类别 Category:flavoring agents
美国 US/欧盟 EU/ fda / jecfa / fema / Flavis / 文献 Scholar /专利 Patent :
物理性质 Physical Properties:
出现 Appearance: | 无色透明液体(est) colorless clear liquid (est) |
化验 Assay: | 96.00至100.00 96.00 to 100.00
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食品化学品法典列表 Food Chemicals Codex Listed: | No |
比重 Specific Gravity: | 1.07700 to 1.07800 @ 25.00 °C.
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磅每加仑-(est)。 Pounds per Gallon - (est).: | 8.962 to 8.970
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折光率 Refractive Index: | 1.53700 to 1.53900 @ 20.00 °C.
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熔点 Melting Point: | -79.00 °C. @ 760.00 mm 汞 Hg
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沸点 Boiling Point: | 169.00 to 173.00 °C. @ 760.00 mm 汞 Hg
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沸点 Boiling Point: | 105.00 °C. @ 100.00 mm 汞 Hg
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蒸汽压力 Vapor Pressure: | 1.952000 毫米汞柱 mm汞 Hg @ 25.00 °C. (est) |
闪点 Flash Point: | 142.00 °F. tcc TCC ( 61.11 °C. )
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logp(o / w) logP (o/w): | 1.730(est) 1.730 (est) |
溶于 Soluble in: |
| alcohol | | 脂肪 fats | | 水 water, 3880 mg / l @ 25°c(est) 3880 mg/L @ 25 °C (est) |
不溶于 Insoluble in: |
| 水 water |
感官特性 Organoleptic Properties:
气味类型 Odor Type: meaty |
气味强度 Odor Strength:high , 建议在0.10%或更少的溶液中闻到 recommend smelling in a 0.10 % solution or less |
meaty sulfurous |
气味描述 Odor Description:at 0.10 % in propylene glycol. 含硫的 meaty sulfurous |
来自其他 的气味和/或风味描述(如果找到)。 Odor and/or flavor descriptions from others (if found). |
化妆品信息 Cosmetic Information:
供应商 Suppliers:
ambles自然与化学 Ambles Nature et Chimie |
1.3-丙二酚 1.3-PROPANEDITHIOL
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Beijing Lys Chemicals |
1,3-丙二酚 3-Propanedithiol
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BOC Sciences |
仅供实验/研究使用。 For experimental / research use only. |
1,3-丙二酚 3-Propanedithiol
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DeLong Chemicals America |
1,3-丙二酚 3-Propanedithiol, 犹太洁食 Kosher
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Endeavour Specialty Chemicals |
1,3-丙二酚98% 3-Propanedithiol 98%
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特种化工产品组 Speciality Chemical Product Groups |
M&U International |
1,3-丙二酚 3-Propanedithiol, 犹太洁食 Kosher
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Penta International |
1,3-丙二酚 3-Propanedithiol
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R C Treatt & Co Ltd |
1,3-丙二酚 3-Propanedithiol
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Robinson Brothers |
1,3-丙二酚 3-Propanedithiol
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https: //www.robinsonbrothers.uk/化学能力 chemistry-competences |
圣克鲁斯生物技术 Santa Cruz Biotechnology |
仅供实验/研究使用。 For experimental / research use only. |
1,3-propanedithiol
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Sigma-Aldrich |
1,3-丙二酚 3-Propanedithiol, ≥96%, fg FG
气味 Odor: meaty |
认证食品级产品 Certified Food Grade Products |
Sunaux International |
1,3-丙二酚 3-Propanedithiol
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TCI AMERICA |
仅供实验/研究使用。 For experimental / research use only. |
1,3-丙二酚> 97.0%(gc)(t) 3-Propanedithiol >97.0%(GC)(T)
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滕州吉田香气化学 Tengzhou Jitian Aroma Chemiclal |
1,3-丙二酚 3-Propanedithiol
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Tianjin Danjun International |
1,3-丙二酚 3-Propanedithiol
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WholeChem |
1,3-丙二酚 3-Propanedithiol
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安全信息 Safety Information:
首选SDS Preferred SDS: 视图 View |
欧洲信息 European information : |
最重要的危害 Most important hazard(s): | xi-刺激性 Xi - Irritant |
r 36/37/38-刺激眼睛 R 36/37/38 - Irritating to eyes, 呼吸系统 respiratory system, and skin 皮. S 02 - 保持 Keep out of the 达到 reach of 孩子们 children. S 03/07/09 - 保持 Keep 容器 container 紧紧 tightly 关闭 关 closed in 凉 cool, 通风良好 好 well-ventilated 地点 place. S 24/25 - 避免 Avoid contact with skin 皮 and 眼睛 eyes. S 26 - In 案件 case of contact with 眼睛 eyes, 冲洗 rinse 立即 immediately with 充裕 plenty of 水 water and 寻求 seek 医疗 medical advice. S 36 - 穿 Wear 适当 suitable 保护性 protective 服装 clothing.
