineoplastic agents 500. Narcistatin.
已发布 PubMed:胶束电动色谱法在口服药物制剂中苏木素的测定中的应用 Application of micellar electrokinetic chromatography to the determination of sultamicillin in oral pharmaceutical preparations.
已发布 PubMed:颗粒对水溶液中声化学反应的影响。 Influence of particles on sonochemical reactions in aqueous solutions.
已发布 PubMed:酸催化的酯交换反应,是从均聚物中获得聚(3-羟基丁酸酯-共ε-己内酯)共聚物的一种途径。 Acid catalyzed transesterification as a route to poly(3-hydroxybutyrate-co-epsilon-caprolactone) copolymers from their homopolymers.
已发布 PubMed:四正相环己吡咯 Tetra-N-confused cyclohexapyrrole: 3的缩合形成的异常产物 the unusual product formed by condensation of 3,3'-dipyrrom乙烷 ethane with 雷公藤醛 tripyrrin-aldehyde.
已发布 PubMed:苯基/苯基封端的低聚苯胺晶体结构中分子间相互作用的比较研究。 A comparative study of intermolecular interactions in the crystal structures of phenyl/phenyl end-capped oligoanilines.
已发布 PubMed:氧化反应的改性 Modification of the swern oxidation: 使用可回收材料 use of a recyclable, 聚苯乙烯结合的亚砜。 polystyrene bound sulfoxide.
已发布 PubMed:新型布朗斯台德酸性离子液体及其作为双重溶剂催化剂的用途。 Novel Brønsted acidic ionic liquids and their use as dual solvent-catalysts.
已发布 PubMed:微波诱导在固体支持物上合成核糖核苷。 Microwave induced synthesis of ribonucleosides on solid support.
已发布 PubMed:酸催化六高氧杂[3]芳烃的形成。 Acid-catalyzed formation of hexahomooxacalix[3]arenes.
已发布 PubMed:固定在聚吡咯/聚四氢呋喃接枝共聚物中的葡萄糖氧化酶。 Immobilization of glucose oxidase in polypyrrole/polytetrahydrofuran graft copolymers.
已发布 PubMed:薄层色谱与表面辅助激光解吸/电离(saldi)飞行时间质谱联用的一种新方法。 A novel approach of combining thin-layer chromatography with surface-assisted laser desorption/ionization (SALDI) time-of-flight mass spectrometry.
已发布 PubMed:使用对甲苯磺酸-正溴代琥珀酰亚胺对苯乙酮进行声化学溴化。 Sonochemical bromination of acetophenones using p-toluenesulfonic acid-N-bromosuccinimide.
已发布 PubMed:制备 Preparation, 结构体 structure, 角共用双荜澄茄/山苍子体[mo(6)hgq(8)(h(2)o)(18)](8+)的性质和性质(q = s and properties of the corner-shared double cubes [Mo(6)HgQ(8)(H(2)O)(18)](8+) (Q = S, se)和钨类似物。 Se) and tungsten analogues.
已发布 PubMed:微波辅助从桉树脑酮制备环状缩酮作为潜在的化妆品成分 Microwave-assisted preparation of cyclic ketals from a cineole ketone as potential cosmetic ingredients: 无溶剂合成 solvent-free synthesis, 气味评估 odour evaluation, 体外细胞毒性和抗菌测定。 in vitro cytotoxicity and antimicrobial assays.
已发布 PubMed:通过亚氨基亚砜的缩聚物环化-去质子化-环加成级联反应合成取代的2-吡啶酮。 Synthesis of Substituted 2-Pyridones via the Pummerer Cyclization-Deprotonation-Cycloaddition Cascade of Imidosulfoxides.
已发布 PubMed:3-(1-羟烷基)邻苯二甲酸酯与酸反应 Reactions of 3-(1-Hydroxyalkyl)phthalides with Acids: (z)-3-亚烷基萘和3-烷基-8-羟基异香豆素的合成。 Synthesis of (Z)-3-Alkylidenephthalides and 3-Alkyl-8-hydroxyisocoumarins.
已发布 PubMed:硫桥三明治古巴型钼锑簇。合成 Sulfur-Bridged Sandwich Cubane-Type Molybdenum-Antimony Cluster. Synthesis, X射线结构 X-ray Structure, 和[(h(2)o)(9)mo(3)s(4)sbs(4)mo(3)(h(2)o)(9)](ch(3)的(121)sbmössbauer光谱)c(6)h(4)so(3))(8).24h(2)o。 and (121)Sb Mössbauer Spectra of [(H(2)O)(9)Mo(3)S(4)SbS(4)Mo(3)(H(2)O)(9)](CH(3)C(6)H(4)SO(3))(8).24H(2)O.
已发布 PubMed:乙腈溶液中羰基和羟基桥接钌二聚体不同氧化态的原位X射线吸收精细结构研究。 An in Situ X-ray Absorption Fine Structure Study of Different Oxidation States of Oxo- and Hydroxo-Bridged Ruthenium Dimers in Acetonitrile Solution.
已发布 PubMed:dna-脂质膜的制备及其对组织的反应。 Preparation of and tissue response to DNA-lipid films.
已发布 PubMed:了解固体/固体有机反应。 Understanding solid/solid organic reactions.
已发布 PubMed:带环外的卟啉。 16.氟卟啉的合成与光谱表征 Porphyrins with exocyclic rings. 16. Synthesis and spectroscopic characterization of fluoranthoporphyrins, 一类新的高度共轭的卟啉发色团。 a new class of highly conjugated porphyrin chromophores.
已发布 PubMed:酚醛糖苷的合成及抗氧化活性 Synthesis and antiperoxidant activity of new phenolic O-glycosides.
已发布 PubMed:直接将甲硅烷基烯醇醚转化为官能化的烯。 Direct transformation of silyl enol ethers into functionalized allenes.
已发布 PubMed:经由n-芳基-n-甲基-3-(苯基亚磺酰基)丙酰胺的pummerer型环化合成甲氧基-2-喹(+)-香柏酮。 Synthesis of methoxy-2-quinolones via pummerer-type cyclization of N-aryl-N-methyl-3-(phenylsulfinyl)propionamides.
已发布 PubMed:使用表面活性剂增强活性炭中的分析物信号 Using surfactants to enhance the analyte signals in activated carbon, 调查葡萄和葡萄衍生产品中的多酚成分。 surface-assisted laser desorption/ionization (SALDI) mass spectrometry.
已发布 PubMed:会聚区域定向装配2 Convergent regiodirected assembly of 2,3-二取代呋喃 3-disubstituted furans
已发布 PubMed:btch(2)tms辅助的羧酸同系物 BtCH(2)TMS-assisted homologation of carboxylic acids: arndt-eistert arndt-eistert反应的安全替代品
已发布 PubMed:3-c-β-d-吡喃半乳糖基苯乙酮转化为螺酮衍生物。 The conversion of 3-C-beta-D-galactopyranosyl phloroacetophenone to a spiroketal derivative.
已发布 PubMed:新型环状苯基偶氮甲三聚体的选择性合成 Selective synthesis of novel cyclic phenylazomethine trimers
已发布 PubMed:使用亚氨基亚砜的pummerer环化-去质子化-环加成级联反应进行生物碱合成。 Using the Pummerer cyclization-deprotonation-cycloaddition cascade of imidosulfoxides for alkaloid synthesis.
已发布 PubMed:聚(乙二醇)(peg)基树脂在组合固相有机化学中的物理Physical properties of poly(ethylene glycol) (PEG)-based resins for combinatorial solid phase organic chemistry: 子交联树脂和 子接枝树脂的比较。 a comparison of PEG-cross-linked and PEG-grafted resins.
已发布 PubMed:在二甲基亚砜中,d-葡萄糖的α和β端基异构体将crvi还原为criii。动力学和力学的比较研究。 The reduction of CrVI to CrIII by the alpha and beta anomers of D-glucose in dimethyl sulfoxide. A comparative kinetic and mechanistic study.
已发布 PubMed:季铵药物的离子对分配 Ion-pair partition of quarternary ammonium drugs: 不同亲脂性的抗衡离子的影响 the influence of counter ions of different lipophilicity, size, 和灵活性。 and flexibility.
已发布 PubMed:模型磷脂膜对血红蛋白复合物的共振能量转移研究。 Resonance energy transfer study of hemoglobin complexes with model phospholipid membranes.