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危害识别 Hazards identification |
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物质或混合物的分类 Classification of the substance or mixture |
根据29 cfr 1910(osha hcs)进行ghs分类 GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
没有找到。 None found. |
ghs标签元素 GHS Label elements, 包括预防性声明 including precautionary statements |
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象形图 Pictogram | |
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危险说明 Hazard statement(s) |
没有找到。 None found. |
防范说明 Precautionary statement(s) |
没有找到。 None found. |
口服/肠胃外毒性 Oral/Parenteral Toxicity: |
口鼠 oral-rat LD50 100 - 200 mg/kg kg (e (Eastman 柯达 Kodak Co., 1955b) 1955b)
老鼠 oral-mouse LD50 1070 mg/kg kg Reported as ALD (近似 Approximate 致死 Lethal 剂量 Dose) (沙弗尔 Schafer & 保龄球 Bowles, 1985)
静脉猫 intravenous-cat LD50 28 mg/kg kg 行为的 BEHAVIORAL: 震颤 TREMOR
胃肠道 GASTROINTESTINAL: 唾液腺结构或功能的变化 CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
行为的 BEHAVIORAL: 抽搐 CONv VULSIONS OR 影响 EFFECT ON 发作 SEIZURE THREsh SHOLD Journal of 药理 Ph臂 armacology and 实验性的 Experimental 疗法 Therapeutics. Vol. 87(补给 Suppl), pg。 6 Pg. 6, 1946.
老鼠 oral-mouse ldlo LDLo 1070 mg/kg kg Archives of 环境的 环保 Env铁 ironmental 污染 Contamination and 毒理学 Toxicology. Vol. 14, pg。 111 Pg. 111, 1985.
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皮肤毒性 Dermal Toxicity: |
未定 Not determined
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吸入毒性 Inhalation Toxicity: |
未定 Not determined
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使用安全信息 Safety in Use Information:
类别 Category: | flavoring agents |
推荐1 Recommendation for 1,3-丙烷二硫醇的使用量高达 3-propane dithiol usage levels up to: | | 不用于香水。 not for fragrance use.