已发布 PubMed:用过氧化氢氧化降解对甲苯磺酸。 Oxidative degradation of p-toluenesulfonic acid using hydrogen peroxide.
已发布 PubMed:抗肿瘤药。 180.姜黄素和孜然苷a的化学研究和细胞毒性评估 Antitumor agents. 180. Chemical Studies and cytotoxic evaluation of cumingianosides and cumindysoside A, 抗白血病三萜糖苷与14 antileukemic triterpene glucosides with a 14,18-环apotirucallcallane骨架。 18-cycloapotirucallane skeleton.
已发布 PubMed: 具有mo(3)gas(4)(n)(+)(n = 5)的硫桥接的古巴型钼 簇 , 6)核心。 [mo(3)gas(4)(h(2)o)(12)](ch(3)c(6)h(4)so(3))(5).14h(2 )o和[mo(3)gas(4)(h(2)o)(12)](ch(3)c(6)h(4)so(3))(6).17h(2)o 。
已发布 PubMed: comamonas 睾丸激素 测试 testosteroni t-2中对甲苯磺酸操纵子tsambcd和tsar的表征。
已发布 PubMed:具有基本功能的吲哚化学 Chemistry of indoles carrying a basic function, 第3部分。螺[环丙烷-1的合成 Part 3. Synthesis of spiro[cyclopropane-1,3'[3H]吲哚 indol]-2'(1'H)-那些 -ones with 缺氧 antihypoxic 效果 影响 effects.
已发布 PubMed:制备 Preparation, Structure, (& 管理者 mgr; -氧 -oxo)dirhenium dirhenium(iii)的性质和性质 ,iv)和三(2-吡啶基甲基)胺及其(6-甲基-2-吡啶基)甲基衍生物的-dir(iv)络合物。 IV) and -dirhenium(IV) Complexes of Tris(2-pyridylmethyl)amine and Its (6-Methyl-2-pyridyl)methyl Derivatives.
已发布 PubMed:n自由基分解的esr研究 ESR Study of Free Radical Decomposition of N,有机溶液中的正双(芳基磺酰基)羟胺。 N-Bis(arylsulfonyl)hydroxylamines in Organic Solution.
已发布 PubMed: 角共享双荜澄茄/山苍子[mo(6)bis(8)(h(2)o)(18)](8+)作为[mo(3)s(4)(h( 2)o)(9)](4+)在酸性水溶液中。
已发布 PubMed:硫醇的简便有效合成[2 A Facile and Efficient Synthesis of Thieno[2,3-c]呋喃和呋喃[3 3-c]furans and Furo[3,4-b]吲哚经由催油剂诱导的环化反应。 4-b]indoles via a Pummerer-Induced Cyclization Reaction.
已发布 PubMed:[3-羟基-二氢降钙素与叔丁基的反应。二氢co香酚的正式合成]。 [Reaction of 3-hydroxy-dihydrosantonin with TsOH. A formal synthesis of dihydrocotunolide].
已发布 PubMed:对苯甲酸睾丸酮菌株psb-4和t-2的对甲苯甲酸和对甲苯磺酸降解途径及其多组分加氧酶。 Degradative pathways for p-toluenecarboxylate and p-toluenesulfonate and their multicomponent oxygenases in Comamonas testosteroni strains PSB-4 and T-2.
已发布 PubMed:吡啶-2-羧甲醛硫代半脲的3-氨基和5-氨基衍生物的合成及生物活性 Synthesis and biological activity of 3- and 5-amino derivatives of pyridine-2-carboxaldehyde thiosemicarbazone.
已发布 PubMed:串联pummerer-diels-alder反应序列。制备1-芳基萘木脂素的新型级联方法。 Tandem Pummerer-Diels-Alder Reaction Sequence. A Novel Cascade Process for the Preparation of 1-Arylnaphthalene Lignans.
已发布 PubMed:改良方法检测本斯-琼斯蛋白尿。 Detection of Bence-Jones proteinuria by a modified method.
已发布 PubMed:葡糖胺恶唑啉的水解 Hydrolysis of the GlcNAc oxazoline: 脱酰胺和酰基重排。 deamidation and acyl rearrangement.
已发布 PubMed:微波诱导 酸有机反应 Microwave-induced organic reactions of bile acids: 酯化 esterification, 使用温和的试剂进行去甲酰基化和去乙酰化。 deformylation and deacetylation using mild reagents.
已发布 PubMed:Studies on the 中文 Chinese 原油 crude 药品 drug "绍玛 shoma." ix IX. 三 Three 小说 novel 环甾烷醇 cyclolanostanol 木糖苷 xylo侧 sides, 花旗苷H-1 cimicifugosides H-1, h-2和h-5 H-2 and H-5, 来自升麻根茎。 from cimicifuga rhizome.
已发布 PubMed:染色蚀刻的环氧树脂切片,用于光学显微镜。 Staining etched epoxy resin sections for light microscopy.
已发布 PubMed:直链烷基苯磺酸盐表面活性剂及相关化合物的脱细菌作用 Desulfonation of linear alkylbenzenesulfonate surfactants and related compounds by bacteria.
已发布 PubMed:3-磺基邻苯二酚2 3-Sulphocatechol 2, 2-氨基苯磺酸降解途径中的3-di加氧酶 oxygenase和其他双加氧酶 di加氧酶 加氧酶 oxygenases(ec 1.13.11.2和ec 1.14.12.-) , 产碱菌属中的苯磺酸和4-甲苯磺酸。 o-1株。 benzenesulphonic and 4-toluenesulphonic acids in Alcaligenes sp. strain O-1.
已发布 PubMed:梳形的化学合成 Chemical synthesis of a comb-shaped, 支链立体有规多糖 branched stereoregular polysaccharide, 4-o-α-d-甘露吡喃糖基-(1→6)-α-d-甘露吡喃。 4-O-alpha-D-mannopyranosyl-(1-->6)-alpha-D-mannopyranan.
已发布 PubMed: comamonas 睾丸激素 测试 testosteroni t-2吸收4-甲苯磺酸盐。
已发布 PubMed: comamonas 睾丸激素 测试 testosteroni t-2的4-甲苯磺酸甲酯单加氧酶 : 纯化和加氧酶成分的一些特性。 purification and some properties of the oxygenase component.
已发布 PubMed:合成4 Synthesis of 4,doc的19-二取代衍生物。 单核明串球菌中某些皮质类固醇衍生物的放射性受体测定。 19-disubstituted derivatives of DOC. Radioreceptor assay of some corticosteroid derivatives in human mononuclear leukocytes.
已发布 PubMed:荧光脂肪酸衍生化后,通过高效液相色谱检测溶血血小板活化因子。 Detection of lyso-platelet-activating factor by high-performance liquid chromatography after derivatisation with fluorescent fatty acids.
已发布 PubMed: 一种用于维生素k K依赖性羧化酶的γ-谷氨酰胺自由基中间体的捕获方法 : α alpha,β-亚甲基谷氨酸。 beta-methyleneglutamic acid.
已发布 PubMed:苯磺酸降解的初始步骤 Initial steps in the degradation of benzene sulfonic acid, 4-甲苯磺酸 4-toluene sulfonic acids, 和邻氨基苯甲酸在产碱菌中。 o-1株。 and orthanilic acid in Alcaligenes sp. strain O-1.
已发布 PubMed:由相应的环状五肽合成升麻素相关肽内酯 Synthesis of an actinomycin-related peptide lactone from the corresponding cyclic pentapeptide by N,邻酰基转移。 O-acyl shift.
已发布 PubMed:侧链氧化降解对甲苯磺酸 Degradation of p-toluenesulphonic acid via sidechain oxidation, 假单胞菌(comamonas)睾丸激素t-2中的去磺化和间环裂解。 desulphonation and meta ring cleavage in Pseudomonas (Comamonas) testosteroni T-2.
已发布 PubMed:赋予蜂蜡独特的塑性。凯斯特蜡k82p包含一系列羟基聚酯,链长在约200到750之间。 56和76个碳原子,由天然脂肪酸和合成脂肪醇制成。凯斯特蜡k82p使大多数化妆品油凝胶化,并显示出良好的保油性。 Synthetic mucin fragments. Benzyl O-beta-D-galactopyranosyl-(1----3)-O-(2-acetamido-2-deoxy-beta-D- glucopyranosyl)-(1----6)-2-acetamido-2-deoxy-alpha-D-galactopyranoside and O-alpha-L-fucopyranosyl-(1----3)-O-(2-acetamido-2-deoxy-beta-D- glucopyranosyl)-(1----6)-2-acetamido-2-deoxy-D-galactopyranose.