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最大化源自调查的每日摄入量(ms di- di- eu) : | 0.85(微克/ 均/天) 0.85 (μg/capita/day) |
结构类 Structure Class: | I |
采用 Use 等级 levels for FEMA GRAS flavoring 物质 substances on 哪一个 which the FEMA 专家 Expert 面板 Panel 基于 based its 判断 judgments that the 物质 substances are 通常 generally 公认的 recognized as safe (GRAS). |
The 专家 Expert 面板 Panel 也 also 发表 publishes 分离 separate 广泛 extensive 评论 reviews of scientific information on all FEMA GRAS flavoring 物质 substances and can be 发现 found at FEMA 味道 Flavor Ingredient 图书馆 Library |
出版编号 publication number: 11 |
单击此处查看出版物11 Click here to view publication 11 |
| 平均 average 通常 usual 百万分之几 ppm | 平均 average 最大 maximum 百万分之几 ppm |
焙烤食品 baked goods: | - | 0.20000 |
饮料(不含醇) beverages(nonalcoholic): | - | - |
醇饮料 beverages(alcoholic): | - | - |
早餐麦片 breakfast cereal: | - | - |
起司 cheese: | - | - |
口香糖 chewing gum: | - | - |
调味品/调味品 condiments / relishes: | - | - |
糖果烧烤 confectionery froastings: | - | - |
蛋制品 egg products: | - | - |
脂肪/油 fats / oils: | - | - |
鱼产品 fish products: | - | - |
冷冻乳制品 frozen dairy: | - | - |
水果冰 fruit ices: | - | - |
明胶/布丁 gelatins / puddings: | - | - |
砂糖 granulated sugar: | - | - |
肉汁 gravies: | - | 0.20000 |
硬糖 hard candy: | - | - |
仿乳制品 imitation dairy: | - | - |
速溶咖啡/茶 instant coffee / tea: | - | - |
果酱/果冻 jams / jellies: | - | - |
肉制品 meat products: | - | 0.20000 |
奶制品 milk products: | - | - |
坚果产品 nut products: | - | 0.20000 |
其他谷物 other grains: | - | - |
家禽 poultry: | - | - |
加工水果 processed fruits: | - | - |
加工蔬菜 processed vegetables: | - | - |
重构蔬菜 reconstituted vegetables: | - | - |
调味料 seasonings / flavors: | - | - |
休闲食品 snack foods: | - | 0.20000 |
软糖 soft candy: | - | - |
汤类 soups: | - | 0.20000 |
糖替代品 sugar substitutes: | - | - |
甜酱 sweet sauces: | - | - |
安全参考 Safety references:
欧洲食品安全法规(efsa) European Food Safety Athority(efsa):风味使用水平;亚急性 Flavor usage levels; Subacute, 亚慢性 Subchronic, 慢性和致癌性研究;发育/ 毒性研究;遗传毒性研究... Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
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欧洲食品安全局(efsa EFSA)参考 :
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调味组评估8(fge.08)[1] Flavouring Group Evaluation 8 (FGE.08)[1]: 脂族和脂环族单- Aliphatic and alicyclic mono-, di- di- , 三 tri-, and 多硫化物 polysulphides with or 没有 without 额外 additional 充氧 oxygenated 功能性 functional groups from chemical group 20 视图 View page or 视图 View pdf
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调味组评估8 Flavouring Group Evaluation 8, 版本1(fge.08rev1) Revision 1 (FGE.08Rev1): 脂族和脂环族单- Aliphatic and alicyclic mono-, di- di- , 三 tri-, and 多硫化物 polysulphides with or 没有 without 额外 additional 充氧 oxygenated 功能性 functional groups from chemical groups 20 and 30 视图 View page or 视图 View pdf