已发布 PubMed:[吡啶酮羧酸代谢研究ii。测定(+-)-7-(3-氨基-1-吡咯烷基)-6-氟-1-(2) [Study on metabolism of pyridonecarboxylic acid II. Determination of metabolites of (+-)-7-(3-amino-1-pyrrolidinyl)-6-fluoro-1-(2,4-二氟苯基)-1 4-difluorophenyl)- 1,4-二氢-4-氧代1 4-dihydro-4-oxo-1,血液中的8-萘啶-3-羧酸对甲苯磺酸水合物(t-3262) 8-naphthyridine-3-carboxylic acid p-toluenesulfonate hydrate (T-3262) in blood, 尿 urine, bile, 和粪便]。 and feces].
已发布 PubMed: Ak KRo- O-锌条85;杂锌棒90; ACTOX 14; ACTOX 16; ACTOX 216;阿马洛克斯偶氮偶氮22;偶氮33;偶氮55;偶氮66;偶氮77tt;卡多尔xx 78;中国白ci77947;沉淀白4; emanay氧化锌埃玛氧化锌锌矿锌花;绿印章8;轮毂白kadox 15;卡多克斯72;卡多克斯25;战胜氧化物ozlo;永久白哲学家的羊毛;粉末基质900;原型类型166
已发布 PubMed:[合成和抑制黑素瘤的4-烷基邻苯二酚-2-o-β-d-吡喃葡萄糖苷橙花糖醛酸及其酯类]。 [Synthesis and melanoma inhibiting properties of 4-alkylpyrocatechol-2-O-beta-D-glucopyranosiduronic acids and their esters].
已发布 PubMed:t-3262的体外和体内活性 In-vitro and in-vivo activities of T-3262, 一种新的吡啶酮羧酸。 a new pyridone carboxylic acid.
已发布 PubMed:环芳烃化 酸合成及诱变性 Synthesis and mutagenicity of a ring-A-aromatized bile acid, 3-羟基-19-nor-1 3-hydroxy-19-nor-1,3,5(10)-胆三烯-24-油酸。 5(10)-cholatrien-24-oic acid.
已发布 PubMed:快速原子轰击质谱法分析亚微克量的核苷酸 Analysis of sub-microgram quantities of nucleotides by fast atom bombardment mass spectrometry.
已发布 PubMed:对硝基苯基6(5)-邻苄基-α-麦芽五糖苷的合成 Synthesis of p-nitrophenyl 6(5)-O-benzyl-alpha-maltopentaoside, α淀粉酶的底物。 a substrate for alpha amylases.
已发布 PubMed:霉素的化学结构和细胞毒活性的实验观察 Observations on the chemical structure and cytotoxic activity of marycin, 血卟啉衍生物。 a hematoporphyrin derivative.
已发布 PubMed:n-(2-氯乙基)修饰的异环磷酰胺类似物的合成及抗肿瘤活性。 Synthesis and antitumor activity of analogues of ifosfamide modified in the N-(2-chloroethyl) group.
已发布 PubMed:合成粘蛋白片段。甲基6-邻-(2-乙酰氨基-2-脱氧-β-d-吡喃葡萄糖基)-β-d-吡喃半乳糖苷 Synthetic mucin fragments. Methyl 6-O-(2-acetamido-2-deoxy-beta-D- glucopyranosyl)-beta-D-galactopyranoside, methyl 3,4-二-邻-(2-乙酰氨基-2-脱氧-β-d-吡喃葡萄糖基)-β-d-吡喃半乳糖苷 4-di-O-(2-acetamido-2-deoxy- beta-D-glucopyranosyl)-beta-D-galactopyranoside, 红姜(姜黄变种)和白姜(姜白变种)对fe(2+)诱导的大鼠脑脂质过氧化的抗氧化和抑制作用。 and methyl O-(2-acetamido-2- deoxy-beta-D-glucopyranosyl)-(1----3)-O-beta-D-galactopyranosyl-(1---- 3)-O-(2- acetamido-2-deoxy-beta-D-glucopyranosyl)-(1----3)-beta-D-galactopyr ano side.
已发布 PubMed:(βs的立体选择性测定 Stereoselective determination of (beta S, γr和beta beta r ,散发着草香气息的玫瑰色天竺葵细腻感,在干燥过程中可被察觉。与前卫的玫瑰木香精配合使用非常好,并且通常与作为搅拌器和花香剂的草木搭配使用。 “ gamma S)-4-[3-(4-acetyl-3-hydroxy-2-propylphenoxy) propylthio]-gamma-hydroxy-beta-methylbenzenebutanoic acid in human and rat plasma by normal-phase high-performance liquid chromatography.
已发布 PubMed:使用对甲苯磺酸同时水解和定量 运铁蛋白中正乙酰氨基葡萄糖和氨基酸可靠性。 The reliability of the use of para toluene sulfonic acid for simultaneous hydrolysis and quantitation of both N-acetyl-glucosamine and amino acids in human transferrins.
已发布 PubMed:对甲苯磺酸水解法测定蛋白质和食品中的蛋氨酸亚砜。 Determination of methionine sulfoxide in protein and food by hydrolysis with p-toluenesulfonic acid.
已发布 PubMed:合成粘蛋白片段 Synthetic mucin fragments: 甲基3-o-(2-乙酰氨基-2-脱氧β-d-吡喃半乳糖基-β-d-3-o-(2-乙酰氨基-2-脱氧-3-o-β-d-吡喃半乳糖基-β-d -吡喃葡萄糖基)-β-d-半乳糖吡喃糖苷;吡喃糖基)-β-d-半乳糖吡喃糖苷。 methyl 3-O-(2-acetamido-2-deoxy-beta-D-galactopyranosyl-beta-D- 3-O-(2-acetamido-2-deoxy-3-O-beta-D-galactopyranosyl- beta-D-glucopyranosyl)-beta-D-galactoyranoside. pyranosyl)-beta-D-galactopyranoside.
已发布 PubMed:储水体中甲苯磺酸钠的卫生调节 [Hygienic regulation of sodium toluene sulfonate in reservoir water].
已发布 PubMed:替代补体途径c3 / 5转换酶cvfbb的改良荧光底物。 An improved fluorogenic substrate for the alternative complement pathway C3/5 converting enzyme CVFBb.
已发布 PubMed:3'-羟基 Hydroxy- and (+/-)-3',11-二羟基-δ9-四氢大麻酚 11-dihydroxy-delta 9-tetrahydrocannabinol: δ9-四氢大麻酚的生物活性代谢产物。 biologically active metabolites of delta 9-tetrahydrocannabinol.
已发布 PubMed:甲基丙烯酸乙二醇酯包埋材料中k-papovavirus抗原的免疫荧光标记 Immunofluorescent labelling of K-papovavirus antigens in glycol methacrylate embedded material: 一种通过荧光显微镜和相邻切片的组织学染色研究感染细胞的方法。 a method for studying infected cell populations by fluorescence microscopy and histological staining of adjacent sections.
已发布 PubMed:硫代硫酸盐硫转移酶中碘乙酸活性位点烷基化的特异性。 The specificity of active-site alkylation by iodoacetic acid in the enzyme thiosulfate sulfurtransferase.
已发布 PubMed:蛋白酶抑制剂抑制角叉菜胶诱导的大鼠炎症中肉芽组织的形成。 Proteinase inhibitors suppress the formation of granulation tissue in the carrageenin-induced inflammation in rats.
已发布 PubMed:对甲苯磺酸/甲醇 p-Toluenesulfonic acid/methanol: 用于制备 酸甲酯的温和试剂。 mild reagent for the preparation of bile acid methyl esters.
已发布 PubMed:小扁豆毒磷脂酶a2的进一步表征和n末端序列。 Further characterization and N-terminal sequence of cobra venom phospholipase A2.
已发布 PubMed:使用对甲苯磺酸盐将突触体膜蛋白溶解到有机溶剂中。 The use of p-toluene sulfonate to dissolve synaptosomal membrane proteins into organic solvents.