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调味品组评价的科学见解8 Scientific Opinion on Flavouring Group Evaluation 8, 版本3(fge.08rev3) Revision 3 (FGE.08Rev3): 脂族和脂环族单- Aliphatic and alicyclic mono-, di- di- , 三 tri-, and 多硫化物 polysulphides with or 没有 without 额外 additional 充氧 oxygenated 功能性 functional groups from chemical groups 20 and 30 视图 View page or 视图 View pdf
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调味品组评价的科学见解08 Scientific Opinion on Flavouring Group Evaluation 08, 修订版4(fge.08rev4) Revision 4 (FGE.08Rev4): 脂族和脂环族单- Aliphatic and alicyclic mono-, di- di- , 三 tri-, and 多硫化物 polysulphides with or 没有 without 额外 additional 充氧 oxygenated 功能性 functional groups from chemical groups 20 and 30 视图 View page or 视图 View pdf
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Epi系统 EPI System: 视图 View |
环境诱变信息中央 Env. Mutagen Info. Center:搜索 Search |
橙花发育和 毒性 NLM Developmental and Reproductive Toxicity:搜索 Search |
EPA物质注册服务(tsca TSCA) :109-80-8 |
EPA ACToR:毒理学资料 Toxicology Data |
EPA物质注册服务(SRS) :注册表 Registry |
实验室化学安全摘要 Laboratory Chemical Safety Summary :8013 |
国家过敏和传染病研究所 National Institute of Allergy and Infectious Diseases:Data |
德国wgk WGK Germany:3 |
丙烷1 propane-1,3-二硫醇 3-dithiol |
chemidplus Chemidplus:0000109808 |
epa / noaa客串 EPA/NOAA CAMEO:有害物质 hazardous materials |
技术 RTECS:CAS#109-80-8的tz2585500 TZ2585500 for cas# 109-80-8 |
参考资料 References:
| 丙烷1 propane-1,3-二硫醇 3-dithiol |
NIST化学网络书籍 NIST Chemistry WebBook: | 搜索INCHI |
加拿大国内分公司。清单 Canada Domestic Sub. List: | 109-80-8 |
pubchem(cid) Pubchem (cid): | 8013 |
pubchem(sid) Pubchem (sid): | 134973858 |
其他资料 Other Information:
潜在搅拌机 Potential Blenders and core 组件 components note
气味 For Odor |
胶质的 alliaceous |
dimethyl trisulfide FL/FR |
烧了 burnt |
rum ether FL/FR |
咖啡 coffee |
咖啡 coffee difuran FL/FR |
2- methyl-3-,5 or 6-(furfuryl thio) pyrazine FL/FR |
meaty |
meaty dithiane FL/FR |
4- methyl nonanoic acid FL/FR |
硫磺基 sulfuryl acetate FL/FR |
发霉的 musty |
榛子坚果 hazel nut pyrazine FL/FR |
坚果 nutty |
4,5- dimethyl-2-ethyl-3-thiazoline FL/FR |
2- methyl pyrazine FL/FR |
2- methyl-3-(methyl thio) pyrazine FL/FR |
sulfurous |
苯并 benzothiazole FL/FR |
ethyl 3-mercaptopropionate FL/FR |
鱼 fish thiol FL/FR |
2- mercaptopropionic acid FL/FR |
4- methyl 4-mercaptopentan-2-one 1% 解 solution FL/FR |
1- phenethyl 硫醇 mercaptan FL/FR |
烟草 tobacco |
methyl 苯并 benzoxole FL/FR |
用于调味 For Flavor |
找不到适合这些的口味组 No flavor group found for these |
4- acetyl-2-methyl pyrimidine FL |
gamma- aminobut butyric acid FL |
戊基 amyl 硫醇 mercaptan FL |
1,2- but butane dithiol FL |
2-(2- but butyl)-4,5-dimethyl-3-thiazoline FL |
环丙基(e cyclopropyl (E,Z)-2,6-nonadienamide FL |