已发布 PubMed:二甲基亚砜-盐酸将色氨酸氧化为羟吲哚丙氨酸。含色氨酸肽的选择性修饰。 Oxidation of tryptophan to oxindolylalanine by dimethyl sulfoxide-hydrochloric acid. Selective modification of tryptophan containing peptides.
已发布 PubMed:色氨酸2-硫醚衍生物的新颖合成。色氨酸与肽和蛋白质中半胱氨酸巯基的共价结合。 A novel synthesis of 2-thioether derivatives of tryptophan. Covalent binding of tryptophan to cysteine sulfhydryl groups in peptides and proteins.
已发布 PubMed:合成 synthesis of 双胞嘧啶 dicytidylyl-(3'-5')-1,2-di(adenosin-N6-yl)乙烷 ethane and 双胞嘧啶 dicytidylyl-(3'-5')-1,4-二(腺苷-n6-基)丁烷 4-di(adenosin-N6-yl)butane: 两个转移核糖核酸共价连接末端及其对 磷酸二酯酶的行为 covalently joined terminals of two transfer ribonucleic acids and their behavior toward snake venom phosphodiesterase.
已发布 PubMed:凝血酶对凝血酶的蛋白水解作用。动力学参数的确定 Proteolysis of prothrombin by thrombin. Determination of kinetic parameters, 以及ca2 +离子异常抑制的演示和表征。 and demonstration and characterization of an unusual inhibition by Ca2+ ions.
已发布 PubMed:芬兰农村儿童营养调查。 iv。与饮食变量有关的血清胆固醇值。 Nutrition survey of Finnish rural children. IV. Serum cholesterol values in relation to dietary variables.
已发布 PubMed:d-半乳糖中添加甘油的立体化学 The stereochemistry of the addition of glycerol to D-galactal, β-d-半乳糖苷酶催化。 catalyzed by beta-D-galactosidase.
已发布 PubMed:脂肪醇的芳基磺酸酯作为降胆固醇药。一世 Arylsulfonate esters of fatty alcohols as hypocholesterolemic agents. I: 对甲苯磺酸油基和亚油基。 Oleyl and linoleyl p-toluenesulfonates.
已发布 PubMed:-β-d-吡喃半乳糖基-(1与4相连)-o-(2-乙酰氨基-2-脱氧-β-d-吡喃葡萄糖基)-(1与2)-d-甘露糖相连的合成及其与各种凝集素的相互作用。 Synthesis of O-beta-D-galactopyranosyl-(1 linked to 4)-O-(2acetamido-2-deoxy-beta-D-glucopyranosyl)-(1 linked to 2)-D-mannose and its interaction with various lectins.
已发布 PubMed:猪胰激肽释放酶a和b的表征。 Characterization of pig pancreatic kallikreins A and B.
已发布 PubMed:2-羰基烷氧基环丙基甲基酮的制备及拜耶-维格反应。 Preparation and Baeyer-Villiger Reaction of certain 2-carbalkoxycyclopropyl methyl ketones.
已发布 PubMed:烷基硫代秋水仙碱和正-去乙酰基-烷基硫代秋水仙碱及其抗白血病活性。 Alkylthiocolchicines and N-deacetyl-alkylthiocolchicines and their antileukemic activity.
已发布 PubMed:2-o-(2-乙酰氨基-2-脱氧β-d-吡喃葡萄糖基)-d-甘露糖的合成 Synthesis of 2-O-(2-acetamido-2-deoxy-beta-D-glucopyranosyl)-D-mannose, 及其与d-甘露糖特异性凝集素的相互作用。 and its interaction with D-mannose-specific lectins.
已发布 PubMed:一些醛糖与2的行为 The behavior of some aldoses with 2,2-二甲氧基丙烷-n 2-dimethoxypropane-N,正二甲基甲酰胺-对甲苯磺酸。 ii。在80度 N-dimethylformamide-p-toluenesulfonic acid. II. At 80 degrees.
已发布 PubMed:一些醛糖与2的行为 The behavior of some aldoses with 2,2-二甲氧基丙烷-n 2-dimethoxypropane-N,正二甲基甲酰胺-对甲苯磺酸。一世。在室温(25度)下。 N-dimethylformamide-p-toluenesulfonic acid. I. At room temperature (25 degrees).
已发布 PubMed:对甲苯磺酸水解后,由2-羟基-5-硝基苄基试剂修饰的色氨酸定量分析。 Quantitative analysis of tryptophan modified by 2-hydroxy-5-nitrobenzyl reagents after hydrolysis with p-toluenesulfonic acid.
已发布 PubMed:"缩醛磷脂型 Plasmalogen-type" cyclic 缩醛 acetals: 1的形成和构象 formation and conformation of the 1,3-二恶烷和1 3-dioxanes and 1,3-dioxolanes from 1-0-cis-alk-1'-enyl-sn-甘油 glycerols.
已发布 PubMed:用对甲苯磺酸水解蛋白质。色氨酸测定。 Hydrolysis of proteins with p-toluenesulfonic acid. Determination of tryptophan.
已发布 PubMed:对甲苯磺酸存在下2-乙酰氨基-2-脱氧-d-甘露糖与乙酸异丙烯酯的反应ii。有关3形成机理的证据 The behavior of 2-acetamido-2-deoxy-d-mannose with isopropenyl acetate in the presence of p-toluenesulfonic acid. II. Evidence bearing on the mechanism of the formation of 3,4,6-三邻乙酰基-2-(正乙酰基乙酰氨基)-1 6-tri-O-acetyl-2-(n-acetylacetamido)-1,2-(d-glycero-1)和2-(d-glycero-1 2-dideoxy-d-arabino-hex-1-enopyranose and of 2-(D-glycero-1,2-二乙酰氧基乙基)-4-(正乙酰乙酰氨基)呋喃。 2-diacetoxyethyl)-4-(N-acetylacetamido)furan.
已发布 PubMed:大肠杆菌atp合酶的茎区域。 γ亚基的酪氨酸205位于f1和f0部分之间的界面中,并且可以与epsilon和c低聚物相互作用。 The behavior of 2-acetamido-2-deoxy-d-mannose with isopropenyl acetate in the presence of p-toluenesulfonic acid. I. Isolation and identification of derivatives of 2-amino-D-glucal (2-amino-1,2-dideoxy-d-arabino-hex-1-enopyranose)和其他产品。 2-dideoxy-D-arabino-hex-1-enopyranose) and of other products.
已发布 PubMed:[通过对甲苯磺酸非水滴定法测定植物中的生物碱]。 [DETERMINATION OF ALKALOIDS IN PLANTS BY MEANS OF THE NON-AQUEOUS TITRATION WITH P-TOLUENESULFONIC ACID].
已发布 PubMed:叶黄素中的维生素原a2。 PROVITAMIN A2 FROM LUTEIN.
已发布 PubMed:[在非水介质中滴定。七。氯仿介质中对甲苯磺酸微量滴定的条件研究] [Titrations in non-aqueous media. VII. Study of the conditions for microtitrations with p-toluenesulfonic acid in a chloroform medium].
已发布 PubMed:[由对甲苯磺酸甲酯引起的损害]。 [Damage caused by the methyl ester of p-toluenesulfonic acid].
已发布 PubMed:[对甲苯磺酸试验]。 [The p-toluenesulfonic acid test].
已发布 PubMed:肝病中对甲苯磺酸沉淀反应 [The precipitation reaction to p-toluenesulfonic acid in liver diseases].
已发布 PubMed:[对甲苯磺酸沉淀反应]。 [The p-toluenesulfonic acid precipitation reaction].
已发布 PubMed:[关于对甲苯磺酸试验的临床价值]。 [On the clinical value of the p-toluenesulfonic acid test].
已发布 PubMed:[关于对甲苯磺酸沉淀试验对弥散性红斑 的特异性。它与正常胶体试验和血液蛋白图像的关系]。 [On the specificity of the p-toluenesulfonic acid precipitation test for disseminated lupus erythematosus. Its relation to tests of eucolloidity and to the blood protein picture].
已发布 PubMed:[对甲苯磺酸血清试验研究。在快速测定γ-球蛋白水平中的应用]。 [Study of p-toluenesulfonic acid serum test. Its application to the rapid determination of the gamma-globulin levels].
已发布 PubMed:对甲苯磺酸测试对系统性红斑 的疗效评价。 Evaluation of the p-toluenesulfonic acid test for systemic lupus erythematosus.
 
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