2,5- diethyl thiazole FL |
dimethyl tetrasulfide FL |
2,6- dimethyl-3-((2-甲基-3- 2-methyl-3-furyl)thio)-4-heptanone FL |
bis(2 ,5- dimethyl-3-furyl) disulfide FL |
(z + e)-2 (Z+E)-2,5- dimethyl-3-tetrahydrofuran thiol FL |
(z + e)-2 (Z+E)-2,5- dimethyl-3-thioacetoxytetrahydrofuran FL |
2,5- dimethyl-3-thiofuroyl furan FL |
乙基(e ethyl (E,Z)-2,6-nonadienamide FL |
s- S- ethyl 2-acetyl 氨基乙烷 amino乙烷 ethane thioate FL |
ethyl 3-mercaptopropionate FL/FR |
ethyl 4-(acetyl thio) but butyrate FL |
(Z+E)-5- ethyl-4-methyl-2-(2-but butyl) thiazoline FL |
(Z+E)-5- ethyl-4-methyl-2-(2-methyl propyl) thiazoline FL |
massoia 皮 bark oil FL |
4- methyl 4-mercaptopentan-2-one 1% 解 solution FL/FR |
methyl 二氢呋喃 dihydrofuran thiol FL |
2- methyl thiazolidine FL |
2-( methyl thio) ethanol FL |
2- methyl-3-,5 or 6-(furfuryl thio) pyrazine FL/FR |
2- methyl-3-(methyl thio) pyrazine FL/FR |
2- methyl-3-furyl tetrasulfide FL |
3-((2- methyl-3-furyl)thio)-4-heptanone FL |
4-((2- methyl-3-furyl)thio)-5-nonanone FL |
1,9- nonane dithiol FL |
花生 pea坚果 nut dithiazine FL |
1- phenethyl 硫醇 mercaptan FL/FR |
propyl 2-甲基-3- 2-methyl-3-furyl disulfide FL |
异 iso propyl disulfide FL |
thiazole FL |
3- thienyl 硫醇 mercaptan FL |
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n-(2-(3 N-(2-(3,4- dimethoxyphenyl)ethyl)-3,4-dimethoxycinnamic acid amide FL |
3,7- dimethyl-2,6-octadien-1-yl 环丙基 cyclopropyl carboxamide FL |
4- mercapto-2-pentanone 1% in acetoin FL |
2- methyl-1-methyl thio-2-but butene FL |
(1 pyrrolidino-(1,2E)-4H-2,4-dimethyl-1,3,5-dithiazine FL |
1-(2- thienyl) but butanone FL |
胶质的 alliaceous |
胶质的 alliaceous |
1,3- but butane dithiol FL |
dimethyl trisulfide FL/FR |
3- tetrahydrothiophenone FL |
烧了 burnt |
培根 bacon dithiazine FL |
1,6- hexane dithiol FL |
rum ether FL/FR |
chemical |
2,5- dimethyl furan FL |
cocoa |
but butyraldehyde FL |
咖啡 coffee |
咖啡 coffee difuran FL/FR |
泥土的 earthy |
二糠基 difurfuryl sulfide FL |
1,8- octane dithiol FL |
蛋黄 eggy |
异 iso propyl 硫醇 mercaptan FL |
脂肪的 fatty |
(e (E,e)-2 E)-2,4- decadienal FL |
4- methyl nonanoic acid FL/FR |
2- pentyl thiophene FL |
绿 green |
4- penten-1-yl acetate FL |
meaty |
4- allyl-2,6-dimethoxyphenol FL |
苯并 benzothiazole FL/FR |
2,6- dimethyl thiophenol FL |
2,5- dimethyl-3-furan thiol FL |
1,1- 乙烷 ethane dithiol 1% in ethanol 94.5% / ethyl acetate 4% FL |
4- furfuryl thio-2-pentanone FL |
meaty dithiane FL/FR |
(r (R,S)-2- mercapto-3-but butanol FL |
2- mercaptomethyl pyrazine FL |
2- mercaptopropionic acid FL/FR |
2- methyl 3-(methyl thio) furan FL |
12- methyl tridecanal FL |
bis(2 - methyl-3-furyl) disulfide FL |
s- S-(2- methyl-3-furyl) 乙烷 ethane thioate FL |
2- methyl-3-tetrahydrofuran thiol FL |
propyl 2-mercaptopropionate FL |
吡嗪基 pyrazinyl 乙烷 ethane thiol FL |
2- pyridinyl m乙烷 ethane thiol FL |
硫磺基 sulfuryl acetate FL/FR |
thialdine FL |
ortho- thiocresol FL |
ortho- thioguaiacol FL |
金属的 metallic |
2,5- dihydroxy-1,4-dithiane FL |
发霉的 musty |
2- ethoxythiazole FL |
榛子坚果 hazel nut pyrazine FL/FR |
坚果 nutty |
3,5- diethyl-2-methyl pyrazine FL |
2,5- diethyl-3-methyl pyrazine FL |
4,5- dimethyl-2-ethyl-3-thiazoline FL/FR |
methyl 苯并 benzoxole FL/FR |
2- methyl pyrazine FL/FR |
坚果 nutty thiazole FL |
洋葱 onion |
furfuryl isopropyl sulfide FL |
methionol FL |
爆米花 popcorn |
2- propionyl-2-thiazoline FL |
烤 roasted |
hexyl 硫醇 mercaptan FL |
savory |
n-(2 N-(2,4- dimethoxybenzyl)-N2-(2-(pyridin-2-yl)ethyl) oxalamide FL |
n- N-( heptan-4-yl)苯并 benzo(D)(1,3)dioxole-5-carboxamide FL |
N1-(2- methoxy-4-methyl benzyl)-N2-(2-(pyridin-2-yl)ethyl) oxalamide FL |
N1-(2- methoxy-4-methyl benzyl)-N2-2(2-(5-methyl pyridin-2-yl)ethyl) oxalamide FL |
sulfurous |
2,3- but butane dithiol FL |
s- S- ethyl thioacetate FL |
鱼 fish thiol FL/FR |
methyl 2-甲基-3- 2-methyl-3-furyl disulfide FL |
3- methyl-2-but butane thiol FL |
2- naphthyl 硫醇 mercaptan FL |
烤 roasted but butanol FL |
2,4,6- trithiaheptane 10% in triacetin FL |
蔬菜 vegetable |
tyramine FL |
潜在用途 Potential Uses:
存在(自然 Occurrence (nature, food, 其他) other): note
| 自然界中找不到 not found in nature |
同义词 Synonyms:
1,3- | dimercaptopropane | 1,3- | dithiolpropane | | 二硫亚甲基dithiomethyleneglycol | | 二硫三亚甲基 dithio三亚甲基 trimethylene glycol | | 二硫三亚甲基 dithio三亚甲基 trimethyleneglycol | 3- | mercaptopropanethiol | 1,3- | propane 二硫醇 di硫醇 mercaptan | | 丙烷1 propane-1,3-二硫醇 3-dithiol | 1,3- | propane二硫醇 di硫醇 mercaptan | 1,3- | propanedithiol | | 三亚甲基 trimethylene 二硫醇 di硫醇 mercaptan | | 三亚甲基 trimethylene 二硫代乙dithioglycol | | 三亚甲基 trimethylene dithiol | | 三亚甲基 trimethylene 硫醇 mercaptan | | 三亚甲基二硫代乙二醇 三亚甲基 trimethylene二硫代乙dithioglycol | | 三亚甲基 trimethylenedithiol | 1,3- | 三亚甲基 trimethylenedithiol |
文章 Articles:
已发布 PubMed:1的结构表征 Structural characterization of 1,具有羧酸3-丙二硫醇 3-propanedithiols that feature carboxylic acids: 汞螯合剂的同系物。 Homologues of mercury chelating agents. |
已发布 PubMed:超高真空下链烷二酚分子电导的链长和温度依赖性。 Chain length and temperature dependence of alkanedithiol molecular conductance under ultra high vacuum. |
已发布 PubMed:合成新糖缀合物,该新糖缀合物含有对应于伯克霍尔德氏菌内核和变形杆菌脂多糖的4-氨基-4-脱氧-1-阿拉伯糖表位。 Synthesis of Neoglycoconjugates Containing 4-Amino-4-deoxy-l-arabinose Epitopes Corresponding to the Inner Core of Burkholderia and Proteus Lipopolysaccharides. |
已发布 PubMed:基于寡核苷酸和鲁米诺功能化的金纳米颗粒的新型组装策略的凝血酶无标记电化学发光适体传感器。 A label-free electrochemiluminescence aptasensor for thrombin based on novel assembly strategy of oligonucleotide and luminol functionalized gold nanoparticles. |
已发布 PubMed:在疏水表面和聚硫化物-橡胶聚合物之间分配溶解的有机物结合汞。 Partitioning of dissolved organic matter-bound mercury between a hydrophobic surface and polysulfide-rubber polymer. |
已发布 PubMed:铋硫醇对体外分离自 类慢性伤口细菌形成的生物膜的体外功效。 In vitro efficacy of bismuth thiols against biofilms formed by bacteria isolated from human chronic wounds. |
已发布 PubMed:2-溴-3-甲基-1反应中新的环氧化物形成 Novel epoxide formation in the reaction of 2-bromo-3-methyl-1,4-萘醌与1 4-naphthoquinone with 1,3-propanedithiol. |
已发布 PubMed:丝裂霉素使二硫醇交联c。 Cross-linking of dithiols by mitomycin C. |
已发布 PubMed:广泛的文献搜索和审查作为评估婴儿和后续配方奶粉的基本准备工作以及成长奶的准备工作查看页面或查看pdf Experimental and theoretical investigation of effect of spacer arm and support matrix of synthetic affinity chromatographic materials for the purification of monoclonal antibodies. |
已发布 PubMed:新的双硫代硫代磷酸酯和双磷代氨基甲酸酯 New bisphosphorothioates and bisphosphoroamidates: synthesis, 分子建模以及杀虫剂和毒理学特性的测定。 molecular modeling and determination of insecticide and toxicological profile. |
已发布 PubMed:无味的制备和应用1 Preparation and application of odorless 1,3-丙二酚试剂。 3-propanedithiol reagents. |
已发布 PubMed:锰和rh的二硫醇盐配合物 Dithiolate complexes of manganese and rhenium: 不欧的混合价簇mn3(co)6(mu-eta2-sch2ch2ch2s)3的x射线结构和性质。 X-ray structure and properties of an unusual mixed valence cluster Mn3(CO)6(mu-eta2-SCH2CH2CH2S)3. |
已发布 PubMed:(v)二硫代磺酸盐的c-s键裂解反应的研究 Studies of C-S bond cleavage reactions of Re(V) dithiolates: synthesis, 反应性 reactivity, 和机制。 and mechanism. |
已发布 PubMed:水中的化学选择性硫缩醛化 Chemoselective thioacetalization in water: 3-(1,3-二噻二-2-亚烷基)戊烷-2 3-dithian-2-ylidene)pentane- 2,4-二酮无味 4-dione as an odorless, 有效率的 efficient, 和实用的硫缩醛化试剂。 and practical thioacetalization reagent. |
已发布 PubMed:与硫代和二硫代配体的配合物 Rhenium(V) complexes with thiolato and dithiolato ligands: synthesis, 结构 structures, 和单体化反应。 and monomerization reactions. |
已发布 PubMed:固相微萃取-多检测器气相色谱法测定罗沙酮的灵敏方法 Sensitive method for the determination of roxarsone using solid-phase microextraction with multi-detector gas chromatography. |
已发布 PubMed:第一种非硫代 The first nonthiolic, 无味的1 odorless 1,3-丙二酚当量及其在硫缩醛化中的应用。 3-propanedithiol equivalent and its application in thioacetalization. |
已发布 PubMed:硫醇分子添加对树枝状金纳米复合材料形态的影响 Effects of various thiol molecules added on morphology of dendrimer-gold nanocomposites. |
已发布 PubMed:固相微萃取-气相色谱-质谱法自动定量 尿中的2-氯乙烯基壬酸 Quantitation of 2-chlorovinylarsonous acid in human urine by automated solid-phase microextraction--gas chromatography--mass spectrometry. |
已发布 PubMed:双金属(v)和二氧or(vii)化合物的合成与表征 Synthesis and characterization of dimetallic oxorhenium(V) and dioxorhenium(VII) compounds, 以及化学计量和催化反应的研究。 and a study of stoichiometric and catalytic reactions. |
已发布 PubMed:rs-.hsr氢键 The RS-.HSR Hydrogen Bond: α的酸度 acidities of alpha,ω-二硫醇及其单自由基的电子亲和力。 omega-dithiols and electron affinities of their monoradicals. |
已发布 PubMed:动力学限制4-甲基-5-(吡嗪-2-基)-1的硫解 Kinetic constraints for the thiolysis of 4-methyl-5-(pyrazin-2-yl)-1, 2-二硫基-3-硫酮(奥提普拉斯 oltipraz)和相关的二硫基-3-硫酮的水溶液。 |
已发布 PubMed:4-噻唑烷酮和1的合成及其抗分枝杆菌活性 Syntheses and experimental studies on the relative stabilities of spiro, 安莎 ansa, 和环状四聚氟磷腈的桥连衍生物。 and bridged derivatives of cyclic tetrameric fluorophosphazene. |
已发布 PubMed:固相微萃取-气相色谱-火焰光度法或质谱检测法测定土壤中的路易斯酸 Determination of lewisite oxide in soil using solid-phase microextraction followed by gas chromatography with flame photometric or mass spectrometric detection. |
已发布 PubMed:二硫醇配体对地噻烷的体外和体内锥虫杀虫活性的影响以及在水溶液中配体交换的研究。 Contribution of dithiol ligands to in vitro and in vivo trypanocidal activities of dithiaarsanes and investigation of ligand exchange in an aqueous solution. |
已发布 PubMed:一些新的二硫杂蒽烷的合成和体外驱虫性能。 Synthesis and in vitro anthelmintic properties of some new dithiaarsanes. |
已发布 PubMed:脱硫弧菌脱硫尿铁还原酶 Desulfovibrio desulfuricans iron hydrogenase: 该结构显示了与活动中心双核中心的异常协调。 the structure shows unusual coordination to an active site Fe binuclear center. |
已发布 PubMed:黄杆菌py2降解环氧烷烃的黄素蛋白的纯化和表征。 Purification and characterization of a flavoprotein involved in the degradation of epoxyalkanes by Xanthobacter Py2. |
已发布 PubMed:固相微萃取-气相色谱-质谱法测定环境中的有机砷 Determination of organoarsenicals in the environment by solid-phase microextraction-gas chromatography-mass spectrometry. |
已发布 PubMed:亲脂性硫醇螯合剂增强铋的抗菌活性。 Enhancement of bismuth antibacterial activity with lipophilic thiol chelators. |
已发布 PubMed:硫醇对大鼠肝脏正弦谷胱甘肽转运的影响的特异性和方向性。 Specificity and directionality of thiol effects on sinusoidal glutathione transport in rat liver. |
已发布 PubMed:半胱胺相关硫醇和胺在大鼠中的生长抑素消耗能力 Somatostatin depleting potency of cysteamine-related thiols and amines in the rat: 构效关系。 structure-activity relation. |
已发布 PubMed:阿拉伯呋喃糖基吡咯烷[2 Arabinofuranosylpyrrolo[2,3-d]嘧啶可作为 类巨细胞 感染的潜在药物。 3-d]pyrimidines as potential agents for human cytomegalovirus infections. |
已发布 PubMed:通过与酶的糖结合位点中的sh基相互作用,四氧嘧啶对葡萄糖激酶的抑制作用。 Inhibition of glucokinase by alloxan through interaction with SH groups in the sugar-binding site of the enzyme. |
已发布 PubMed:电泳法测定配体的新方法 A new electrophoretic method for determining ligand: mt化学计量的无载体99mtc-放射性药物。 technetium stoichiometry in carrier free 99mTc-radiopharmaceuticals. |
已发布 PubMed:[2-氨基-1的合成 [Synthesis of 2-amino-1,3-丙二酚及相关化合物]。 3-propanedithiol and related compounds]. |
已发布 PubMed:某些长链酸二硫醇二酯的X射线衍射粉末研究。 X-ray diffraction powder studies of some dithiol diesters of long chain acids. |
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